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Renormalized Flory‐Huggins lattice model of physicochemical kinetics and dynamic complexity in self‐healing double‐network hydrogel

Ziyu Xing, Haibao Lu, Mokarram Hossain Orcid Logo

Journal of Applied Polymer Science, Volume: 138, Issue: 17, Start page: 50304

Swansea University Author: Mokarram Hossain Orcid Logo

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DOI (Published version): 10.1002/app.50304

Abstract

Self‐healing capability offers great designability on mechanical properties of double‐network (DN) hydrogel. However, the thermodynamics understanding behind such physicochemical transitions and self‐healing behaviors are yet to be explored properly. This study describes a renormalized Flory‐Huggins...

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Published in: Journal of Applied Polymer Science
ISSN: 0021-8995 1097-4628
Published: Wiley 2021
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URI: https://cronfa.swan.ac.uk/Record/cronfa55753
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spelling 2021-05-01T12:06:31.1312406 v2 55753 2020-11-25 Renormalized Flory‐Huggins lattice model of physicochemical kinetics and dynamic complexity in self‐healing double‐network hydrogel 140f4aa5c5ec18ec173c8542a7fddafd 0000-0002-4616-1104 Mokarram Hossain Mokarram Hossain true false 2020-11-25 GENG Self‐healing capability offers great designability on mechanical properties of double‐network (DN) hydrogel. However, the thermodynamics understanding behind such physicochemical transitions and self‐healing behaviors are yet to be explored properly. This study describes a renormalized Flory‐Huggins lattice model for DN hydrogels, of which the physicochemical kinetics and dynamic complexity are resulted from stress‐induced bond scission and macromolecule rearrangement. Based on the Flory‐Huggins lattice model and Gaussian distribution theory, an extended free‐energy model was formulated by the steric repulsive free‐energy function. Afterwards, the function was used to identify the working mechanisms and thermodynamics in self‐healing DN hydrogels with ultra‐high mechanical strength. Finally, the effectiveness of model was demonstrated by applying it to predict the mechanical behaviors of DN hydrogels, where the analytical results showed good agreements with experiment data. Journal Article Journal of Applied Polymer Science 138 17 50304 Wiley 0021-8995 1097-4628 kinetics; stimuli‐sensitive polymers; theory and modeling 5 5 2021 2021-05-05 10.1002/app.50304 COLLEGE NANME General Engineering COLLEGE CODE GENG Swansea University 2021-05-01T12:06:31.1312406 2020-11-25T10:32:47.6486008 Faculty of Science and Engineering School of Aerospace, Civil, Electrical, General and Mechanical Engineering - General Engineering Ziyu Xing 1 Haibao Lu 2 Mokarram Hossain 0000-0002-4616-1104 3 55753__18743__807829b7de9a43c3b8a984b6e1edb8fe.pdf 55753.pdf 2020-11-25T10:35:16.9891958 Output 2688187 application/pdf Accepted Manuscript true 2021-11-24T00:00:00.0000000 true eng http://creativecommons.org/licenses/by-nc-nd/4.0/
title Renormalized Flory‐Huggins lattice model of physicochemical kinetics and dynamic complexity in self‐healing double‐network hydrogel
spellingShingle Renormalized Flory‐Huggins lattice model of physicochemical kinetics and dynamic complexity in self‐healing double‐network hydrogel
Mokarram Hossain
title_short Renormalized Flory‐Huggins lattice model of physicochemical kinetics and dynamic complexity in self‐healing double‐network hydrogel
title_full Renormalized Flory‐Huggins lattice model of physicochemical kinetics and dynamic complexity in self‐healing double‐network hydrogel
title_fullStr Renormalized Flory‐Huggins lattice model of physicochemical kinetics and dynamic complexity in self‐healing double‐network hydrogel
title_full_unstemmed Renormalized Flory‐Huggins lattice model of physicochemical kinetics and dynamic complexity in self‐healing double‐network hydrogel
title_sort Renormalized Flory‐Huggins lattice model of physicochemical kinetics and dynamic complexity in self‐healing double‐network hydrogel
author_id_str_mv 140f4aa5c5ec18ec173c8542a7fddafd
author_id_fullname_str_mv 140f4aa5c5ec18ec173c8542a7fddafd_***_Mokarram Hossain
author Mokarram Hossain
author2 Ziyu Xing
Haibao Lu
Mokarram Hossain
format Journal article
container_title Journal of Applied Polymer Science
container_volume 138
container_issue 17
container_start_page 50304
publishDate 2021
institution Swansea University
issn 0021-8995
1097-4628
doi_str_mv 10.1002/app.50304
publisher Wiley
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Aerospace, Civil, Electrical, General and Mechanical Engineering - General Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Aerospace, Civil, Electrical, General and Mechanical Engineering - General Engineering
document_store_str 1
active_str 0
description Self‐healing capability offers great designability on mechanical properties of double‐network (DN) hydrogel. However, the thermodynamics understanding behind such physicochemical transitions and self‐healing behaviors are yet to be explored properly. This study describes a renormalized Flory‐Huggins lattice model for DN hydrogels, of which the physicochemical kinetics and dynamic complexity are resulted from stress‐induced bond scission and macromolecule rearrangement. Based on the Flory‐Huggins lattice model and Gaussian distribution theory, an extended free‐energy model was formulated by the steric repulsive free‐energy function. Afterwards, the function was used to identify the working mechanisms and thermodynamics in self‐healing DN hydrogels with ultra‐high mechanical strength. Finally, the effectiveness of model was demonstrated by applying it to predict the mechanical behaviors of DN hydrogels, where the analytical results showed good agreements with experiment data.
published_date 2021-05-05T04:10:11Z
_version_ 1763753707960270848
score 11.037056

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