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Flame assisted chemical vapour deposition NiO hole transport layers for mesoporous carbon perovskite cells

Heather M. Yates, Simone M. P. Meroni, Dimitrios Raptis, John L. Hodgkinson, Trystan Watson Orcid Logo

Journal of Materials Chemistry C, Volume: 7, Issue: 42, Pages: 13235 - 13242

Swansea University Author: Trystan Watson Orcid Logo

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DOI (Published version): 10.1039/c9tc03922h

Abstract

Flame assisted chemical vapour deposition was utilised to directly deposit polycrystalline mesoporous NiO to enhance charge transport within carbon perovskite solar cells (C-PSC). This versatile technique is highly suited for deposition of large area thin films along with the ability to use simple,...

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Published in: Journal of Materials Chemistry C
ISSN: 2050-7526 2050-7534
Published: Royal Society of Chemistry (RSC) 2019
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URI: https://cronfa.swan.ac.uk/Record/cronfa51378
first_indexed 2019-08-12T15:30:21Z
last_indexed 2021-09-22T03:11:12Z
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spelling 2021-09-21T16:21:56.0297307 v2 51378 2019-08-12 Flame assisted chemical vapour deposition NiO hole transport layers for mesoporous carbon perovskite cells a210327b52472cfe8df9b8108d661457 0000-0002-8015-1436 Trystan Watson Trystan Watson true false 2019-08-12 EAAS Flame assisted chemical vapour deposition was utilised to directly deposit polycrystalline mesoporous NiO to enhance charge transport within carbon perovskite solar cells (C-PSC). This versatile technique is highly suited for deposition of large area thin films along with the ability to use simple, stable aqueous salts. The combination of low cost methods of screen printing and FACVD to produce the C-PSC make this an attractive route towards commercialisation. The effects of deposition parameters on the morphology, crystallinity and density of the deposited NiO are discussed, along with the importance of use of a low propane, ‘lean flame’ on both the NiO and underlying F-doped tin oxide electrode. The thickness of the NiO layer was found to be critical in optimising the C-PSC efficiency. Addition of the NiO layer resulted in an increased short circuit current density (17.30 mA cm−2 to 20.28 mA cm−2). At an estimated NiO thickness of 17 nm the average cell efficiency (10.73%) surpassed that of the control sample (9.08%) so confirming the promise of this technique. Journal Article Journal of Materials Chemistry C 7 42 13235 13242 Royal Society of Chemistry (RSC) 2050-7526 2050-7534 12 11 2019 2019-11-12 10.1039/c9tc03922h http://dx.doi.org/10.1039/c9tc03922h COLLEGE NANME Engineering and Applied Sciences School COLLEGE CODE EAAS Swansea University 2021-09-21T16:21:56.0297307 2019-08-12T12:04:31.9668551 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Heather M. Yates 1 Simone M. P. Meroni 2 Dimitrios Raptis 3 John L. Hodgkinson 4 Trystan Watson 0000-0002-8015-1436 5 51378__15859__68fd9165c0c04627be675f6ef5d496dc.pdf yates2019(2).pdf 2019-11-12T09:20:33.8528337 Output 3183840 application/pdf Version of Record true 2019-11-12T00:00:00.0000000 This article is licensed under a Creative Commons Attiribution 3.0 Unported Licence. (CC-BY) true eng http://creativecommons.org/licenses/by/3.0/
title Flame assisted chemical vapour deposition NiO hole transport layers for mesoporous carbon perovskite cells
spellingShingle Flame assisted chemical vapour deposition NiO hole transport layers for mesoporous carbon perovskite cells
Trystan Watson
title_short Flame assisted chemical vapour deposition NiO hole transport layers for mesoporous carbon perovskite cells
title_full Flame assisted chemical vapour deposition NiO hole transport layers for mesoporous carbon perovskite cells
title_fullStr Flame assisted chemical vapour deposition NiO hole transport layers for mesoporous carbon perovskite cells
title_full_unstemmed Flame assisted chemical vapour deposition NiO hole transport layers for mesoporous carbon perovskite cells
title_sort Flame assisted chemical vapour deposition NiO hole transport layers for mesoporous carbon perovskite cells
author_id_str_mv a210327b52472cfe8df9b8108d661457
author_id_fullname_str_mv a210327b52472cfe8df9b8108d661457_***_Trystan Watson
author Trystan Watson
author2 Heather M. Yates
Simone M. P. Meroni
Dimitrios Raptis
John L. Hodgkinson
Trystan Watson
format Journal article
container_title Journal of Materials Chemistry C
container_volume 7
container_issue 42
container_start_page 13235
publishDate 2019
institution Swansea University
issn 2050-7526
2050-7534
doi_str_mv 10.1039/c9tc03922h
publisher Royal Society of Chemistry (RSC)
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
url http://dx.doi.org/10.1039/c9tc03922h
document_store_str 1
active_str 0
description Flame assisted chemical vapour deposition was utilised to directly deposit polycrystalline mesoporous NiO to enhance charge transport within carbon perovskite solar cells (C-PSC). This versatile technique is highly suited for deposition of large area thin films along with the ability to use simple, stable aqueous salts. The combination of low cost methods of screen printing and FACVD to produce the C-PSC make this an attractive route towards commercialisation. The effects of deposition parameters on the morphology, crystallinity and density of the deposited NiO are discussed, along with the importance of use of a low propane, ‘lean flame’ on both the NiO and underlying F-doped tin oxide electrode. The thickness of the NiO layer was found to be critical in optimising the C-PSC efficiency. Addition of the NiO layer resulted in an increased short circuit current density (17.30 mA cm−2 to 20.28 mA cm−2). At an estimated NiO thickness of 17 nm the average cell efficiency (10.73%) surpassed that of the control sample (9.08%) so confirming the promise of this technique.
published_date 2019-11-12T07:47:04Z
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score 11.3254

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