Recent progress, fabrication challenges and stability issues of lead-free tin-based perovskite thin films in the field of photovoltaics

Mahajan, Prerna; Datt, Ram; Tsoi, Wing Chung; Gupta, Vinay; Tomar, Amit; Arya, Sandeep

doi:10.1016/j.ccr.2020.213633

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Recent progress, fabrication challenges and stability issues of lead-free tin-based perovskite thin films in the field of photovoltaics

Prerna Mahajan, Ram Datt

, Wing Chung Tsoi

, Vinay Gupta, Amit Tomar, Sandeep Arya

Coordination Chemistry Reviews, Volume: 429, Start page: 213633

Swansea University Authors: Ram Datt , Wing Chung Tsoi

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DOI (Published version): 10.1016/j.ccr.2020.213633

Abstract

Lead-halide perovskite materials have fascinated incredible attention among the research communities due to their favorable electrical and optical properties for optoelectronics and photovoltaic application such as significant light absorption coefficient, higher values of diffusion length, carrier...

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Published in:	Coordination Chemistry Reviews
ISSN:	0010-8545
Published:	Elsevier BV 2021
Online Access:	Check full text
URI:	https://cronfa.swan.ac.uk/Record/cronfa55557
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first_indexed	2020-10-29T14:01:14Z
last_indexed	2021-01-09T04:18:54Z
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spelling	v2 55557 2020-10-29 Recent progress, fabrication challenges and stability issues of lead-free tin-based perovskite thin films in the field of photovoltaics 350d1f64ddd9787a6eda98611dcbb8d2 0000-0003-3109-1278 Ram Datt Ram Datt true false 7e5f541df6635a9a8e1a579ff2de5d56 0000-0003-3836-5139 Wing Chung Tsoi Wing Chung Tsoi true false 2020-10-29 MTLS Lead-halide perovskite materials have fascinated incredible attention among the research communities due to their favorable electrical and optical properties for optoelectronics and photovoltaic application such as significant light absorption coefficient, higher values of diffusion length, carrier mobility, carrier lifetime, etc. However, lead toxicity as well as its low material stability makes it still far from commercialization. Finding of lead ion replacement is therefore needed to form environmental friendly perovskite materials that are called lead-free perovskites. Among different substitutions, tin is the most potential candidate that is also non-toxic. In this review, the recent development of tin-based lead-free perovskite thin films in photovoltaics research area during the period 2014 till now is summarized. Moreover, the technical challenges and the stability issues faced by them are also discussed. Further, it is suggested that more efforts are needed for the advancement of tin-based lead-free perovskite thin films based solar cells to bring up this field as a cost competent technology for long term sustainability. Journal Article Coordination Chemistry Reviews 429 213633 Elsevier BV 0010-8545 Perovskites, Tin-based perovskites, Lead-free perovskites, Photovoltaics, Solar cells 1 2 2021 2021-02-01 10.1016/j.ccr.2020.213633 http://dx.doi.org/10.1016/j.ccr.2020.213633 COLLEGE NANME Materials Science and Engineering COLLEGE CODE MTLS Swansea University 2023-06-02T15:37:56.9817294 2020-10-29T13:58:16.7810935 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Prerna Mahajan 1 Ram Datt 0000-0003-3109-1278 2 Wing Chung Tsoi 0000-0003-3836-5139 3 Vinay Gupta 4 Amit Tomar 5 Sandeep Arya 6 55557__18532__44566c04dfc74b4287634e09f6b6c143.pdf 55557.pdf 2020-10-29T14:00:35.5083793 Output 2604421 application/pdf Accepted Manuscript true 2021-10-22T00:00:00.0000000 © 2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license true eng http://creativecommons.org/licenses/by-nc-nd/4.0/
title	Recent progress, fabrication challenges and stability issues of lead-free tin-based perovskite thin films in the field of photovoltaics
spellingShingle	Recent progress, fabrication challenges and stability issues of lead-free tin-based perovskite thin films in the field of photovoltaics Ram Datt Wing Chung Tsoi
title_short	Recent progress, fabrication challenges and stability issues of lead-free tin-based perovskite thin films in the field of photovoltaics
title_full	Recent progress, fabrication challenges and stability issues of lead-free tin-based perovskite thin films in the field of photovoltaics
title_fullStr	Recent progress, fabrication challenges and stability issues of lead-free tin-based perovskite thin films in the field of photovoltaics
title_full_unstemmed	Recent progress, fabrication challenges and stability issues of lead-free tin-based perovskite thin films in the field of photovoltaics
title_sort	Recent progress, fabrication challenges and stability issues of lead-free tin-based perovskite thin films in the field of photovoltaics
author_id_str_mv	350d1f64ddd9787a6eda98611dcbb8d2 7e5f541df6635a9a8e1a579ff2de5d56
author_id_fullname_str_mv	350d1f64ddd9787a6eda98611dcbb8d2_*_Ram Datt 7e5f541df6635a9a8e1a579ff2de5d56_*_Wing Chung Tsoi
author	Ram Datt Wing Chung Tsoi
author2	Prerna Mahajan Ram Datt Wing Chung Tsoi Vinay Gupta Amit Tomar Sandeep Arya
format	Journal article
container_title	Coordination Chemistry Reviews
container_volume	429
container_start_page	213633
publishDate	2021
institution	Swansea University
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url	http://dx.doi.org/10.1016/j.ccr.2020.213633
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description	Lead-halide perovskite materials have fascinated incredible attention among the research communities due to their favorable electrical and optical properties for optoelectronics and photovoltaic application such as significant light absorption coefficient, higher values of diffusion length, carrier mobility, carrier lifetime, etc. However, lead toxicity as well as its low material stability makes it still far from commercialization. Finding of lead ion replacement is therefore needed to form environmental friendly perovskite materials that are called lead-free perovskites. Among different substitutions, tin is the most potential candidate that is also non-toxic. In this review, the recent development of tin-based lead-free perovskite thin films in photovoltaics research area during the period 2014 till now is summarized. Moreover, the technical challenges and the stability issues faced by them are also discussed. Further, it is suggested that more efforts are needed for the advancement of tin-based lead-free perovskite thin films based solar cells to bring up this field as a cost competent technology for long term sustainability.
published_date	2021-02-01T15:37:55Z
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Recent progress, fabrication challenges and stability issues of lead-free tin-based perovskite thin films in the field of photovoltaics

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