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Derivation of the Statistical Distribution of the Mass Peak Centroids of Mass Spectrometers Employing Analog-to-Digital Converters and Electron Multipliers
Analytical Chemistry, Volume: 89, Issue: 4, Pages: 2232 - 2241
Swansea University Author: Andreas Ipsen
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DOI (Published version): 10.1021/acs.analchem.6b02446
Abstract
The statistical distribution of mass peak centroids recorded on mass spectrometers employing analog-to-digital converters (ADCs) and electron multipliers is derived from the first principles of the data generation process. The resulting Gaussian model is discussed and is validated with experimental...
| Published in: | Analytical Chemistry |
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| Published: |
ACS Publications
2017
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| URI: | https://cronfa.swan.ac.uk/Record/cronfa31939 |
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| Abstract: |
The statistical distribution of mass peak centroids recorded on mass spectrometers employing analog-to-digital converters (ADCs) and electron multipliers is derived from the first principles of the data generation process. The resulting Gaussian model is discussed and is validated with experimental data and with Monte Carlo simulations. |
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| Keywords: |
mass spectrometry, mass peak centroid, statistical distribution |
| College: |
Faculty of Medicine, Health and Life Sciences |
| Issue: |
4 |
| Start Page: |
2232 |
| End Page: |
2241 |