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Dynamic Raman spectroscopy of hydrogen isotopomer mixtures in-line at TILO

R.J Lewis, H.H Telle, B Bornschein, O Kazachenko, N Kernert, M Sturm, Helmut Telle

Laser Physics Letters, Volume: 5, Issue: 7, Pages: 522 - 531

Swansea University Author: Helmut Telle

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DOI (Published version): 10.1002/lapl.200810026

Abstract

The pure rotational and vibration-rotational Stokes Raman spectra of flowing gaseous mixtures of the hydrogen isotopomers H2, HD, and D2 were measured in order to test the performance of the proposed tritium purity monitoring system designed for the Karlsruhe Tritium Neutrino (KATRIN) mass experimen...

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Published in: Laser Physics Letters
ISSN: 1612-2011 1612-202X
Published: 2008
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URI: https://cronfa.swan.ac.uk/Record/cronfa1161
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Abstract: The pure rotational and vibration-rotational Stokes Raman spectra of flowing gaseous mixtures of the hydrogen isotopomers H2, HD, and D2 were measured in order to test the performance of the proposed tritium purity monitoring system designed for the Karlsruhe Tritium Neutrino (KATRIN) mass experiment, which utilises 532 nm CW laser excitation and fibrecoupled scattered light collection, exploiting 90° excitation observation geometry. Short (100–300 s) exposure times were used to simulate the real-time in-line measurement of hydrogen isotopomer composition at the low (∼ 100–150 mbar) pressure required for KATRIN. At 100 s exposure time, an in-line sensitivity of better than 1% was achieved for dynamic changes in the sample gas composition.
Item Description: a. The author made a substantial contribution to the conception and design of the study; to the organisation of the conduct of the study; and to analysis and interpretation of study data.
College: Faculty of Science and Engineering
Issue: 7
Start Page: 522
End Page: 531