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Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties

Yuting Li Orcid Logo, Julian Brückel Orcid Logo, Marjan Jereb Orcid Logo, Anže Zupanc Orcid Logo, Sami‐Pekka Hirvonen Orcid Logo, Sami Hietala Orcid Logo, Marianna Kemell, YUE WU, Olaf Fuhr, Ross D. Jansen‐van Vuuren Orcid Logo, Mariolino Carta Orcid Logo, Stefan Bräse Orcid Logo

Advanced Functional Materials, Volume: 34, Issue: 47, Start page: 2401957

Swansea University Authors: YUE WU, Mariolino Carta Orcid Logo

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DOI (Published version): 10.1002/adfm.202401957

Abstract

The unique structure of [2.2]paracyclophane (PCP) with its rigidity, stability, and planar chirality has gained significant attention in polymer and material research. In this work, the incorporation of amino‐functionalized PCPs within polymers of intrinsic microporosity (PIMs) is reported for the f...

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Published in: Advanced Functional Materials
ISSN: 1616-301X 1616-3028
Published: Wiley 2024
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URI: https://cronfa.swan.ac.uk/Record/cronfa68471
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In this work, the incorporation of amino&#x2010;functionalized PCPs within polymers of intrinsic microporosity (PIMs) is reported for the first time. Three different PCP&#x2010;PIMs were prepared via a Tr&#xF6;ger's base formation mechanism, and their structures characterized via solid&#x2010;state NMR, MALDI&#x2010;TOF, and SEM. Their porosity was evaluated using gas adsorption (N2 and CO2) based on theoretical calculations such as Brunauer&#x2013;Emmett&#x2013;Teller (BET), NLDFT pore size distribution (PSD) and ideal IAST CO2/N2 selectivity (15/85), a crucial separation when considering the capture of CO2 from flue gas. The surface areas were found to be between 200&#x2013;230 m2 g&#x2212;1 while the selectivity for CO2/N2 ranged from 46 to 70.</abstract><type>Journal Article</type><journal>Advanced Functional Materials</journal><volume>34</volume><journalNumber>47</journalNumber><paginationStart>2401957</paginationStart><paginationEnd/><publisher>Wiley</publisher><placeOfPublication/><isbnPrint/><isbnElectronic/><issnPrint>1616-301X</issnPrint><issnElectronic>1616-3028</issnElectronic><keywords>Gas sorption, paracyclophanes, PIMs, polymers, porosity, Tr&#xF6;ger&#x2019;s base</keywords><publishedDay>19</publishedDay><publishedMonth>11</publishedMonth><publishedYear>2024</publishedYear><publishedDate>2024-11-19</publishedDate><doi>10.1002/adfm.202401957</doi><url/><notes/><college>COLLEGE NANME</college><CollegeCode>COLLEGE CODE</CollegeCode><institution>Swansea University</institution><apcterm>Another institution paid the OA fee</apcterm><funders>Y.L. receives funding from CSC scholarship 202208080097. J.B. thanks the Carl Zeiss Foundation for financial support and acknowledges funding by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany`s Excellence Strategy &#x2013; 2082/1 &#x2013; 390761711. RJvV acknowledges the Slovenian Innovation and Research Agency (ARIS) for funding (Project No. J7-50041). R.D.Jv.V. and M.J. acknowledge ARIS for funding under the Research Core Funding Grant P1-0230, and the authors thank Mr. Bla&#x17E; Kisovec for technical assistance during the synthesis of the monomers. M.C. and Y.W. gratefully acknowledge funding from the Engineering and Physical Sciences Research Council (EPSRC), Grant number: EP/T007362/1 &#x201C;Novel polymers of intrinsic microporosity for heterogeneous base-catalyzed reactions (HBC-PIMs)&#x201D; and Swansea University. A.Z. acknowledges the Magnus Ehrnrooth Foundation for financial support. The authors acknowledge the financial support of the University of Helsinki and the use of ALD center Finland research infrastructure. Open access funding enabled and organized by Projekt DEAL.</funders><projectreference/><lastEdited>2024-12-05T15:39:17.9106558</lastEdited><Created>2024-12-05T15:30:13.0449491</Created><path><level id="1">Faculty of Science and Engineering</level><level id="2">School of Engineering and Applied Sciences - Chemistry</level></path><authors><author><firstname>Yuting</firstname><surname>Li</surname><orcid>0009-0006-0038-0965</orcid><order>1</order></author><author><firstname>Julian</firstname><surname>Br&#xFC;ckel</surname><orcid>0000-0002-0430-9801</orcid><order>2</order></author><author><firstname>Marjan</firstname><surname>Jereb</surname><orcid>0000-0002-1318-0560</orcid><order>3</order></author><author><firstname>An&#x17E;e</firstname><surname>Zupanc</surname><orcid>0000-0002-3697-7839</orcid><order>4</order></author><author><firstname>Sami&#x2010;Pekka</firstname><surname>Hirvonen</surname><orcid>0000-0002-3255-1558</orcid><order>5</order></author><author><firstname>Sami</firstname><surname>Hietala</surname><orcid>0000-0003-1448-1813</orcid><order>6</order></author><author><firstname>Marianna</firstname><surname>Kemell</surname><order>7</order></author><author><firstname>YUE</firstname><surname>WU</surname><order>8</order></author><author><firstname>Olaf</firstname><surname>Fuhr</surname><order>9</order></author><author><firstname>Ross D. Jansen&#x2010;van</firstname><surname>Vuuren</surname><orcid>0000-0002-2919-6962</orcid><order>10</order></author><author><firstname>Mariolino</firstname><surname>Carta</surname><orcid>0000-0003-0718-6971</orcid><order>11</order></author><author><firstname>Stefan</firstname><surname>Br&#xE4;se</surname><orcid>0000-0003-4845-3191</orcid><order>12</order></author></authors><documents/><OutputDurs/></rfc1807>
spelling 2024-12-05T15:39:17.9106558 v2 68471 2024-12-05 Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties a0ecf03ae879c40cd3740391e4af4f62 YUE WU YUE WU true false 56aebf2bba457f395149bbecbfa6d3eb 0000-0003-0718-6971 Mariolino Carta Mariolino Carta true false 2024-12-05 The unique structure of [2.2]paracyclophane (PCP) with its rigidity, stability, and planar chirality has gained significant attention in polymer and material research. In this work, the incorporation of amino‐functionalized PCPs within polymers of intrinsic microporosity (PIMs) is reported for the first time. Three different PCP‐PIMs were prepared via a Tröger's base formation mechanism, and their structures characterized via solid‐state NMR, MALDI‐TOF, and SEM. Their porosity was evaluated using gas adsorption (N2 and CO2) based on theoretical calculations such as Brunauer–Emmett–Teller (BET), NLDFT pore size distribution (PSD) and ideal IAST CO2/N2 selectivity (15/85), a crucial separation when considering the capture of CO2 from flue gas. The surface areas were found to be between 200–230 m2 g−1 while the selectivity for CO2/N2 ranged from 46 to 70. Journal Article Advanced Functional Materials 34 47 2401957 Wiley 1616-301X 1616-3028 Gas sorption, paracyclophanes, PIMs, polymers, porosity, Tröger’s base 19 11 2024 2024-11-19 10.1002/adfm.202401957 COLLEGE NANME COLLEGE CODE Swansea University Another institution paid the OA fee Y.L. receives funding from CSC scholarship 202208080097. J.B. thanks the Carl Zeiss Foundation for financial support and acknowledges funding by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany`s Excellence Strategy – 2082/1 – 390761711. RJvV acknowledges the Slovenian Innovation and Research Agency (ARIS) for funding (Project No. J7-50041). R.D.Jv.V. and M.J. acknowledge ARIS for funding under the Research Core Funding Grant P1-0230, and the authors thank Mr. Blaž Kisovec for technical assistance during the synthesis of the monomers. M.C. and Y.W. gratefully acknowledge funding from the Engineering and Physical Sciences Research Council (EPSRC), Grant number: EP/T007362/1 “Novel polymers of intrinsic microporosity for heterogeneous base-catalyzed reactions (HBC-PIMs)” and Swansea University. A.Z. acknowledges the Magnus Ehrnrooth Foundation for financial support. The authors acknowledge the financial support of the University of Helsinki and the use of ALD center Finland research infrastructure. Open access funding enabled and organized by Projekt DEAL. 2024-12-05T15:39:17.9106558 2024-12-05T15:30:13.0449491 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemistry Yuting Li 0009-0006-0038-0965 1 Julian Brückel 0000-0002-0430-9801 2 Marjan Jereb 0000-0002-1318-0560 3 Anže Zupanc 0000-0002-3697-7839 4 Sami‐Pekka Hirvonen 0000-0002-3255-1558 5 Sami Hietala 0000-0003-1448-1813 6 Marianna Kemell 7 YUE WU 8 Olaf Fuhr 9 Ross D. Jansen‐van Vuuren 0000-0002-2919-6962 10 Mariolino Carta 0000-0003-0718-6971 11 Stefan Bräse 0000-0003-4845-3191 12
title Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties
spellingShingle Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties
YUE WU
Mariolino Carta
title_short Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties
title_full Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties
title_fullStr Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties
title_full_unstemmed Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties
title_sort Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties
author_id_str_mv a0ecf03ae879c40cd3740391e4af4f62
56aebf2bba457f395149bbecbfa6d3eb
author_id_fullname_str_mv a0ecf03ae879c40cd3740391e4af4f62_***_YUE WU
56aebf2bba457f395149bbecbfa6d3eb_***_Mariolino Carta
author YUE WU
Mariolino Carta
author2 Yuting Li
Julian Brückel
Marjan Jereb
Anže Zupanc
Sami‐Pekka Hirvonen
Sami Hietala
Marianna Kemell
YUE WU
Olaf Fuhr
Ross D. Jansen‐van Vuuren
Mariolino Carta
Stefan Bräse
format Journal article
container_title Advanced Functional Materials
container_volume 34
container_issue 47
container_start_page 2401957
publishDate 2024
institution Swansea University
issn 1616-301X
1616-3028
doi_str_mv 10.1002/adfm.202401957
publisher Wiley
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Chemistry{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemistry
document_store_str 0
active_str 0
description The unique structure of [2.2]paracyclophane (PCP) with its rigidity, stability, and planar chirality has gained significant attention in polymer and material research. In this work, the incorporation of amino‐functionalized PCPs within polymers of intrinsic microporosity (PIMs) is reported for the first time. Three different PCP‐PIMs were prepared via a Tröger's base formation mechanism, and their structures characterized via solid‐state NMR, MALDI‐TOF, and SEM. Their porosity was evaluated using gas adsorption (N2 and CO2) based on theoretical calculations such as Brunauer–Emmett–Teller (BET), NLDFT pore size distribution (PSD) and ideal IAST CO2/N2 selectivity (15/85), a crucial separation when considering the capture of CO2 from flue gas. The surface areas were found to be between 200–230 m2 g−1 while the selectivity for CO2/N2 ranged from 46 to 70.
published_date 2024-11-19T05:36:48Z
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