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Improving the Corrosion Performance of Organically Coated Steel Using a Sol–Gel Overcoat

Evan Watkins Orcid Logo, Christian Griffiths, Calvin Richards, Sarah-Jane Potts Orcid Logo, Chris Batchelor Orcid Logo, Peter Barker, Justin Searle Orcid Logo, Eifion Jewell Orcid Logo

Materials, Volume: 17, Issue: 5, Start page: 1075

Swansea University Authors: Evan Watkins Orcid Logo, Christian Griffiths, Calvin Richards, Sarah-Jane Potts Orcid Logo, Justin Searle Orcid Logo, Eifion Jewell Orcid Logo

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DOI (Published version): 10.3390/ma17051075

Abstract

Organically coated steels are widely used in applications in which they are subjected to the natural environment and therefore require excellent corrosion resistance. Organic clearcoats are typically employed as a barrier that improves the overall corrosion resistance; however, they are typically de...

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Published in: Materials
ISSN: 1996-1944
Published: MDPI AG 2024
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URI: https://cronfa.swan.ac.uk/Record/cronfa65848
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The successful demonstration of using a simple TEOS-based coating to improve the corrosion resistance of organically coated steel highlights the potential for further investigation into the use of sol–gels for these applications.</abstract><type>Journal Article</type><journal>Materials</journal><volume>17</volume><journalNumber>5</journalNumber><paginationStart>1075</paginationStart><paginationEnd/><publisher>MDPI AG</publisher><placeOfPublication/><isbnPrint/><isbnElectronic/><issnPrint/><issnElectronic>1996-1944</issnElectronic><keywords>sol–gel; coatings; corrosion; barrier; coil coating</keywords><publishedDay>26</publishedDay><publishedMonth>2</publishedMonth><publishedYear>2024</publishedYear><publishedDate>2024-02-26</publishedDate><doi>10.3390/ma17051075</doi><url/><notes/><college>COLLEGE NANME</college><CollegeCode>COLLEGE CODE</CollegeCode><institution>Swansea University</institution><apcterm>External research funder(s) paid the OA fee (includes OA grants disbursed by the Library)</apcterm><funders>This work was made possible by the Engineering and Physical Science Research Council (EP/S02252X/1), Innovate UK and by the European Regional Development Fund through the Welsh Government. 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spelling v2 65848 2024-03-15 Improving the Corrosion Performance of Organically Coated Steel Using a Sol–Gel Overcoat ac8763e21b39071c449e017bcb8e2299 0009-0000-5202-2357 Evan Watkins Evan Watkins true false 6ec8aad26102e4a1c7b00c1832471424 Christian Griffiths Christian Griffiths true false fba04fac258816964c5a4ba702b025e9 Calvin Richards Calvin Richards true false 8c536622ba65fa1e04912d0e2ede88f7 0000-0003-0208-2364 Sarah-Jane Potts Sarah-Jane Potts true false 0e3f2c3812f181eaed11c45554d4cdd0 0000-0003-1101-075X Justin Searle Justin Searle true false 13dc152c178d51abfe0634445b0acf07 0000-0002-6894-2251 Eifion Jewell Eifion Jewell true false 2024-03-15 Organically coated steels are widely used in applications in which they are subjected to the natural environment and therefore require excellent corrosion resistance. Organic clearcoats are typically employed as a barrier that improves the overall corrosion resistance; however, they are typically derived from fossil fuel-based feedstock. A more sustainable alternative could be possible using sol–gel coatings. The application of a simple tetraethoxysilane (TEOS)-based sol–gel was applied to polyurethane-coated steels using a spray coater. The concentration of TEOS was altered to produce coatings containing either 2.5% or 10%. The 10% TEOS resulted in dense, homogeneous coatings that offered a significant improvement in corrosion resistance compared to an uncoated substrate. Whereas the 2.5% TEOS coatings were inhomogeneous and porous, which indicated a limitation of concentration required to produce a uniform coating. The successful demonstration of using a simple TEOS-based coating to improve the corrosion resistance of organically coated steel highlights the potential for further investigation into the use of sol–gels for these applications. Journal Article Materials 17 5 1075 MDPI AG 1996-1944 sol–gel; coatings; corrosion; barrier; coil coating 26 2 2024 2024-02-26 10.3390/ma17051075 COLLEGE NANME COLLEGE CODE Swansea University External research funder(s) paid the OA fee (includes OA grants disbursed by the Library) This work was made possible by the Engineering and Physical Science Research Council (EP/S02252X/1), Innovate UK and by the European Regional Development Fund through the Welsh Government. The authors would like to thank the Materials and Manufacturing Academy and COATED CDT (COATED M2A) in Swansea University, Engineering and Physical Sciences Research Council (EPSRC via UKRI), the European Social Fund via the Welsh Government and TATA Steel UK for supporting the work described in this article. SEM facilities were provided by the Swansea University AIM Facility, funded in part by the EPSRC. Thanks also to NSG Pilkinton for providing spray coating facilities. EP/S02252X/1 2024-04-18T14:20:28.4916155 2024-03-15T15:14:10.8910066 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Evan Watkins 0009-0000-5202-2357 1 Christian Griffiths 2 Calvin Richards 3 Sarah-Jane Potts 0000-0003-0208-2364 4 Chris Batchelor 0000-0002-2257-3913 5 Peter Barker 6 Justin Searle 0000-0003-1101-075X 7 Eifion Jewell 0000-0002-6894-2251 8 65848__29729__0987a5538c5e4023aa3e51ba67e0f66a.pdf 65848.VOR.pdf 2024-03-15T15:20:16.5015203 Output 7237785 application/pdf Version of Record true Copyright: © 2024 by the authors. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license true eng https://creativecommons.org/licenses/by/4.0/
title Improving the Corrosion Performance of Organically Coated Steel Using a Sol–Gel Overcoat
spellingShingle Improving the Corrosion Performance of Organically Coated Steel Using a Sol–Gel Overcoat
Evan Watkins
Christian Griffiths
Calvin Richards
Sarah-Jane Potts
Justin Searle
Eifion Jewell
title_short Improving the Corrosion Performance of Organically Coated Steel Using a Sol–Gel Overcoat
title_full Improving the Corrosion Performance of Organically Coated Steel Using a Sol–Gel Overcoat
title_fullStr Improving the Corrosion Performance of Organically Coated Steel Using a Sol–Gel Overcoat
title_full_unstemmed Improving the Corrosion Performance of Organically Coated Steel Using a Sol–Gel Overcoat
title_sort Improving the Corrosion Performance of Organically Coated Steel Using a Sol–Gel Overcoat
author_id_str_mv ac8763e21b39071c449e017bcb8e2299
6ec8aad26102e4a1c7b00c1832471424
fba04fac258816964c5a4ba702b025e9
8c536622ba65fa1e04912d0e2ede88f7
0e3f2c3812f181eaed11c45554d4cdd0
13dc152c178d51abfe0634445b0acf07
author_id_fullname_str_mv ac8763e21b39071c449e017bcb8e2299_***_Evan Watkins
6ec8aad26102e4a1c7b00c1832471424_***_Christian Griffiths
fba04fac258816964c5a4ba702b025e9_***_Calvin Richards
8c536622ba65fa1e04912d0e2ede88f7_***_Sarah-Jane Potts
0e3f2c3812f181eaed11c45554d4cdd0_***_Justin Searle
13dc152c178d51abfe0634445b0acf07_***_Eifion Jewell
author Evan Watkins
Christian Griffiths
Calvin Richards
Sarah-Jane Potts
Justin Searle
Eifion Jewell
author2 Evan Watkins
Christian Griffiths
Calvin Richards
Sarah-Jane Potts
Chris Batchelor
Peter Barker
Justin Searle
Eifion Jewell
format Journal article
container_title Materials
container_volume 17
container_issue 5
container_start_page 1075
publishDate 2024
institution Swansea University
issn 1996-1944
doi_str_mv 10.3390/ma17051075
publisher MDPI AG
college_str Faculty of Science and Engineering
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hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
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description Organically coated steels are widely used in applications in which they are subjected to the natural environment and therefore require excellent corrosion resistance. Organic clearcoats are typically employed as a barrier that improves the overall corrosion resistance; however, they are typically derived from fossil fuel-based feedstock. A more sustainable alternative could be possible using sol–gel coatings. The application of a simple tetraethoxysilane (TEOS)-based sol–gel was applied to polyurethane-coated steels using a spray coater. The concentration of TEOS was altered to produce coatings containing either 2.5% or 10%. The 10% TEOS resulted in dense, homogeneous coatings that offered a significant improvement in corrosion resistance compared to an uncoated substrate. Whereas the 2.5% TEOS coatings were inhomogeneous and porous, which indicated a limitation of concentration required to produce a uniform coating. The successful demonstration of using a simple TEOS-based coating to improve the corrosion resistance of organically coated steel highlights the potential for further investigation into the use of sol–gels for these applications.
published_date 2024-02-26T14:20:25Z
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