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In situ monitoring and optimization of room temperature ultra-fast sensitization for dye-sensitized solar cells

Matthew Davies Orcid Logo, Trystan Watson Orcid Logo, Peter Holliman Orcid Logo, Arthur Connell, David Worsley Orcid Logo

Chem. Commun., Volume: 50, Issue: 83, Pages: 12512 - 12514

Swansea University Authors: Matthew Davies Orcid Logo, Trystan Watson Orcid Logo, Peter Holliman Orcid Logo, David Worsley Orcid Logo

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DOI (Published version): 10.1039/C4CC05766J

Abstract

We describe the fastest dyeing of TiO2 photo-electrodes for dye-sensitized solar cells reported to date (<2 min) at room temperature giving η = 7.5% for an N719–SQ1–CDCA mixture which is significantly higher than devices dyed for >12 h using the same dye mixture (η = 5.5%). Time-lapse photogra...

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Published in: Chem. Commun.
ISSN: 1359-7345
Published: 2014
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URI: https://cronfa.swan.ac.uk/Record/cronfa18691
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first_indexed 2014-10-11T01:30:04Z
last_indexed 2021-01-14T03:33:20Z
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spelling 2021-01-13T13:15:31.3635066 v2 18691 2014-10-10 In situ monitoring and optimization of room temperature ultra-fast sensitization for dye-sensitized solar cells 4ad478e342120ca3434657eb13527636 0000-0003-2595-5121 Matthew Davies Matthew Davies true false a210327b52472cfe8df9b8108d661457 0000-0002-8015-1436 Trystan Watson Trystan Watson true false c8f52394d776279c9c690dc26066ddf9 0000-0002-9911-8513 Peter Holliman Peter Holliman true false c426b1c1b0123d7057c1b969083cea69 0000-0002-9956-6228 David Worsley David Worsley true false 2014-10-10 CHEG We describe the fastest dyeing of TiO2 photo-electrodes for dye-sensitized solar cells reported to date (<2 min) at room temperature giving η = 7.5% for an N719–SQ1–CDCA mixture which is significantly higher than devices dyed for >12 h using the same dye mixture (η = 5.5%). Time-lapse photography has been used to monitor the ultra-fast co-sensitization. The data show significantly different dye uptake between passive and pump dyeing reflecting competitive sorption between a Ru complex (N719) and an organic dye (SQ1). Journal Article Chem. Commun. 50 83 12512 12514 1359-7345 25 10 2014 2014-10-25 10.1039/C4CC05766J COLLEGE NANME Chemical Engineering COLLEGE CODE CHEG Swansea University 2021-01-13T13:15:31.3635066 2014-10-10T22:25:31.0294498 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Matthew Davies 0000-0003-2595-5121 1 Trystan Watson 0000-0002-8015-1436 2 Peter Holliman 0000-0002-9911-8513 3 Arthur Connell 4 David Worsley 0000-0002-9956-6228 5
title In situ monitoring and optimization of room temperature ultra-fast sensitization for dye-sensitized solar cells
spellingShingle In situ monitoring and optimization of room temperature ultra-fast sensitization for dye-sensitized solar cells
Matthew Davies
Trystan Watson
Peter Holliman
David Worsley
title_short In situ monitoring and optimization of room temperature ultra-fast sensitization for dye-sensitized solar cells
title_full In situ monitoring and optimization of room temperature ultra-fast sensitization for dye-sensitized solar cells
title_fullStr In situ monitoring and optimization of room temperature ultra-fast sensitization for dye-sensitized solar cells
title_full_unstemmed In situ monitoring and optimization of room temperature ultra-fast sensitization for dye-sensitized solar cells
title_sort In situ monitoring and optimization of room temperature ultra-fast sensitization for dye-sensitized solar cells
author_id_str_mv 4ad478e342120ca3434657eb13527636
a210327b52472cfe8df9b8108d661457
c8f52394d776279c9c690dc26066ddf9
c426b1c1b0123d7057c1b969083cea69
author_id_fullname_str_mv 4ad478e342120ca3434657eb13527636_***_Matthew Davies
a210327b52472cfe8df9b8108d661457_***_Trystan Watson
c8f52394d776279c9c690dc26066ddf9_***_Peter Holliman
c426b1c1b0123d7057c1b969083cea69_***_David Worsley
author Matthew Davies
Trystan Watson
Peter Holliman
David Worsley
author2 Matthew Davies
Trystan Watson
Peter Holliman
Arthur Connell
David Worsley
format Journal article
container_title Chem. Commun.
container_volume 50
container_issue 83
container_start_page 12512
publishDate 2014
institution Swansea University
issn 1359-7345
doi_str_mv 10.1039/C4CC05766J
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
document_store_str 0
active_str 0
description We describe the fastest dyeing of TiO2 photo-electrodes for dye-sensitized solar cells reported to date (<2 min) at room temperature giving η = 7.5% for an N719–SQ1–CDCA mixture which is significantly higher than devices dyed for >12 h using the same dye mixture (η = 5.5%). Time-lapse photography has been used to monitor the ultra-fast co-sensitization. The data show significantly different dye uptake between passive and pump dyeing reflecting competitive sorption between a Ru complex (N719) and an organic dye (SQ1).
published_date 2014-10-25T03:21:56Z
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