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Fully 3D Printed Tin Selenide (SnSe) Thermoelectric Generators with Alternating n-Type and p-Type Legs

Matthew Richard Burton Orcid Logo, Geraint Howells, Shahin Mehraban, James McGettrick Orcid Logo, Nicholas Lavery Orcid Logo, Matt Carnie Orcid Logo

ACS Applied Energy Materials, Volume: 6, Issue: 10, Pages: 5498 - 5507

Swansea University Authors: Geraint Howells, Shahin Mehraban, James McGettrick Orcid Logo, Nicholas Lavery Orcid Logo, Matt Carnie Orcid Logo

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DOI (Published version): 10.1021/acsaem.3c00576

Abstract

Tin selenide (SnSe) has attracted much attention in the field of thermoelectrics since the discovery of the record figure of merit (zT) of 2.6 ± 0.3. While there have been many publications on p-type SnSe, to manufacture efficient SnSe thermoelectric generators, ann-type is also required. Publicatio...

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Published in: ACS Applied Energy Materials
ISSN: 2574-0962 2574-0962
Published: American Chemical Society (ACS) 2023
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URI: https://cronfa.swan.ac.uk/Record/cronfa63518
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While there have been many publications on p-type SnSe, to manufacture efficient SnSe thermoelectric generators, ann-type is also required. Publications on n-type SnSe, however, are limited. This paper reports a pseudo-3D-printing technique to fabricate bulk n-type SnSe elements, by utilizing Bi as a dopant. Various Bi doping levels are investigated and characterized over a wide range of temperatures and through multiple thermal cycles. Stable n-type SnSe elements are then combined with printed p-type SnSe elements to fabricate a fully printed alternating n- and p-type thermoelectric generator, which is shown to produce 145 μW at 774 K.</abstract><type>Journal Article</type><journal>ACS Applied Energy Materials</journal><volume>6</volume><journalNumber>10</journalNumber><paginationStart>5498</paginationStart><paginationEnd>5507</paginationEnd><publisher>American Chemical Society (ACS)</publisher><placeOfPublication/><isbnPrint/><isbnElectronic/><issnPrint>2574-0962</issnPrint><issnElectronic>2574-0962</issnElectronic><keywords>thermoelectrics, printed, tin selenide, thermoelectric generator, TEG, n-type</keywords><publishedDay>22</publishedDay><publishedMonth>5</publishedMonth><publishedYear>2023</publishedYear><publishedDate>2023-05-22</publishedDate><doi>10.1021/acsaem.3c00576</doi><url>http://dx.doi.org/10.1021/acsaem.3c00576</url><notes/><college>COLLEGE NANME</college><department>Science and Engineering - Faculty</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>FGSEN</DepartmentCode><institution>Swansea University</institution><apcterm>SU Library paid the OA fee (TA Institutional Deal)</apcterm><funders>EPSRC (EP/N020863/1), European Regional Development Fund (c80892) through the Welsh Government for funding. EPSRC (EP/S018107/1), M2A funding from the European Social Fund via Welsh Government (c80816), EPSRC (EP/L015099/1), and Tata steel. Welsh Government, ERDF, and SMART Expertise Wales for funding MACH1 and COMET. ERDF and WEFO for funding of SPARC II. 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spelling v2 63518 2023-05-22 Fully 3D Printed Tin Selenide (SnSe) Thermoelectric Generators with Alternating n-Type and p-Type Legs 38ea375f0590c53c9cfbf34daa1eb766 Geraint Howells Geraint Howells true false c7e4a4152b2cf403da129be7d1c2904d Shahin Mehraban Shahin Mehraban true false bdbacc591e2de05180e0fd3cc13fa480 0000-0002-7719-2958 James McGettrick James McGettrick true false 9f102ff59824fd4f7ce3d40144304395 0000-0003-0953-5936 Nicholas Lavery Nicholas Lavery true false 73b367694366a646b90bb15db32bb8c0 0000-0002-4232-1967 Matt Carnie Matt Carnie true false 2023-05-22 FGSEN Tin selenide (SnSe) has attracted much attention in the field of thermoelectrics since the discovery of the record figure of merit (zT) of 2.6 ± 0.3. While there have been many publications on p-type SnSe, to manufacture efficient SnSe thermoelectric generators, ann-type is also required. Publications on n-type SnSe, however, are limited. This paper reports a pseudo-3D-printing technique to fabricate bulk n-type SnSe elements, by utilizing Bi as a dopant. Various Bi doping levels are investigated and characterized over a wide range of temperatures and through multiple thermal cycles. Stable n-type SnSe elements are then combined with printed p-type SnSe elements to fabricate a fully printed alternating n- and p-type thermoelectric generator, which is shown to produce 145 μW at 774 K. Journal Article ACS Applied Energy Materials 6 10 5498 5507 American Chemical Society (ACS) 2574-0962 2574-0962 thermoelectrics, printed, tin selenide, thermoelectric generator, TEG, n-type 22 5 2023 2023-05-22 10.1021/acsaem.3c00576 http://dx.doi.org/10.1021/acsaem.3c00576 COLLEGE NANME Science and Engineering - Faculty COLLEGE CODE FGSEN Swansea University SU Library paid the OA fee (TA Institutional Deal) EPSRC (EP/N020863/1), European Regional Development Fund (c80892) through the Welsh Government for funding. EPSRC (EP/S018107/1), M2A funding from the European Social Fund via Welsh Government (c80816), EPSRC (EP/L015099/1), and Tata steel. Welsh Government, ERDF, and SMART Expertise Wales for funding MACH1 and COMET. ERDF and WEFO for funding of SPARC II. All authors acknowledge the SU AIM Facility (EPSRC EP/M028267/1) for microscopy and imaging. 2023-06-13T15:23:59.3477799 2023-05-22T14:58:04.7140462 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Matthew Richard Burton 0000-0002-0376-6322 1 Geraint Howells 2 Shahin Mehraban 3 James McGettrick 0000-0002-7719-2958 4 Nicholas Lavery 0000-0003-0953-5936 5 Matt Carnie 0000-0002-4232-1967 6 63518__27565__2dd64e27aef143fcbbd84faa0478c98a.pdf 63518.VOR.pdf 2023-05-22T15:09:45.0147664 Output 5262717 application/pdf Version of Record true Distributed under the terms of a Creative Commons Attribution CC-BY International 4.0 Licence true eng https://creativecommons.org/licenses/by/4.0/ 191 Matthew Burton 0000-0002-0376-6322 m.r.burton@swansea.ac.uk true https://doi.org/10.5281/zenodo.6447783 false
title Fully 3D Printed Tin Selenide (SnSe) Thermoelectric Generators with Alternating n-Type and p-Type Legs
spellingShingle Fully 3D Printed Tin Selenide (SnSe) Thermoelectric Generators with Alternating n-Type and p-Type Legs
Geraint Howells
Shahin Mehraban
James McGettrick
Nicholas Lavery
Matt Carnie
title_short Fully 3D Printed Tin Selenide (SnSe) Thermoelectric Generators with Alternating n-Type and p-Type Legs
title_full Fully 3D Printed Tin Selenide (SnSe) Thermoelectric Generators with Alternating n-Type and p-Type Legs
title_fullStr Fully 3D Printed Tin Selenide (SnSe) Thermoelectric Generators with Alternating n-Type and p-Type Legs
title_full_unstemmed Fully 3D Printed Tin Selenide (SnSe) Thermoelectric Generators with Alternating n-Type and p-Type Legs
title_sort Fully 3D Printed Tin Selenide (SnSe) Thermoelectric Generators with Alternating n-Type and p-Type Legs
author_id_str_mv 38ea375f0590c53c9cfbf34daa1eb766
c7e4a4152b2cf403da129be7d1c2904d
bdbacc591e2de05180e0fd3cc13fa480
9f102ff59824fd4f7ce3d40144304395
73b367694366a646b90bb15db32bb8c0
author_id_fullname_str_mv 38ea375f0590c53c9cfbf34daa1eb766_***_Geraint Howells
c7e4a4152b2cf403da129be7d1c2904d_***_Shahin Mehraban
bdbacc591e2de05180e0fd3cc13fa480_***_James McGettrick
9f102ff59824fd4f7ce3d40144304395_***_Nicholas Lavery
73b367694366a646b90bb15db32bb8c0_***_Matt Carnie
author Geraint Howells
Shahin Mehraban
James McGettrick
Nicholas Lavery
Matt Carnie
author2 Matthew Richard Burton
Geraint Howells
Shahin Mehraban
James McGettrick
Nicholas Lavery
Matt Carnie
format Journal article
container_title ACS Applied Energy Materials
container_volume 6
container_issue 10
container_start_page 5498
publishDate 2023
institution Swansea University
issn 2574-0962
2574-0962
doi_str_mv 10.1021/acsaem.3c00576
publisher American Chemical Society (ACS)
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
url http://dx.doi.org/10.1021/acsaem.3c00576
document_store_str 1
active_str 0
description Tin selenide (SnSe) has attracted much attention in the field of thermoelectrics since the discovery of the record figure of merit (zT) of 2.6 ± 0.3. While there have been many publications on p-type SnSe, to manufacture efficient SnSe thermoelectric generators, ann-type is also required. Publications on n-type SnSe, however, are limited. This paper reports a pseudo-3D-printing technique to fabricate bulk n-type SnSe elements, by utilizing Bi as a dopant. Various Bi doping levels are investigated and characterized over a wide range of temperatures and through multiple thermal cycles. Stable n-type SnSe elements are then combined with printed p-type SnSe elements to fabricate a fully printed alternating n- and p-type thermoelectric generator, which is shown to produce 145 μW at 774 K.
published_date 2023-05-22T15:23:57Z
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score 11.013731

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