Journal article 88 views
Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties
Advanced Functional Materials, Volume: 34, Issue: 47, Start page: 2401957
Swansea University Authors: YUE WU, Mariolino Carta
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DOI (Published version): 10.1002/adfm.202401957
Abstract
The unique structure of [2.2]paracyclophane (PCP) with its rigidity, stability, and planar chirality has gained significant attention in polymer and material research. In this work, the incorporation of amino‐functionalized PCPs within polymers of intrinsic microporosity (PIMs) is reported for the f...
Published in: | Advanced Functional Materials |
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ISSN: | 1616-301X 1616-3028 |
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Wiley
2024
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URI: | https://cronfa.swan.ac.uk/Record/cronfa68471 |
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2024-12-05T15:39:17.9106558 v2 68471 2024-12-05 Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties a0ecf03ae879c40cd3740391e4af4f62 YUE WU YUE WU true false 56aebf2bba457f395149bbecbfa6d3eb 0000-0003-0718-6971 Mariolino Carta Mariolino Carta true false 2024-12-05 The unique structure of [2.2]paracyclophane (PCP) with its rigidity, stability, and planar chirality has gained significant attention in polymer and material research. In this work, the incorporation of amino‐functionalized PCPs within polymers of intrinsic microporosity (PIMs) is reported for the first time. Three different PCP‐PIMs were prepared via a Tröger's base formation mechanism, and their structures characterized via solid‐state NMR, MALDI‐TOF, and SEM. Their porosity was evaluated using gas adsorption (N2 and CO2) based on theoretical calculations such as Brunauer–Emmett–Teller (BET), NLDFT pore size distribution (PSD) and ideal IAST CO2/N2 selectivity (15/85), a crucial separation when considering the capture of CO2 from flue gas. The surface areas were found to be between 200–230 m2 g−1 while the selectivity for CO2/N2 ranged from 46 to 70. Journal Article Advanced Functional Materials 34 47 2401957 Wiley 1616-301X 1616-3028 Gas sorption, paracyclophanes, PIMs, polymers, porosity, Tröger’s base 19 11 2024 2024-11-19 10.1002/adfm.202401957 COLLEGE NANME COLLEGE CODE Swansea University Another institution paid the OA fee Y.L. receives funding from CSC scholarship 202208080097. J.B. thanks the Carl Zeiss Foundation for financial support and acknowledges funding by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany`s Excellence Strategy – 2082/1 – 390761711. RJvV acknowledges the Slovenian Innovation and Research Agency (ARIS) for funding (Project No. J7-50041). R.D.Jv.V. and M.J. acknowledge ARIS for funding under the Research Core Funding Grant P1-0230, and the authors thank Mr. Blaž Kisovec for technical assistance during the synthesis of the monomers. M.C. and Y.W. gratefully acknowledge funding from the Engineering and Physical Sciences Research Council (EPSRC), Grant number: EP/T007362/1 “Novel polymers of intrinsic microporosity for heterogeneous base-catalyzed reactions (HBC-PIMs)” and Swansea University. A.Z. acknowledges the Magnus Ehrnrooth Foundation for financial support. The authors acknowledge the financial support of the University of Helsinki and the use of ALD center Finland research infrastructure. Open access funding enabled and organized by Projekt DEAL. 2024-12-05T15:39:17.9106558 2024-12-05T15:30:13.0449491 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemistry Yuting Li 0009-0006-0038-0965 1 Julian Brückel 0000-0002-0430-9801 2 Marjan Jereb 0000-0002-1318-0560 3 Anže Zupanc 0000-0002-3697-7839 4 Sami‐Pekka Hirvonen 0000-0002-3255-1558 5 Sami Hietala 0000-0003-1448-1813 6 Marianna Kemell 7 YUE WU 8 Olaf Fuhr 9 Ross D. Jansen‐van Vuuren 0000-0002-2919-6962 10 Mariolino Carta 0000-0003-0718-6971 11 Stefan Bräse 0000-0003-4845-3191 12 |
title |
Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties |
spellingShingle |
Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties YUE WU Mariolino Carta |
title_short |
Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties |
title_full |
Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties |
title_fullStr |
Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties |
title_full_unstemmed |
Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties |
title_sort |
Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties |
author_id_str_mv |
a0ecf03ae879c40cd3740391e4af4f62 56aebf2bba457f395149bbecbfa6d3eb |
author_id_fullname_str_mv |
a0ecf03ae879c40cd3740391e4af4f62_***_YUE WU 56aebf2bba457f395149bbecbfa6d3eb_***_Mariolino Carta |
author |
YUE WU Mariolino Carta |
author2 |
Yuting Li Julian Brückel Marjan Jereb Anže Zupanc Sami‐Pekka Hirvonen Sami Hietala Marianna Kemell YUE WU Olaf Fuhr Ross D. Jansen‐van Vuuren Mariolino Carta Stefan Bräse |
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Journal article |
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Advanced Functional Materials |
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34 |
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47 |
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2401957 |
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2024 |
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Swansea University |
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1616-301X 1616-3028 |
doi_str_mv |
10.1002/adfm.202401957 |
publisher |
Wiley |
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Faculty of Science and Engineering |
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facultyofscienceandengineering |
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Faculty of Science and Engineering |
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facultyofscienceandengineering |
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Faculty of Science and Engineering |
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School of Engineering and Applied Sciences - Chemistry{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemistry |
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description |
The unique structure of [2.2]paracyclophane (PCP) with its rigidity, stability, and planar chirality has gained significant attention in polymer and material research. In this work, the incorporation of amino‐functionalized PCPs within polymers of intrinsic microporosity (PIMs) is reported for the first time. Three different PCP‐PIMs were prepared via a Tröger's base formation mechanism, and their structures characterized via solid‐state NMR, MALDI‐TOF, and SEM. Their porosity was evaluated using gas adsorption (N2 and CO2) based on theoretical calculations such as Brunauer–Emmett–Teller (BET), NLDFT pore size distribution (PSD) and ideal IAST CO2/N2 selectivity (15/85), a crucial separation when considering the capture of CO2 from flue gas. The surface areas were found to be between 200–230 m2 g−1 while the selectivity for CO2/N2 ranged from 46 to 70. |
published_date |
2024-11-19T05:36:48Z |
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1822469766686703616 |
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11.048604 |