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Study of all solid-state rechargeable fluoride ion batteries based on thin-film electrolyte

Le Zhang, Anji Munnangi Orcid Logo, Ping Gao, Thomas Diemant, R. Jürgen Behm, Maximilian Fichtner

Journal of Solid State Electrochemistry, Volume: 21, Issue: 5, Pages: 1243 - 1251

Swansea University Author: Anji Munnangi Orcid Logo

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Abstract

In this work, a solid-state fluoride ion battery based on a thin-film electrolyte with 10 μm thickness was built and tested. The electrochemical performance was examined using Bi or Cu metals as the active cathode materials and MgF2 as the active anode material, respectively. X-ray diffraction and X...

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Published in: Journal of Solid State Electrochemistry
ISSN: 1432-8488 1433-0768
Published: Springer Science and Business Media LLC 2017
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa51575
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Abstract: In this work, a solid-state fluoride ion battery based on a thin-film electrolyte with 10 μm thickness was built and tested. The electrochemical performance was examined using Bi or Cu metals as the active cathode materials and MgF2 as the active anode material, respectively. X-ray diffraction and X-ray photoelectron spectroscopy data showed that the charge transfer ions between the cathode and anode were fluoride ions. Initial discharge capacities of 66 and 76 mAh g−1 were obtained at 160 °C when Bi and Cu were used as cathodes, respectively. Furthermore, this type of fluoride ion battery was rechargeable, but the capacity faded during the subsequent cycles, similar to the bulk-type systems.
Keywords: fluoride ion battery, thin-film electrolyte, all solid-state battery, spin-coating technique
College: Faculty of Science and Engineering
Issue: 5
Start Page: 1243
End Page: 1251