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High performance non-fullerene organic photovoltaics under implant light illumination region

Ram Datt Orcid Logo, Harrison Lee, Michael Spence, Matt Carnie Orcid Logo, Wing Chung Tsoi Orcid Logo

Applied Physics Letters, Volume: 122, Issue: 14, Start page: 143906

Swansea University Authors: Ram Datt Orcid Logo, Harrison Lee, Michael Spence, Matt Carnie Orcid Logo, Wing Chung Tsoi Orcid Logo

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DOI (Published version): 10.1063/5.0144861

Abstract

Implantable biomedical electronics, such as pacemakers, drug pumps, cochlear implants, cardioverter-defibrillators, and neurological stimulators, help humans to overcome various diseases. Currently, the power supply for these devices relies on small-size batteries, and replacement of the battery is...

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Published in: Applied Physics Letters
ISSN: 0003-6951 1077-3118
Published: AIP Publishing 2023
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URI: https://cronfa.swan.ac.uk/Record/cronfa63147
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Currently, the power supply for these devices relies on small-size batteries, and replacement of the battery is required after running for a period of time. Recharging the battery could be a way to prolong the replacement cycle. Organic photovoltaics (OPVs) are a class of emerging photovoltaics, which are now becoming more practical with recently developed device and material engineering. The absorption of OPVs using a non-fullerene acceptor (NFA) could be extended to the near-infrared (NIR) region to cover the transmission window of human skin between 650 and 1000 nm. Motivated by this, we conducted a study of NFA-based OPVs under light irradiation of wavelengths of 650–1000 nm for implants. The devices using donor (PTB7-Th) and NFA (IEICO-4F) as the active material have strong absorption in the NIR region and obtained a promising power conversion efficiency (PCE) of 14.3% under the implant light illumination, compared to 8.11% when using a benchmark fullerene derivative-based acceptor (PC71BM). Importantly, the PCE and power density of the NFA-based OPVs are significantly higher than the previously reported fullerene-based OPVs devices. 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spelling v2 63147 2023-04-14 High performance non-fullerene organic photovoltaics under implant light illumination region 350d1f64ddd9787a6eda98611dcbb8d2 0000-0003-3109-1278 Ram Datt Ram Datt true false 0ef65494d0dda7f6aea5ead8bb6ce466 Harrison Lee Harrison Lee true false 801454eb7d42eeb5165b73fb362381ee Michael Spence Michael Spence true false 73b367694366a646b90bb15db32bb8c0 0000-0002-4232-1967 Matt Carnie Matt Carnie true false 7e5f541df6635a9a8e1a579ff2de5d56 0000-0003-3836-5139 Wing Chung Tsoi Wing Chung Tsoi true false 2023-04-14 MTLS Implantable biomedical electronics, such as pacemakers, drug pumps, cochlear implants, cardioverter-defibrillators, and neurological stimulators, help humans to overcome various diseases. Currently, the power supply for these devices relies on small-size batteries, and replacement of the battery is required after running for a period of time. Recharging the battery could be a way to prolong the replacement cycle. Organic photovoltaics (OPVs) are a class of emerging photovoltaics, which are now becoming more practical with recently developed device and material engineering. The absorption of OPVs using a non-fullerene acceptor (NFA) could be extended to the near-infrared (NIR) region to cover the transmission window of human skin between 650 and 1000 nm. Motivated by this, we conducted a study of NFA-based OPVs under light irradiation of wavelengths of 650–1000 nm for implants. The devices using donor (PTB7-Th) and NFA (IEICO-4F) as the active material have strong absorption in the NIR region and obtained a promising power conversion efficiency (PCE) of 14.3% under the implant light illumination, compared to 8.11% when using a benchmark fullerene derivative-based acceptor (PC71BM). Importantly, the PCE and power density of the NFA-based OPVs are significantly higher than the previously reported fullerene-based OPVs devices. This study shows that NFA-based OPVs have high potential for future applications in powering implants, e.g., through charging batteries. Journal Article Applied Physics Letters 122 14 143906 AIP Publishing 0003-6951 1077-3118 3 4 2023 2023-04-03 10.1063/5.0144861 http://dx.doi.org/10.1063/5.0144861 COLLEGE NANME Materials Science and Engineering COLLEGE CODE MTLS Swansea University We are very grateful to the SPECIFIC Innovation and Knowledge Center (No. EP/N020863/1), EPSRC ICASE (No. EP/S513714/1), and the Welsh European Funding Office (SPARC II) grants for providing financial support. 2023-05-18T14:13:20.4312274 2023-04-14T10:05:05.8949494 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Ram Datt 0000-0003-3109-1278 1 Harrison Lee 2 Michael Spence 3 Matt Carnie 0000-0002-4232-1967 4 Wing Chung Tsoi 0000-0003-3836-5139 5 63147__27042__af1e12a75d114de3984e895db661f92e.pdf 63147.pdf 2023-04-14T10:12:49.2974941 Output 2412093 application/pdf Version of Record true false
title High performance non-fullerene organic photovoltaics under implant light illumination region
spellingShingle High performance non-fullerene organic photovoltaics under implant light illumination region
Ram Datt
Harrison Lee
Michael Spence
Matt Carnie
Wing Chung Tsoi
title_short High performance non-fullerene organic photovoltaics under implant light illumination region
title_full High performance non-fullerene organic photovoltaics under implant light illumination region
title_fullStr High performance non-fullerene organic photovoltaics under implant light illumination region
title_full_unstemmed High performance non-fullerene organic photovoltaics under implant light illumination region
title_sort High performance non-fullerene organic photovoltaics under implant light illumination region
author_id_str_mv 350d1f64ddd9787a6eda98611dcbb8d2
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7e5f541df6635a9a8e1a579ff2de5d56
author_id_fullname_str_mv 350d1f64ddd9787a6eda98611dcbb8d2_***_Ram Datt
0ef65494d0dda7f6aea5ead8bb6ce466_***_Harrison Lee
801454eb7d42eeb5165b73fb362381ee_***_Michael Spence
73b367694366a646b90bb15db32bb8c0_***_Matt Carnie
7e5f541df6635a9a8e1a579ff2de5d56_***_Wing Chung Tsoi
author Ram Datt
Harrison Lee
Michael Spence
Matt Carnie
Wing Chung Tsoi
author2 Ram Datt
Harrison Lee
Michael Spence
Matt Carnie
Wing Chung Tsoi
format Journal article
container_title Applied Physics Letters
container_volume 122
container_issue 14
container_start_page 143906
publishDate 2023
institution Swansea University
issn 0003-6951
1077-3118
doi_str_mv 10.1063/5.0144861
publisher AIP Publishing
college_str Faculty of Science and Engineering
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hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
url http://dx.doi.org/10.1063/5.0144861
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description Implantable biomedical electronics, such as pacemakers, drug pumps, cochlear implants, cardioverter-defibrillators, and neurological stimulators, help humans to overcome various diseases. Currently, the power supply for these devices relies on small-size batteries, and replacement of the battery is required after running for a period of time. Recharging the battery could be a way to prolong the replacement cycle. Organic photovoltaics (OPVs) are a class of emerging photovoltaics, which are now becoming more practical with recently developed device and material engineering. The absorption of OPVs using a non-fullerene acceptor (NFA) could be extended to the near-infrared (NIR) region to cover the transmission window of human skin between 650 and 1000 nm. Motivated by this, we conducted a study of NFA-based OPVs under light irradiation of wavelengths of 650–1000 nm for implants. The devices using donor (PTB7-Th) and NFA (IEICO-4F) as the active material have strong absorption in the NIR region and obtained a promising power conversion efficiency (PCE) of 14.3% under the implant light illumination, compared to 8.11% when using a benchmark fullerene derivative-based acceptor (PC71BM). Importantly, the PCE and power density of the NFA-based OPVs are significantly higher than the previously reported fullerene-based OPVs devices. This study shows that NFA-based OPVs have high potential for future applications in powering implants, e.g., through charging batteries.
published_date 2023-04-03T14:13:19Z
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