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A Direct Measurement of the C2H2 Concentration from the C2H2–Oil Mixed Solution Using the Photoacoustic Spectroscopy Method
Photonics, Volume: 12, Issue: 5, Start page: 471
Swansea University Author:
Lijie Li
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DOI (Published version): 10.3390/photonics12050471
Abstract
The photoacoustic (PA) method is commonly used in the measurement of trace gas concentration owing to its high accuracy and reliability. However, the conventional PA method is usually used in the gas-phase environment, which leads to a long measurement time and a large equipment volume for the degas...
| Published in: | Photonics |
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| ISSN: | 2304-6732 |
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MDPI
2025
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| URI: | https://cronfa.swan.ac.uk/Record/cronfa69655 |
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<?xml version="1.0"?><rfc1807><datestamp>2025-06-09T14:31:27.1389736</datestamp><bib-version>v2</bib-version><id>69655</id><entry>2025-06-09</entry><title>A Direct Measurement of the C2H2 Concentration from the C2H2–Oil Mixed Solution Using the Photoacoustic Spectroscopy Method</title><swanseaauthors><author><sid>ed2c658b77679a28e4c1dcf95af06bd6</sid><ORCID>0000-0003-4630-7692</ORCID><firstname>Lijie</firstname><surname>Li</surname><name>Lijie Li</name><active>true</active><ethesisStudent>false</ethesisStudent></author></swanseaauthors><date>2025-06-09</date><deptcode>ACEM</deptcode><abstract>The photoacoustic (PA) method is commonly used in the measurement of trace gas concentration owing to its high accuracy and reliability. However, the conventional PA method is usually used in the gas-phase environment, which leads to a long measurement time and a large equipment volume for the degassing process. In this paper, we report a scheme to measure the acetylene (C2H2) concentration from the acetylene–dielectric oil (C2H2–Oil) mixed solution without the degassing process. The frequency and intensity distribution of the PA signal in the C2H2–Oil mixed liquid is investigated using the finite element method (FEM). Simulation results reveal that the incident light modulation frequency and the geometry size of the PA cell are two core factors to determine the PA signal. Furthermore, a PA sensor system is constructed to measure the concentration of C2H2 from the C2H2–Oil mixed solution. The measurement results demonstrate that the intensity of the PA signal in the C2H2–Oil mixed solution rises mostly linearly with the concentration of C2H2 from 0 to 100 mL/L. The Allan variance results from the continuous tests indicate that the measurement limit of the PA sensor system is about 0.2 mL/L. This work points to a novel method for the measurement of the C2H2 concentration from the C2H2–Oil mixed solution.</abstract><type>Journal Article</type><journal>Photonics</journal><volume>12</volume><journalNumber>5</journalNumber><paginationStart>471</paginationStart><paginationEnd/><publisher>MDPI</publisher><placeOfPublication/><isbnPrint/><isbnElectronic/><issnPrint/><issnElectronic>2304-6732</issnElectronic><keywords>photoacoustic spectroscopy; gas–liquid mixed solution; direct measurement; acetylene concentration</keywords><publishedDay>10</publishedDay><publishedMonth>5</publishedMonth><publishedYear>2025</publishedYear><publishedDate>2025-05-10</publishedDate><doi>10.3390/photonics12050471</doi><url/><notes/><college>COLLEGE NANME</college><department>Aerospace, Civil, Electrical, and Mechanical Engineering</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>ACEM</DepartmentCode><institution>Swansea University</institution><apcterm>Another institution paid the OA fee</apcterm><funders>National Natural Science Foundation of China (62304161); Key R&D Program of Hubei Province (2024BAB009).</funders><projectreference/><lastEdited>2025-06-09T14:31:27.1389736</lastEdited><Created>2025-06-09T14:22:45.3972444</Created><path><level id="1">Faculty of Science and Engineering</level><level id="2">School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Electronic and Electrical Engineering</level></path><authors><author><firstname>Zikang</firstname><surname>Rong</surname><order>1</order></author><author><firstname>Jian</firstname><surname>Ke</surname><order>2</order></author><author><firstname>Haifei</firstname><surname>Lu</surname><order>3</order></author><author><firstname>Xiaoyan</firstname><surname>Wen</surname><order>4</order></author><author><firstname>Lijie</firstname><surname>Li</surname><orcid>0000-0003-4630-7692</orcid><order>5</order></author><author><firstname>Zhiwen</firstname><surname>Ming</surname><order>6</order></author><author><firstname>Shuo</firstname><surname>Deng</surname><orcid>0009-0004-1079-1165</orcid><order>7</order></author><author><firstname>Min</firstname><surname>Li</surname><orcid>0000-0003-1037-3663</orcid><order>8</order></author></authors><documents><document><filename>69655__34428__025c833ed1dd4775a6f487cdef16bc26.pdf</filename><originalFilename>photonics-12-00471-v2.pdf</originalFilename><uploaded>2025-06-09T14:22:45.3262713</uploaded><type>Output</type><contentLength>4527434</contentLength><contentType>application/pdf</contentType><version>Version of Record</version><cronfaStatus>true</cronfaStatus><documentNotes>© 2025 by the authors. This article is an open access article distributed under the terms and
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| spelling |
2025-06-09T14:31:27.1389736 v2 69655 2025-06-09 A Direct Measurement of the C2H2 Concentration from the C2H2–Oil Mixed Solution Using the Photoacoustic Spectroscopy Method ed2c658b77679a28e4c1dcf95af06bd6 0000-0003-4630-7692 Lijie Li Lijie Li true false 2025-06-09 ACEM The photoacoustic (PA) method is commonly used in the measurement of trace gas concentration owing to its high accuracy and reliability. However, the conventional PA method is usually used in the gas-phase environment, which leads to a long measurement time and a large equipment volume for the degassing process. In this paper, we report a scheme to measure the acetylene (C2H2) concentration from the acetylene–dielectric oil (C2H2–Oil) mixed solution without the degassing process. The frequency and intensity distribution of the PA signal in the C2H2–Oil mixed liquid is investigated using the finite element method (FEM). Simulation results reveal that the incident light modulation frequency and the geometry size of the PA cell are two core factors to determine the PA signal. Furthermore, a PA sensor system is constructed to measure the concentration of C2H2 from the C2H2–Oil mixed solution. The measurement results demonstrate that the intensity of the PA signal in the C2H2–Oil mixed solution rises mostly linearly with the concentration of C2H2 from 0 to 100 mL/L. The Allan variance results from the continuous tests indicate that the measurement limit of the PA sensor system is about 0.2 mL/L. This work points to a novel method for the measurement of the C2H2 concentration from the C2H2–Oil mixed solution. Journal Article Photonics 12 5 471 MDPI 2304-6732 photoacoustic spectroscopy; gas–liquid mixed solution; direct measurement; acetylene concentration 10 5 2025 2025-05-10 10.3390/photonics12050471 COLLEGE NANME Aerospace, Civil, Electrical, and Mechanical Engineering COLLEGE CODE ACEM Swansea University Another institution paid the OA fee National Natural Science Foundation of China (62304161); Key R&D Program of Hubei Province (2024BAB009). 2025-06-09T14:31:27.1389736 2025-06-09T14:22:45.3972444 Faculty of Science and Engineering School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Electronic and Electrical Engineering Zikang Rong 1 Jian Ke 2 Haifei Lu 3 Xiaoyan Wen 4 Lijie Li 0000-0003-4630-7692 5 Zhiwen Ming 6 Shuo Deng 0009-0004-1079-1165 7 Min Li 0000-0003-1037-3663 8 69655__34428__025c833ed1dd4775a6f487cdef16bc26.pdf photonics-12-00471-v2.pdf 2025-06-09T14:22:45.3262713 Output 4527434 application/pdf Version of Record true © 2025 by the authors. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license. true eng https://creativecommons.org/licenses/by/4.0/ |
| title |
A Direct Measurement of the C2H2 Concentration from the C2H2–Oil Mixed Solution Using the Photoacoustic Spectroscopy Method |
| spellingShingle |
A Direct Measurement of the C2H2 Concentration from the C2H2–Oil Mixed Solution Using the Photoacoustic Spectroscopy Method Lijie Li |
| title_short |
A Direct Measurement of the C2H2 Concentration from the C2H2–Oil Mixed Solution Using the Photoacoustic Spectroscopy Method |
| title_full |
A Direct Measurement of the C2H2 Concentration from the C2H2–Oil Mixed Solution Using the Photoacoustic Spectroscopy Method |
| title_fullStr |
A Direct Measurement of the C2H2 Concentration from the C2H2–Oil Mixed Solution Using the Photoacoustic Spectroscopy Method |
| title_full_unstemmed |
A Direct Measurement of the C2H2 Concentration from the C2H2–Oil Mixed Solution Using the Photoacoustic Spectroscopy Method |
| title_sort |
A Direct Measurement of the C2H2 Concentration from the C2H2–Oil Mixed Solution Using the Photoacoustic Spectroscopy Method |
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ed2c658b77679a28e4c1dcf95af06bd6 |
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ed2c658b77679a28e4c1dcf95af06bd6_***_Lijie Li |
| author |
Lijie Li |
| author2 |
Zikang Rong Jian Ke Haifei Lu Xiaoyan Wen Lijie Li Zhiwen Ming Shuo Deng Min Li |
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Journal article |
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Photonics |
| container_volume |
12 |
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5 |
| container_start_page |
471 |
| publishDate |
2025 |
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Swansea University |
| issn |
2304-6732 |
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10.3390/photonics12050471 |
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MDPI |
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Faculty of Science and Engineering |
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School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Electronic and Electrical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Electronic and Electrical Engineering |
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| description |
The photoacoustic (PA) method is commonly used in the measurement of trace gas concentration owing to its high accuracy and reliability. However, the conventional PA method is usually used in the gas-phase environment, which leads to a long measurement time and a large equipment volume for the degassing process. In this paper, we report a scheme to measure the acetylene (C2H2) concentration from the acetylene–dielectric oil (C2H2–Oil) mixed solution without the degassing process. The frequency and intensity distribution of the PA signal in the C2H2–Oil mixed liquid is investigated using the finite element method (FEM). Simulation results reveal that the incident light modulation frequency and the geometry size of the PA cell are two core factors to determine the PA signal. Furthermore, a PA sensor system is constructed to measure the concentration of C2H2 from the C2H2–Oil mixed solution. The measurement results demonstrate that the intensity of the PA signal in the C2H2–Oil mixed solution rises mostly linearly with the concentration of C2H2 from 0 to 100 mL/L. The Allan variance results from the continuous tests indicate that the measurement limit of the PA sensor system is about 0.2 mL/L. This work points to a novel method for the measurement of the C2H2 concentration from the C2H2–Oil mixed solution. |
| published_date |
2025-05-10T05:27:33Z |
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1851369616191782912 |
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11.089572 |

