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Photonic sintering of copper for rapid processing of thick film conducting circuits on FTO coated glass
Scientific Reports, Volume: 13, Issue: 1
Swansea University Authors: Bahaa Abbas, Eifion Jewell , Justin Searle , Tim Claypole
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DOI (Published version): 10.1038/s41598-023-32044-2
Abstract
Copper potentially provides a cost-effective replacement for silver in printed electronic circuitry with diverse applications in healthcare, solar energy, IOT devices and automotive applications. The primary challenge facing copper is that it readily oxidizes to its non-conductive state during the s...
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ISSN: | 2045-2322 |
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Springer Science and Business Media LLC
2023
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The primary challenge facing copper is that it readily oxidizes to its non-conductive state during the sintering process. Photonic sintering offers a means of overcoming the oxidation by which rapid conversion from discrete nano-micro particles to fully or partially sintered products occurs. An experimental study of flash lamp sintering of mixed nano copper and mixed nano/ micro copper thick film screen printed structures on FTO coated glass was carried out. It shows that there may be multiple energy windows which can successfully sinter the thick film copper print preventing detrimental copper oxidation. Under optimum conditions, the conductivities achieved in under 1 s was (3.11–4.3 × 10–7 Ω m) matched those achieved in 90 min at 250 °C under reducing gas conditions, offering a significant improvement in productivity and reduced energy demand. 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v2 63055 2023-03-31 Photonic sintering of copper for rapid processing of thick film conducting circuits on FTO coated glass 70f72a44d3b1b045e0473147441a80d2 Bahaa Abbas Bahaa Abbas true false 13dc152c178d51abfe0634445b0acf07 0000-0002-6894-2251 Eifion Jewell Eifion Jewell true false 0e3f2c3812f181eaed11c45554d4cdd0 0000-0003-1101-075X Justin Searle Justin Searle true false 7735385522f1e68a8775b4f709e91d55 0000-0003-1393-9634 Tim Claypole Tim Claypole true false 2023-03-31 Copper potentially provides a cost-effective replacement for silver in printed electronic circuitry with diverse applications in healthcare, solar energy, IOT devices and automotive applications. The primary challenge facing copper is that it readily oxidizes to its non-conductive state during the sintering process. Photonic sintering offers a means of overcoming the oxidation by which rapid conversion from discrete nano-micro particles to fully or partially sintered products occurs. An experimental study of flash lamp sintering of mixed nano copper and mixed nano/ micro copper thick film screen printed structures on FTO coated glass was carried out. It shows that there may be multiple energy windows which can successfully sinter the thick film copper print preventing detrimental copper oxidation. Under optimum conditions, the conductivities achieved in under 1 s was (3.11–4.3 × 10–7 Ω m) matched those achieved in 90 min at 250 °C under reducing gas conditions, offering a significant improvement in productivity and reduced energy demand. Also present a good film stability of a 14% increase in line resistance of 100 N material, around 10% for the 50N50M ink and only around 2% for the 20N80M. Journal Article Scientific Reports 13 1 Springer Science and Business Media LLC 2045-2322 28 3 2023 2023-03-28 10.1038/s41598-023-32044-2 COLLEGE NANME COLLEGE CODE Swansea University External research funder(s) paid the OA fee (includes OA grants disbursed by the Library) EP/N509905/1 2024-10-18T16:53:16.1423726 2023-03-31T13:36:29.8662316 Faculty of Science and Engineering School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Mechanical Engineering Bahaa Abbas 1 Eifion Jewell 0000-0002-6894-2251 2 Yin Cheung Lau 3 Justin Searle 0000-0003-1101-075X 4 Tim Claypole 0000-0003-1393-9634 5 63055__26985__4fb9d0c0f84d47089b382d48049bab52.pdf 63055.pdf 2023-04-05T09:14:46.6187252 Output 5595179 application/pdf Version of Record true This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. false eng http://creativecommons.org/licenses/by/4.0/ |
title |
Photonic sintering of copper for rapid processing of thick film conducting circuits on FTO coated glass |
spellingShingle |
Photonic sintering of copper for rapid processing of thick film conducting circuits on FTO coated glass Bahaa Abbas Eifion Jewell Justin Searle Tim Claypole |
title_short |
Photonic sintering of copper for rapid processing of thick film conducting circuits on FTO coated glass |
title_full |
Photonic sintering of copper for rapid processing of thick film conducting circuits on FTO coated glass |
title_fullStr |
Photonic sintering of copper for rapid processing of thick film conducting circuits on FTO coated glass |
title_full_unstemmed |
Photonic sintering of copper for rapid processing of thick film conducting circuits on FTO coated glass |
title_sort |
Photonic sintering of copper for rapid processing of thick film conducting circuits on FTO coated glass |
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70f72a44d3b1b045e0473147441a80d2 13dc152c178d51abfe0634445b0acf07 0e3f2c3812f181eaed11c45554d4cdd0 7735385522f1e68a8775b4f709e91d55 |
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70f72a44d3b1b045e0473147441a80d2_***_Bahaa Abbas 13dc152c178d51abfe0634445b0acf07_***_Eifion Jewell 0e3f2c3812f181eaed11c45554d4cdd0_***_Justin Searle 7735385522f1e68a8775b4f709e91d55_***_Tim Claypole |
author |
Bahaa Abbas Eifion Jewell Justin Searle Tim Claypole |
author2 |
Bahaa Abbas Eifion Jewell Yin Cheung Lau Justin Searle Tim Claypole |
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10.1038/s41598-023-32044-2 |
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Copper potentially provides a cost-effective replacement for silver in printed electronic circuitry with diverse applications in healthcare, solar energy, IOT devices and automotive applications. The primary challenge facing copper is that it readily oxidizes to its non-conductive state during the sintering process. Photonic sintering offers a means of overcoming the oxidation by which rapid conversion from discrete nano-micro particles to fully or partially sintered products occurs. An experimental study of flash lamp sintering of mixed nano copper and mixed nano/ micro copper thick film screen printed structures on FTO coated glass was carried out. It shows that there may be multiple energy windows which can successfully sinter the thick film copper print preventing detrimental copper oxidation. Under optimum conditions, the conductivities achieved in under 1 s was (3.11–4.3 × 10–7 Ω m) matched those achieved in 90 min at 250 °C under reducing gas conditions, offering a significant improvement in productivity and reduced energy demand. Also present a good film stability of a 14% increase in line resistance of 100 N material, around 10% for the 50N50M ink and only around 2% for the 20N80M. |
published_date |
2023-03-28T16:53:13Z |
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11.037603 |