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Engineering Nanocomposite Membranes; Fabrication, Modification and Application / Saif Al-Aani

Swansea University Author: Saif Al-Aani

DOI (Published version): 10.23889/SUthesis.40523

Abstract

The engineering of novel membranes through fabrication and modification using engineered nanoscale materials (ENMs) presents tremendous opportunity within desalination and water treatment. This work presents an endeavour dedicated to investigate the design and fabrication of polymeric membranes and...

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Published: 2018
Institution: Swansea University
Degree level: Doctoral
Degree name: Ph.D
URI: https://cronfa.swan.ac.uk/Record/cronfa40523
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Also, to probe the role of nanoscale materials integration on the function of separating membranes aiming to diminish the propensity of the surface to foul.In the first part of the work, an attempt was made to research and compare the potential of versatile UF membranes structures in terms of morphology, surface characteristics and performance. The potential performance of the hand-made fabricated (UF) membranes was systematically evaluated against three organic model foulants with dissimilar origins; humic acid (HA), sodium alginate (NaAlg), and bovine serum albumin (BSA), under different initial feed concentration and pH chemistry. A diverse range of surface characteristics and morphologies have been produced as a result of varying the dope casting solution concentration, which corresponds to the wide range of commercially available UF membranes (6, 10, 35 and 100kDa). Also, a disparate fouling behaviour was observed depending on the membrane characteristics and the organic model foulant used. A one or more pore blocking mechanism were distinctly observed depending on the UF membrane cut-off used.Subsequently, the research presented the development of a novel nanocomposite membrane incorporating antimicrobial nanoparticles which have the potential to lower membrane biofouling. Antibacterial hybrid nanostructures (HNS) comprising of Ag decorated MWCNTs were successfully synthesised with the assistance of microwave irradiation. The HNS were then employed to fabricated antibacterial nanocomposite membranes via the classical phase inversion technique in order to assess their antimicrobial properties against two bacterial species; E. coli and S. aureus. The nanocomposite membranes remarkably displayed antibacterial activity (4.24 and 2.9 log kill) against the two species respectively. A higher stability under crossflow conditions was also demonstrated.Finally, for desalination applications, novel HNS comprising of a mussel-inspired PDA coated M/MO&#x2013;MWCNTs, were successfully synthesised and used to fabricate TFN membranes. For comparison, four different M/MO (Al2O3, Fe2O3, TiO2 and Ag) nanoparticles (NPs) were in situ synthesised/loaded on the surface of CNTs, and the resultant HNS were further coated with a thin polymeric film of PDA. An intermediate layer of the HNS was then deposited on a PES substrate membrane, and an interfacial polymerisation (IP) process was carried out to render a polyamide (PA) thin layer above the intermediate layer. Both HNS and TFN were characterised using different characterisation tools, and the performance of nanofiltration (NF) membranes was evaluated against monovalent, divalent salts and heavy metal solutions. The fabricated TFN-NF membranes had higher performance in terms of their permeation characteristics compared to the thin film composite TFC membrane (&#x2053;9.6-11.6 LMH), while maintaining their selectivity (&#x2265;91%) against both monovalent and divalent salts solutions, and (&gt; 92%) against the multi-component heavy metal solution. The experimental results disclosed a high retention capability for TFC and TFN membranes along with greater potential stability/compatibility within the polymeric PA matrix. 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spelling 2020-09-01T16:02:48.2997545 v2 40523 2018-05-31 Engineering Nanocomposite Membranes; Fabrication, Modification and Application 81c41439a46a02e57ec21887b975ca54 NULL Saif Al-Aani Saif Al-Aani true true 2018-05-31 The engineering of novel membranes through fabrication and modification using engineered nanoscale materials (ENMs) presents tremendous opportunity within desalination and water treatment. This work presents an endeavour dedicated to investigate the design and fabrication of polymeric membranes and nanoscale materials. Also, to probe the role of nanoscale materials integration on the function of separating membranes aiming to diminish the propensity of the surface to foul.In the first part of the work, an attempt was made to research and compare the potential of versatile UF membranes structures in terms of morphology, surface characteristics and performance. The potential performance of the hand-made fabricated (UF) membranes was systematically evaluated against three organic model foulants with dissimilar origins; humic acid (HA), sodium alginate (NaAlg), and bovine serum albumin (BSA), under different initial feed concentration and pH chemistry. A diverse range of surface characteristics and morphologies have been produced as a result of varying the dope casting solution concentration, which corresponds to the wide range of commercially available UF membranes (6, 10, 35 and 100kDa). Also, a disparate fouling behaviour was observed depending on the membrane characteristics and the organic model foulant used. A one or more pore blocking mechanism were distinctly observed depending on the UF membrane cut-off used.Subsequently, the research presented the development of a novel nanocomposite membrane incorporating antimicrobial nanoparticles which have the potential to lower membrane biofouling. Antibacterial hybrid nanostructures (HNS) comprising of Ag decorated MWCNTs were successfully synthesised with the assistance of microwave irradiation. The HNS were then employed to fabricated antibacterial nanocomposite membranes via the classical phase inversion technique in order to assess their antimicrobial properties against two bacterial species; E. coli and S. aureus. The nanocomposite membranes remarkably displayed antibacterial activity (4.24 and 2.9 log kill) against the two species respectively. A higher stability under crossflow conditions was also demonstrated.Finally, for desalination applications, novel HNS comprising of a mussel-inspired PDA coated M/MO–MWCNTs, were successfully synthesised and used to fabricate TFN membranes. For comparison, four different M/MO (Al2O3, Fe2O3, TiO2 and Ag) nanoparticles (NPs) were in situ synthesised/loaded on the surface of CNTs, and the resultant HNS were further coated with a thin polymeric film of PDA. An intermediate layer of the HNS was then deposited on a PES substrate membrane, and an interfacial polymerisation (IP) process was carried out to render a polyamide (PA) thin layer above the intermediate layer. Both HNS and TFN were characterised using different characterisation tools, and the performance of nanofiltration (NF) membranes was evaluated against monovalent, divalent salts and heavy metal solutions. The fabricated TFN-NF membranes had higher performance in terms of their permeation characteristics compared to the thin film composite TFC membrane (⁓9.6-11.6 LMH), while maintaining their selectivity (≥91%) against both monovalent and divalent salts solutions, and (> 92%) against the multi-component heavy metal solution. The experimental results disclosed a high retention capability for TFC and TFN membranes along with greater potential stability/compatibility within the polymeric PA matrix. This implies that the NF membranes fabricated in this work can be employed for water reclamation purposes. E-Thesis Novel membranes, water treatment 31 12 2018 2018-12-31 10.23889/SUthesis.40523 COLLEGE NANME Engineering COLLEGE CODE Swansea University Doctoral Ph.D Higher Committee for Education Development in Iraq (HCED) 2020-09-01T16:02:48.2997545 2018-05-31T10:50:30.6137419 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised Saif Al-Aani NULL 1 0040523-31052018105530.pdf Al__Aani,__Saif_PhD_final.2018.pdf 2018-05-31T10:55:30.4800000 Output 12841138 application/pdf E-Thesis – open access true 2020-01-01T00:00:00.0000000 true
title Engineering Nanocomposite Membranes; Fabrication, Modification and Application
spellingShingle Engineering Nanocomposite Membranes; Fabrication, Modification and Application
Saif Al-Aani
title_short Engineering Nanocomposite Membranes; Fabrication, Modification and Application
title_full Engineering Nanocomposite Membranes; Fabrication, Modification and Application
title_fullStr Engineering Nanocomposite Membranes; Fabrication, Modification and Application
title_full_unstemmed Engineering Nanocomposite Membranes; Fabrication, Modification and Application
title_sort Engineering Nanocomposite Membranes; Fabrication, Modification and Application
author_id_str_mv 81c41439a46a02e57ec21887b975ca54
author_id_fullname_str_mv 81c41439a46a02e57ec21887b975ca54_***_Saif Al-Aani
author Saif Al-Aani
author2 Saif Al-Aani
format E-Thesis
publishDate 2018
institution Swansea University
doi_str_mv 10.23889/SUthesis.40523
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
document_store_str 1
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description The engineering of novel membranes through fabrication and modification using engineered nanoscale materials (ENMs) presents tremendous opportunity within desalination and water treatment. This work presents an endeavour dedicated to investigate the design and fabrication of polymeric membranes and nanoscale materials. Also, to probe the role of nanoscale materials integration on the function of separating membranes aiming to diminish the propensity of the surface to foul.In the first part of the work, an attempt was made to research and compare the potential of versatile UF membranes structures in terms of morphology, surface characteristics and performance. The potential performance of the hand-made fabricated (UF) membranes was systematically evaluated against three organic model foulants with dissimilar origins; humic acid (HA), sodium alginate (NaAlg), and bovine serum albumin (BSA), under different initial feed concentration and pH chemistry. A diverse range of surface characteristics and morphologies have been produced as a result of varying the dope casting solution concentration, which corresponds to the wide range of commercially available UF membranes (6, 10, 35 and 100kDa). Also, a disparate fouling behaviour was observed depending on the membrane characteristics and the organic model foulant used. A one or more pore blocking mechanism were distinctly observed depending on the UF membrane cut-off used.Subsequently, the research presented the development of a novel nanocomposite membrane incorporating antimicrobial nanoparticles which have the potential to lower membrane biofouling. Antibacterial hybrid nanostructures (HNS) comprising of Ag decorated MWCNTs were successfully synthesised with the assistance of microwave irradiation. The HNS were then employed to fabricated antibacterial nanocomposite membranes via the classical phase inversion technique in order to assess their antimicrobial properties against two bacterial species; E. coli and S. aureus. The nanocomposite membranes remarkably displayed antibacterial activity (4.24 and 2.9 log kill) against the two species respectively. A higher stability under crossflow conditions was also demonstrated.Finally, for desalination applications, novel HNS comprising of a mussel-inspired PDA coated M/MO–MWCNTs, were successfully synthesised and used to fabricate TFN membranes. For comparison, four different M/MO (Al2O3, Fe2O3, TiO2 and Ag) nanoparticles (NPs) were in situ synthesised/loaded on the surface of CNTs, and the resultant HNS were further coated with a thin polymeric film of PDA. An intermediate layer of the HNS was then deposited on a PES substrate membrane, and an interfacial polymerisation (IP) process was carried out to render a polyamide (PA) thin layer above the intermediate layer. Both HNS and TFN were characterised using different characterisation tools, and the performance of nanofiltration (NF) membranes was evaluated against monovalent, divalent salts and heavy metal solutions. The fabricated TFN-NF membranes had higher performance in terms of their permeation characteristics compared to the thin film composite TFC membrane (⁓9.6-11.6 LMH), while maintaining their selectivity (≥91%) against both monovalent and divalent salts solutions, and (> 92%) against the multi-component heavy metal solution. The experimental results disclosed a high retention capability for TFC and TFN membranes along with greater potential stability/compatibility within the polymeric PA matrix. This implies that the NF membranes fabricated in this work can be employed for water reclamation purposes.
published_date 2018-12-31T03:51:34Z
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score 11.037581

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