E-Thesis 142 views 92 downloads
Investigating Water Treatment Procedures with a Focus on Novel Porous Silicon / CHIALUKA IKOKWU
Swansea University Author: CHIALUKA IKOKWU
DOI (Published version): 10.23889/SUThesis.70853
Abstract
Membrane processes for seawater desalination offer solutions to global water challenges, but factors such as high energy consumption and membrane fouling limit their capacity to provide fresh water worldwide.This work investigated the use of nanofiltration to desalinate seawater, with specific refer...
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Swansea
2025
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| Institution: | Swansea University |
| Degree level: | Master of Philosophy |
| Degree name: | M.Phil |
| Supervisor: | Guy, O. |
| URI: | https://cronfa.swan.ac.uk/Record/cronfa70853 |
| first_indexed |
2025-11-06T15:25:03Z |
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| last_indexed |
2025-11-07T07:35:32Z |
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cronfa70853 |
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RisThesis |
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| spelling |
2025-11-06T15:30:23.2492771 v2 70853 2025-11-06 Investigating Water Treatment Procedures with a Focus on Novel Porous Silicon a19a83a38d93bf01abcd24205d8a955e CHIALUKA IKOKWU CHIALUKA IKOKWU true false 2025-11-06 Membrane processes for seawater desalination offer solutions to global water challenges, but factors such as high energy consumption and membrane fouling limit their capacity to provide fresh water worldwide.This work investigated the use of nanofiltration to desalinate seawater, with specific reference to the removal of monovalent and divalent ions. Nanofiltration was found capable of removing 85% of calcium and 93% of magnesium from seawater. However, one limitation of the process is its inability to effectively remove monovalent ions such as Na.Electrodialysis as a means of seawater desalination was also investigated in this study. It achieved over 90% ion exchange in seawater within 75 minutes of operation. However, it has high energy requirements and is unable to remove organics from seawater.Surface modification of the NF membrane with oxygen plasma was found to improve hydrophilicity and flux while trading off performance in rejection. Ammonia plasma treatment for 50 seconds showed hydrophobic recovery after some time.Metal-assisted etching was used to create pores in a silicon wafer. Filtration results showed that water was able to pass through these pores, presenting a new approach to water desalination. E-Thesis Swansea desalination, nanofiltration, silicon, electrodialysis, plasma surface modification, porous silicon membranes, ion rejection, membrane fouling 26 8 2025 2025-08-26 10.23889/SUThesis.70853 COLLEGE NANME COLLEGE CODE Swansea University Guy, O. Master of Philosophy M.Phil 2025-11-06T15:30:23.2492771 2025-11-06T15:21:36.4024502 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemical Engineering CHIALUKA IKOKWU 1 70853__35575__47415045030148fa89fe27ee87236466.pdf 2025_Ikokwu_C.final.70853.pdf 2025-11-06T15:24:38.0587570 Output 4083898 application/pdf E-Thesis – open access true Copyright: The author, Chialuka Ikokwu, 2025 true eng |
| title |
Investigating Water Treatment Procedures with a Focus on Novel Porous Silicon |
| spellingShingle |
Investigating Water Treatment Procedures with a Focus on Novel Porous Silicon CHIALUKA IKOKWU |
| title_short |
Investigating Water Treatment Procedures with a Focus on Novel Porous Silicon |
| title_full |
Investigating Water Treatment Procedures with a Focus on Novel Porous Silicon |
| title_fullStr |
Investigating Water Treatment Procedures with a Focus on Novel Porous Silicon |
| title_full_unstemmed |
Investigating Water Treatment Procedures with a Focus on Novel Porous Silicon |
| title_sort |
Investigating Water Treatment Procedures with a Focus on Novel Porous Silicon |
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a19a83a38d93bf01abcd24205d8a955e |
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a19a83a38d93bf01abcd24205d8a955e_***_CHIALUKA IKOKWU |
| author |
CHIALUKA IKOKWU |
| author2 |
CHIALUKA IKOKWU |
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E-Thesis |
| publishDate |
2025 |
| institution |
Swansea University |
| doi_str_mv |
10.23889/SUThesis.70853 |
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Faculty of Science and Engineering |
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Faculty of Science and Engineering |
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School of Engineering and Applied Sciences - Chemical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemical Engineering |
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| description |
Membrane processes for seawater desalination offer solutions to global water challenges, but factors such as high energy consumption and membrane fouling limit their capacity to provide fresh water worldwide.This work investigated the use of nanofiltration to desalinate seawater, with specific reference to the removal of monovalent and divalent ions. Nanofiltration was found capable of removing 85% of calcium and 93% of magnesium from seawater. However, one limitation of the process is its inability to effectively remove monovalent ions such as Na.Electrodialysis as a means of seawater desalination was also investigated in this study. It achieved over 90% ion exchange in seawater within 75 minutes of operation. However, it has high energy requirements and is unable to remove organics from seawater.Surface modification of the NF membrane with oxygen plasma was found to improve hydrophilicity and flux while trading off performance in rejection. Ammonia plasma treatment for 50 seconds showed hydrophobic recovery after some time.Metal-assisted etching was used to create pores in a silicon wafer. Filtration results showed that water was able to pass through these pores, presenting a new approach to water desalination. |
| published_date |
2025-08-26T05:31:52Z |
| _version_ |
1851098097061462016 |
| score |
11.089407 |

