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Study of all solid-state rechargeable fluoride ion batteries based on thin-film electrolyte

Le Zhang, Anji Munnangi Orcid Logo, Ping Gao, Thomas Diemant, R. Jürgen Behm, Maximilian Fichtner

Journal of Solid State Electrochemistry, Volume: 21, Issue: 5, Pages: 1243 - 1251

Swansea University Author: Anji Munnangi Orcid Logo

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DOI (Published version): 10.1007/s10008-016-3479-x

Abstract

In this work, a solid-state fluoride ion battery based on a thin-film electrolyte with 10 μm thickness was built and tested. The electrochemical performance was examined using Bi or Cu metals as the active cathode materials and MgF2 as the active anode material, respectively. X-ray diffraction and X...

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Published in: Journal of Solid State Electrochemistry
ISSN: 1432-8488 1433-0768
Published: Springer Science and Business Media LLC 2017
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URI: https://cronfa.swan.ac.uk/Record/cronfa51575
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first_indexed 2019-08-27T15:30:58Z
last_indexed 2019-09-04T14:49:34Z
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spelling 2019-09-04T11:09:15.3819762 v2 51575 2019-08-27 Study of all solid-state rechargeable fluoride ion batteries based on thin-film electrolyte 3ed0b4f2ff4fb9e87c7a73e7a3c39da7 0000-0001-9101-0252 Anji Munnangi Anji Munnangi true false 2019-08-27 MTLS In this work, a solid-state fluoride ion battery based on a thin-film electrolyte with 10 μm thickness was built and tested. The electrochemical performance was examined using Bi or Cu metals as the active cathode materials and MgF2 as the active anode material, respectively. X-ray diffraction and X-ray photoelectron spectroscopy data showed that the charge transfer ions between the cathode and anode were fluoride ions. Initial discharge capacities of 66 and 76 mAh g−1 were obtained at 160 °C when Bi and Cu were used as cathodes, respectively. Furthermore, this type of fluoride ion battery was rechargeable, but the capacity faded during the subsequent cycles, similar to the bulk-type systems. Journal Article Journal of Solid State Electrochemistry 21 5 1243 1251 Springer Science and Business Media LLC 1432-8488 1433-0768 fluoride ion battery, thin-film electrolyte, all solid-state battery, spin-coating technique 31 5 2017 2017-05-31 10.1007/s10008-016-3479-x COLLEGE NANME Materials Science and Engineering COLLEGE CODE MTLS Swansea University 2019-09-04T11:09:15.3819762 2019-08-27T12:21:41.6445752 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Le Zhang 1 Anji Munnangi 0000-0001-9101-0252 2 Ping Gao 3 Thomas Diemant 4 R. Jürgen Behm 5 Maximilian Fichtner 6
title Study of all solid-state rechargeable fluoride ion batteries based on thin-film electrolyte
spellingShingle Study of all solid-state rechargeable fluoride ion batteries based on thin-film electrolyte
Anji Munnangi
title_short Study of all solid-state rechargeable fluoride ion batteries based on thin-film electrolyte
title_full Study of all solid-state rechargeable fluoride ion batteries based on thin-film electrolyte
title_fullStr Study of all solid-state rechargeable fluoride ion batteries based on thin-film electrolyte
title_full_unstemmed Study of all solid-state rechargeable fluoride ion batteries based on thin-film electrolyte
title_sort Study of all solid-state rechargeable fluoride ion batteries based on thin-film electrolyte
author_id_str_mv 3ed0b4f2ff4fb9e87c7a73e7a3c39da7
author_id_fullname_str_mv 3ed0b4f2ff4fb9e87c7a73e7a3c39da7_***_Anji Munnangi
author Anji Munnangi
author2 Le Zhang
Anji Munnangi
Ping Gao
Thomas Diemant
R. Jürgen Behm
Maximilian Fichtner
format Journal article
container_title Journal of Solid State Electrochemistry
container_volume 21
container_issue 5
container_start_page 1243
publishDate 2017
institution Swansea University
issn 1432-8488
1433-0768
doi_str_mv 10.1007/s10008-016-3479-x
publisher Springer Science and Business Media LLC
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
document_store_str 0
active_str 0
description In this work, a solid-state fluoride ion battery based on a thin-film electrolyte with 10 μm thickness was built and tested. The electrochemical performance was examined using Bi or Cu metals as the active cathode materials and MgF2 as the active anode material, respectively. X-ray diffraction and X-ray photoelectron spectroscopy data showed that the charge transfer ions between the cathode and anode were fluoride ions. Initial discharge capacities of 66 and 76 mAh g−1 were obtained at 160 °C when Bi and Cu were used as cathodes, respectively. Furthermore, this type of fluoride ion battery was rechargeable, but the capacity faded during the subsequent cycles, similar to the bulk-type systems.
published_date 2017-05-31T04:03:31Z
_version_ 1763753287903870976
score 11.013731

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