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New Directions in Metal Phosphonate and Phosphinate Chemistry

Steve Shearan, Stephen J.I. Shearan, Norbert Stock, Franziska Emmerling, Jan Demel, Paul A. Wright, Konstantinos D. Demadis, Maria Vassaki, Ferdinando Costantino, Riccardo Vivani, Sébastien Sallard, Inés Ruiz Salcedo, Aurelio Cabeza, Marco Taddei Orcid Logo

Crystals, Volume: 9, Issue: 5, Start page: 270

Swansea University Authors: Steve Shearan, Marco Taddei Orcid Logo

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DOI (Published version): 10.3390/cryst9050270

Abstract

In September 2018, the First European Workshop on Metal Phosphonates Chemistry brought together some prominent researchers in the field of metal phosphonates and phosphinates with the aim of discussing past and current research efforts and identifying future directions. The scope of this perspective...

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Published in: Crystals
ISSN: 2073-4352
Published: 2019
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URI: https://cronfa.swan.ac.uk/Record/cronfa50572
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spelling 2019-07-18T16:30:51.0483151 v2 50572 2019-05-30 New Directions in Metal Phosphonate and Phosphinate Chemistry feed41db390519dc46cbc1365e86d35f Steve Shearan Steve Shearan true false 5cffd1038508554d8596dee8b4e51052 0000-0003-2805-6375 Marco Taddei Marco Taddei true false 2019-05-30 In September 2018, the First European Workshop on Metal Phosphonates Chemistry brought together some prominent researchers in the field of metal phosphonates and phosphinates with the aim of discussing past and current research efforts and identifying future directions. The scope of this perspective article is to provide a critical overview of the topics discussed during the workshop, which are divided into two main areas: synthesis and characterisation, and applications. In terms of synthetic methods, there has been a push towards cleaner and more efficient approaches. This has led to the introduction of high-throughput synthesis and mechanochemical synthesis. The recent success of metal–organic frameworks has also promoted renewed interest in the synthesis of porous metal phosphonates and phosphinates. Regarding characterisation, the main advances are the development of electron diffraction as a tool for crystal structure determination and the deployment of in situ characterisation techniques, which have allowed for a better understanding of reaction pathways. In terms of applications, metal phosphonates have been found to be suitable materials for several purposes: they have been employed as heterogeneous catalysts for the synthesis of fine chemicals, as solid sorbents for gas separation, notably CO2 capture, as materials for electrochemical devices, such as fuel cells and rechargeable batteries, and as matrices for drug delivery. Journal Article Crystals 9 5 270 2073-4352 metal phosphonates and phosphinates; layered materials; metal–organic frameworks; synthesis; X-ray and electron diffraction; in situ characterisation; heterogeneous catalysis; gas sorption/separation; proton conduction; rechargeable batteries; drug delivery 31 12 2019 2019-12-31 10.3390/cryst9050270 COLLEGE NANME COLLEGE CODE Swansea University 2019-07-18T16:30:51.0483151 2019-05-30T11:50:06.7008730 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised Steve Shearan 1 Stephen J.I. Shearan 2 Norbert Stock 3 Franziska Emmerling 4 Jan Demel 5 Paul A. Wright 6 Konstantinos D. Demadis 7 Maria Vassaki 8 Ferdinando Costantino 9 Riccardo Vivani 10 Sébastien Sallard 11 Inés Ruiz Salcedo 12 Aurelio Cabeza 13 Marco Taddei 0000-0003-2805-6375 14 0050572-30052019115312.pdf shearan2019v2.pdf 2019-05-30T11:53:12.4000000 Output 16048481 application/pdf Version of Record true 2019-05-30T00:00:00.0000000 Distributed under the terms of a Creative Commons Attribution (CC-BY-4.0) true eng
title New Directions in Metal Phosphonate and Phosphinate Chemistry
spellingShingle New Directions in Metal Phosphonate and Phosphinate Chemistry
Steve Shearan
Marco Taddei
title_short New Directions in Metal Phosphonate and Phosphinate Chemistry
title_full New Directions in Metal Phosphonate and Phosphinate Chemistry
title_fullStr New Directions in Metal Phosphonate and Phosphinate Chemistry
title_full_unstemmed New Directions in Metal Phosphonate and Phosphinate Chemistry
title_sort New Directions in Metal Phosphonate and Phosphinate Chemistry
author_id_str_mv feed41db390519dc46cbc1365e86d35f
5cffd1038508554d8596dee8b4e51052
author_id_fullname_str_mv feed41db390519dc46cbc1365e86d35f_***_Steve Shearan
5cffd1038508554d8596dee8b4e51052_***_Marco Taddei
author Steve Shearan
Marco Taddei
author2 Steve Shearan
Stephen J.I. Shearan
Norbert Stock
Franziska Emmerling
Jan Demel
Paul A. Wright
Konstantinos D. Demadis
Maria Vassaki
Ferdinando Costantino
Riccardo Vivani
Sébastien Sallard
Inés Ruiz Salcedo
Aurelio Cabeza
Marco Taddei
format Journal article
container_title Crystals
container_volume 9
container_issue 5
container_start_page 270
publishDate 2019
institution Swansea University
issn 2073-4352
doi_str_mv 10.3390/cryst9050270
college_str Faculty of Science and Engineering
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hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
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description In September 2018, the First European Workshop on Metal Phosphonates Chemistry brought together some prominent researchers in the field of metal phosphonates and phosphinates with the aim of discussing past and current research efforts and identifying future directions. The scope of this perspective article is to provide a critical overview of the topics discussed during the workshop, which are divided into two main areas: synthesis and characterisation, and applications. In terms of synthetic methods, there has been a push towards cleaner and more efficient approaches. This has led to the introduction of high-throughput synthesis and mechanochemical synthesis. The recent success of metal–organic frameworks has also promoted renewed interest in the synthesis of porous metal phosphonates and phosphinates. Regarding characterisation, the main advances are the development of electron diffraction as a tool for crystal structure determination and the deployment of in situ characterisation techniques, which have allowed for a better understanding of reaction pathways. In terms of applications, metal phosphonates have been found to be suitable materials for several purposes: they have been employed as heterogeneous catalysts for the synthesis of fine chemicals, as solid sorbents for gas separation, notably CO2 capture, as materials for electrochemical devices, such as fuel cells and rechargeable batteries, and as matrices for drug delivery.
published_date 2019-12-31T07:45:10Z
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