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Modelling the curing process in particle-filled electro-active polymers with a dispersion anisotropy
Continuum Mechanics and Thermodynamics
Swansea University Author: Mokarram Hossain
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DOI (Published version): 10.1007/s00161-019-00747-5
Abstract
Even for a moderate actuation, a large electric voltage requirement hinders the application of electro-active polymers (EAPs) in many areas. Hence, among other mechanisms, the actuation enhancement in EAPs is performed via inclusions of high-dielectric-permittivity fillers in the matrix material in...
Published in: | Continuum Mechanics and Thermodynamics |
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ISSN: | 0935-1175 1432-0959 |
Published: |
2019
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Online Access: |
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URI: | https://cronfa.swan.ac.uk/Record/cronfa48719 |
Abstract: |
Even for a moderate actuation, a large electric voltage requirement hinders the application of electro-active polymers (EAPs) in many areas. Hence, among other mechanisms, the actuation enhancement in EAPs is performed via inclusions of high-dielectric-permittivity fillers in the matrix material in the uncured stage. Moreover, to obtain an optimum advantage from the high-dielectric-permittivity fillers, an electric field can be applied during the curing process which helps the particles to align in a preferred direction. To be specific, recent experimental evidences show that these particles form a dispersed anisotropy rather than a perfect transverse anisotropic structure. The polymer curing process is a complex (visco-) elastic phenomenon where a liquid polymer gradually transforms into a solid macromolecular structure due to cross-linking of the initial solution of short polymer chains. This phase transition comes along with an increase in the material stiffness and a volume shrinkage. In this paper we present a phenomenologically inspired large strain framework for simulating the curing process of particle-filled electro-active polymers with a dispersion-type anisotropy that can work under the influence of an electro-mechanically coupled load. The application of the proposed approach is demonstrated with some numerical examples. These examples illustrate that the model can predict common features in particle-filled dispersed electro-active polymers undergoing curing processes in the presence of an electro-mechanically coupled load. |
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Keywords: |
Electro-active polymers, Polymer curing, Electro-mechanically coupled problem, Dispersion anisotropy, Electro-elasticity, Curing shrinkage |
College: |
Faculty of Science and Engineering |