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Derivation of the Statistical Distribution of the Mass Peak Centroids of Mass Spectrometers Employing Analog-to-Digital Converters and Electron Multipliers

Andreas Ipsen

Analytical Chemistry, Volume: 89, Issue: 4, Pages: 2232 - 2241

Swansea University Author: Andreas Ipsen

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DOI (Published version): 10.1021/acs.analchem.6b02446

Abstract

The statistical distribution of mass peak centroids recorded on mass spectrometers employing analog-to-digital converters (ADCs) and electron multipliers is derived from the first principles of the data generation process. The resulting Gaussian model is discussed and is validated with experimental...

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Published in: Analytical Chemistry
Published: ACS Publications 2017
URI: https://cronfa.swan.ac.uk/Record/cronfa31939
first_indexed 2017-02-14T19:52:52Z
last_indexed 2018-02-09T05:19:19Z
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spelling 2018-01-12T11:05:16.9964049 v2 31939 2017-02-10 Derivation of the Statistical Distribution of the Mass Peak Centroids of Mass Spectrometers Employing Analog-to-Digital Converters and Electron Multipliers 5bc63515666926dd39a5ccf64f6ba865 Andreas Ipsen Andreas Ipsen true false 2017-02-10 The statistical distribution of mass peak centroids recorded on mass spectrometers employing analog-to-digital converters (ADCs) and electron multipliers is derived from the first principles of the data generation process. The resulting Gaussian model is discussed and is validated with experimental data and with Monte Carlo simulations. Journal Article Analytical Chemistry 89 4 2232 2241 ACS Publications mass spectrometry, mass peak centroid, statistical distribution 21 2 2017 2017-02-21 10.1021/acs.analchem.6b02446 COLLEGE NANME COLLEGE CODE Swansea University RCUK, MR/J013994/1 2018-01-12T11:05:16.9964049 2017-02-10T22:52:06.4608305 Faculty of Medicine, Health and Life Sciences Swansea University Medical School - Medicine Andreas Ipsen 1 0031939-09062017100908.pdf acs.analchem.6b02446.pdf 2017-06-09T10:09:08.7200000 Output 473930 application/pdf Version of Record true 2017-06-09T00:00:00.0000000 Distributed under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited. true eng
title Derivation of the Statistical Distribution of the Mass Peak Centroids of Mass Spectrometers Employing Analog-to-Digital Converters and Electron Multipliers
spellingShingle Derivation of the Statistical Distribution of the Mass Peak Centroids of Mass Spectrometers Employing Analog-to-Digital Converters and Electron Multipliers
Andreas Ipsen
title_short Derivation of the Statistical Distribution of the Mass Peak Centroids of Mass Spectrometers Employing Analog-to-Digital Converters and Electron Multipliers
title_full Derivation of the Statistical Distribution of the Mass Peak Centroids of Mass Spectrometers Employing Analog-to-Digital Converters and Electron Multipliers
title_fullStr Derivation of the Statistical Distribution of the Mass Peak Centroids of Mass Spectrometers Employing Analog-to-Digital Converters and Electron Multipliers
title_full_unstemmed Derivation of the Statistical Distribution of the Mass Peak Centroids of Mass Spectrometers Employing Analog-to-Digital Converters and Electron Multipliers
title_sort Derivation of the Statistical Distribution of the Mass Peak Centroids of Mass Spectrometers Employing Analog-to-Digital Converters and Electron Multipliers
author_id_str_mv 5bc63515666926dd39a5ccf64f6ba865
author_id_fullname_str_mv 5bc63515666926dd39a5ccf64f6ba865_***_Andreas Ipsen
author Andreas Ipsen
author2 Andreas Ipsen
format Journal article
container_title Analytical Chemistry
container_volume 89
container_issue 4
container_start_page 2232
publishDate 2017
institution Swansea University
doi_str_mv 10.1021/acs.analchem.6b02446
publisher ACS Publications
college_str Faculty of Medicine, Health and Life Sciences
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hierarchy_top_id facultyofmedicinehealthandlifesciences
hierarchy_top_title Faculty of Medicine, Health and Life Sciences
hierarchy_parent_id facultyofmedicinehealthandlifesciences
hierarchy_parent_title Faculty of Medicine, Health and Life Sciences
department_str Swansea University Medical School - Medicine{{{_:::_}}}Faculty of Medicine, Health and Life Sciences{{{_:::_}}}Swansea University Medical School - Medicine
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description The statistical distribution of mass peak centroids recorded on mass spectrometers employing analog-to-digital converters (ADCs) and electron multipliers is derived from the first principles of the data generation process. The resulting Gaussian model is discussed and is validated with experimental data and with Monte Carlo simulations.
published_date 2017-02-21T13:03:22Z
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score 11.048518

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