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Continuous-Flow Microwave Synthesis of Metal-Organic Frameworks: A Highly Efficient Method for Large-Scale Production

M. Taddei, D. Antti, J. Anton, M. Ranocchiari, Marco Taddei Orcid Logo

Chemistry - A European Journal, Volume: 22, Issue: 10, Pages: 3245 - 3249

Swansea University Author: Marco Taddei Orcid Logo

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DOI (Published version): 10.1002/chem.201505139

Abstract

Metal–organic frameworks are having a tremendous impact on novel strategic applications, with prospective employment in industrially relevant processes. The development of such processes is strictly dependent on the ability to generate materials with high yield efficiency and production rate. We rep...

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Published in: Chemistry - A European Journal
ISSN: 0947-6539
Published: Wiley-Blackwell 2016
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URI: https://cronfa.swan.ac.uk/Record/cronfa32743
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last_indexed 2018-02-09T05:20:59Z
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spelling 2017-04-03T11:21:46.3833130 v2 32743 2017-03-29 Continuous-Flow Microwave Synthesis of Metal-Organic Frameworks: A Highly Efficient Method for Large-Scale Production 5cffd1038508554d8596dee8b4e51052 0000-0003-2805-6375 Marco Taddei Marco Taddei true false 2017-03-29 Metal–organic frameworks are having a tremendous impact on novel strategic applications, with prospective employment in industrially relevant processes. The development of such processes is strictly dependent on the ability to generate materials with high yield efficiency and production rate. We report a versatile and highly efficient method for synthesis of metal–organic frameworks in large quantities using continuous flow processing under microwave irradiation. Benchmark materials such as UiO-66, MIL-53(Al), and HKUST-1 were obtained with remarkable mass, space–time yields, and often using stoichiometric amounts of reactants. In the case of UiO-66 and MIL-53(Al), we attained unprecedented space–time yields far greater than those reported previously. All of the syntheses were successfully extended to multi-gram high quality products in a matter of minutes, proving the effectiveness of continuous flow microwave technology for the large scale production of metal–organic frameworks. Journal Article Chemistry - A European Journal 22 10 3245 3249 Wiley-Blackwell 0947-6539 continuous flow synthesis; metal–organic frameworks; microporous materials; microwave chemistry 1 3 2016 2016-03-01 10.1002/chem.201505139 COLLEGE NANME COLLEGE CODE Swansea University 2017-04-03T11:21:46.3833130 2017-03-29T09:52:36.6580854 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised M. Taddei 1 D. Antti 2 J. Anton 3 M. Ranocchiari 4 Marco Taddei 0000-0003-2805-6375 5
title Continuous-Flow Microwave Synthesis of Metal-Organic Frameworks: A Highly Efficient Method for Large-Scale Production
spellingShingle Continuous-Flow Microwave Synthesis of Metal-Organic Frameworks: A Highly Efficient Method for Large-Scale Production
Marco Taddei
title_short Continuous-Flow Microwave Synthesis of Metal-Organic Frameworks: A Highly Efficient Method for Large-Scale Production
title_full Continuous-Flow Microwave Synthesis of Metal-Organic Frameworks: A Highly Efficient Method for Large-Scale Production
title_fullStr Continuous-Flow Microwave Synthesis of Metal-Organic Frameworks: A Highly Efficient Method for Large-Scale Production
title_full_unstemmed Continuous-Flow Microwave Synthesis of Metal-Organic Frameworks: A Highly Efficient Method for Large-Scale Production
title_sort Continuous-Flow Microwave Synthesis of Metal-Organic Frameworks: A Highly Efficient Method for Large-Scale Production
author_id_str_mv 5cffd1038508554d8596dee8b4e51052
author_id_fullname_str_mv 5cffd1038508554d8596dee8b4e51052_***_Marco Taddei
author Marco Taddei
author2 M. Taddei
D. Antti
J. Anton
M. Ranocchiari
Marco Taddei
format Journal article
container_title Chemistry - A European Journal
container_volume 22
container_issue 10
container_start_page 3245
publishDate 2016
institution Swansea University
issn 0947-6539
doi_str_mv 10.1002/chem.201505139
publisher Wiley-Blackwell
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
document_store_str 0
active_str 0
description Metal–organic frameworks are having a tremendous impact on novel strategic applications, with prospective employment in industrially relevant processes. The development of such processes is strictly dependent on the ability to generate materials with high yield efficiency and production rate. We report a versatile and highly efficient method for synthesis of metal–organic frameworks in large quantities using continuous flow processing under microwave irradiation. Benchmark materials such as UiO-66, MIL-53(Al), and HKUST-1 were obtained with remarkable mass, space–time yields, and often using stoichiometric amounts of reactants. In the case of UiO-66 and MIL-53(Al), we attained unprecedented space–time yields far greater than those reported previously. All of the syntheses were successfully extended to multi-gram high quality products in a matter of minutes, proving the effectiveness of continuous flow microwave technology for the large scale production of metal–organic frameworks.
published_date 2016-03-01T04:09:32Z
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score 11.3749895

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