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Cooperative dynamics of heuristic swelling and inhibitive micellization in double-network hydrogels by ionic dissociation of polyelectrolyte

Ziyu Xing, Haibao Lu, Mokarram Hossain Orcid Logo, Yong Qing Fu, Jinsong Leng, Shanyi Du

Polymer, Volume: 186, Start page: 122039

Swansea University Author: Mokarram Hossain Orcid Logo

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DOI (Published version): 10.1016/j.polymer.2019.122039

Abstract

In this study, a cooperative model has been proposed for the double network (DN) hydrogel, which synchronously undergoes heuristic swelling and inhibitive micellization by the ionic dissociation of polyelectrolyte. Flory-Huggins solution theory is initially employed to identify the working mechanism...

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Published in: Polymer
ISSN: 0032-3861
Published: Elsevier BV 2020
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URI: https://cronfa.swan.ac.uk/Record/cronfa52910
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first_indexed 2019-11-30T04:14:07Z
last_indexed 2020-12-15T04:14:56Z
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spelling 2020-12-14T16:31:06.4781254 v2 52910 2019-11-29 Cooperative dynamics of heuristic swelling and inhibitive micellization in double-network hydrogels by ionic dissociation of polyelectrolyte 140f4aa5c5ec18ec173c8542a7fddafd 0000-0002-4616-1104 Mokarram Hossain Mokarram Hossain true false 2019-11-29 GENG In this study, a cooperative model has been proposed for the double network (DN) hydrogel, which synchronously undergoes heuristic swelling and inhibitive micellization by the ionic dissociation of polyelectrolyte. Flory-Huggins solution theory is initially employed to identify the working mechanism of dielectric constants on swelling behavior of the DN hydrogel. Then a free-energy function is introduced to formulate the constitutive relationship of the DN hydrogels, in which the first hydrotropic network undergoes a heuristic swelling and the second hydrophobic network undergoes an inhibitive micellization. Finally, the proposed model has been verified using the experimental results reported in the literature. A good agreement between the theoretical results and experimental ones has been achieved. This study provides a fundamental approach to formulate the constitutive relationship and to understand the cooperative dynamics of two types of networks in DN hydrogels induced by the polyelectrolyte. Journal Article Polymer 186 122039 Elsevier BV 0032-3861 Double network (DN) hydrogels, ionic dissociation, free energy function 9 1 2020 2020-01-09 10.1016/j.polymer.2019.122039 COLLEGE NANME General Engineering COLLEGE CODE GENG Swansea University 2020-12-14T16:31:06.4781254 2019-11-29T18:24:00.5117110 Faculty of Science and Engineering School of Aerospace, Civil, Electrical, General and Mechanical Engineering - General Engineering Ziyu Xing 1 Haibao Lu 2 Mokarram Hossain 0000-0002-4616-1104 3 Yong Qing Fu 4 Jinsong Leng 5 Shanyi Du 6 52910__16006__f01f5f5ecb2d4f908bbd95b5ad94eae7.pdf xing2019.pdf 2019-12-02T10:03:03.7877157 Output 2212483 application/pdf Accepted Manuscript true 2020-11-29T00:00:00.0000000 ©2019 All rights reserved. All article content, except where otherwise noted, is licensed under a Creative Commons Attribution Non-Commercial No Derivatives License (CC-BY-NC-ND) true eng http://creativecommons.org/licenses/by-nc-nd/4.0/
title Cooperative dynamics of heuristic swelling and inhibitive micellization in double-network hydrogels by ionic dissociation of polyelectrolyte
spellingShingle Cooperative dynamics of heuristic swelling and inhibitive micellization in double-network hydrogels by ionic dissociation of polyelectrolyte
Mokarram Hossain
title_short Cooperative dynamics of heuristic swelling and inhibitive micellization in double-network hydrogels by ionic dissociation of polyelectrolyte
title_full Cooperative dynamics of heuristic swelling and inhibitive micellization in double-network hydrogels by ionic dissociation of polyelectrolyte
title_fullStr Cooperative dynamics of heuristic swelling and inhibitive micellization in double-network hydrogels by ionic dissociation of polyelectrolyte
title_full_unstemmed Cooperative dynamics of heuristic swelling and inhibitive micellization in double-network hydrogels by ionic dissociation of polyelectrolyte
title_sort Cooperative dynamics of heuristic swelling and inhibitive micellization in double-network hydrogels by ionic dissociation of polyelectrolyte
author_id_str_mv 140f4aa5c5ec18ec173c8542a7fddafd
author_id_fullname_str_mv 140f4aa5c5ec18ec173c8542a7fddafd_***_Mokarram Hossain
author Mokarram Hossain
author2 Ziyu Xing
Haibao Lu
Mokarram Hossain
Yong Qing Fu
Jinsong Leng
Shanyi Du
format Journal article
container_title Polymer
container_volume 186
container_start_page 122039
publishDate 2020
institution Swansea University
issn 0032-3861
doi_str_mv 10.1016/j.polymer.2019.122039
publisher Elsevier BV
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Aerospace, Civil, Electrical, General and Mechanical Engineering - General Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Aerospace, Civil, Electrical, General and Mechanical Engineering - General Engineering
document_store_str 1
active_str 0
description In this study, a cooperative model has been proposed for the double network (DN) hydrogel, which synchronously undergoes heuristic swelling and inhibitive micellization by the ionic dissociation of polyelectrolyte. Flory-Huggins solution theory is initially employed to identify the working mechanism of dielectric constants on swelling behavior of the DN hydrogel. Then a free-energy function is introduced to formulate the constitutive relationship of the DN hydrogels, in which the first hydrotropic network undergoes a heuristic swelling and the second hydrophobic network undergoes an inhibitive micellization. Finally, the proposed model has been verified using the experimental results reported in the literature. A good agreement between the theoretical results and experimental ones has been achieved. This study provides a fundamental approach to formulate the constitutive relationship and to understand the cooperative dynamics of two types of networks in DN hydrogels induced by the polyelectrolyte.
published_date 2020-01-09T04:05:34Z
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score 11.037056

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