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A cost-effective alkaline polysulfide-air redox flow battery enabled by a dual-membrane cell architecture

Yuhua Xia, Mengzheng Ouyang, Vladimir Yufit, Rui Tan Orcid Logo, Anna Regoutz, Anqi Wang Orcid Logo, Wenjie Mao, Barun Chakrabarti Orcid Logo, Ashkan Kavei, Qilei Song Orcid Logo, Anthony R. Kucernak Orcid Logo, Nigel P. Brandon

Nature Communications, Volume: 13, Issue: 1

Swansea University Author: Rui Tan Orcid Logo

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DOI (Published version): 10.1038/s41467-022-30044-w

Abstract

With the rapid development of renewable energy harvesting technologies, there is a significant demand for long-duration energy storage technologies that can be deployed at grid scale. In this regard, polysulfide-air redox flow batteries demonstrated great potential. However, the crossover of polysul...

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Published in: Nature Communications
ISSN: 2041-1723
Published: Springer Science and Business Media LLC 2022
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URI: https://cronfa.swan.ac.uk/Record/cronfa67805
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Here, we report a stable and cost-effective alkaline-based hybrid polysulfide-air redox flow battery where a dual-membrane-structured flow cell design mitigates the sulfur crossover issue. Moreover, combining manganese/carbon catalysed air electrodes with sulfidised Ni foam polysulfide electrodes, the redox flow battery achieves a maximum power density of 5.8 mW cm&#x2212;2 at 50% state of charge and 55&#x2009;&#xB0;C. An average round-trip energy efficiency of 40% is also achieved over 80 cycles at 1 mA cm&#x2212;2. 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spelling 2024-10-18T12:04:22.3212023 v2 67805 2024-09-25 A cost-effective alkaline polysulfide-air redox flow battery enabled by a dual-membrane cell architecture 774c33a0a76a9152ca86a156b5ae26ff 0009-0001-9278-7327 Rui Tan Rui Tan true false 2024-09-25 EAAS With the rapid development of renewable energy harvesting technologies, there is a significant demand for long-duration energy storage technologies that can be deployed at grid scale. In this regard, polysulfide-air redox flow batteries demonstrated great potential. However, the crossover of polysulfide is one significant challenge. Here, we report a stable and cost-effective alkaline-based hybrid polysulfide-air redox flow battery where a dual-membrane-structured flow cell design mitigates the sulfur crossover issue. Moreover, combining manganese/carbon catalysed air electrodes with sulfidised Ni foam polysulfide electrodes, the redox flow battery achieves a maximum power density of 5.8 mW cm−2 at 50% state of charge and 55 °C. An average round-trip energy efficiency of 40% is also achieved over 80 cycles at 1 mA cm−2. Based on the performance reported, techno-economic analyses suggested that energy and power costs of about 2.5 US$/kWh and 1600 US$/kW, respectively, has be achieved for this type of alkaline polysulfide-air redox flow battery, with significant scope for further reduction. Journal Article Nature Communications 13 1 Springer Science and Business Media LLC 2041-1723 2 5 2022 2022-05-02 10.1038/s41467-022-30044-w COLLEGE NANME Engineering and Applied Sciences School COLLEGE CODE EAAS Swansea University Another institution paid the OA fee The authors gratefully acknowledge financial support from the EPSRC for projects EP/L014289/1 and EP/K002252/1. The authors would also like to thank RFC Power Ltd for the technical discussion. This project has received funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement no. 851272, ERC-StG-PE8-NanoMMES). R.T. acknowledges a full Ph.D. scholarship funded by the China Scholarship Council. A.R. acknowledges support from the Analytical Chemistry Trust Fund for her CAMS-UK Fellowship and from Imperial College London for her Imperial College Research Fellowship. 2024-10-18T12:04:22.3212023 2024-09-25T21:30:57.6544937 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemical Engineering Yuhua Xia 1 Mengzheng Ouyang 2 Vladimir Yufit 3 Rui Tan 0009-0001-9278-7327 4 Anna Regoutz 5 Anqi Wang 0000-0003-3409-823x 6 Wenjie Mao 7 Barun Chakrabarti 0000-0002-0172-986x 8 Ashkan Kavei 9 Qilei Song 0000-0001-8570-3626 10 Anthony R. Kucernak 0000-0002-5790-9683 11 Nigel P. Brandon 12 67805__32631__df4c713bd1a9435598acb0fca63f7718.pdf 67805.VoR.pdf 2024-10-18T11:21:04.7397096 Output 2159900 application/pdf Version of Record true © The Author(s) 2022. This article is licensed under a Creative Commons Attribution 4.0 International License. true eng http://creativecommons.org/licenses/by/4.0/
title A cost-effective alkaline polysulfide-air redox flow battery enabled by a dual-membrane cell architecture
spellingShingle A cost-effective alkaline polysulfide-air redox flow battery enabled by a dual-membrane cell architecture
Rui Tan
title_short A cost-effective alkaline polysulfide-air redox flow battery enabled by a dual-membrane cell architecture
title_full A cost-effective alkaline polysulfide-air redox flow battery enabled by a dual-membrane cell architecture
title_fullStr A cost-effective alkaline polysulfide-air redox flow battery enabled by a dual-membrane cell architecture
title_full_unstemmed A cost-effective alkaline polysulfide-air redox flow battery enabled by a dual-membrane cell architecture
title_sort A cost-effective alkaline polysulfide-air redox flow battery enabled by a dual-membrane cell architecture
author_id_str_mv 774c33a0a76a9152ca86a156b5ae26ff
author_id_fullname_str_mv 774c33a0a76a9152ca86a156b5ae26ff_***_Rui Tan
author Rui Tan
author2 Yuhua Xia
Mengzheng Ouyang
Vladimir Yufit
Rui Tan
Anna Regoutz
Anqi Wang
Wenjie Mao
Barun Chakrabarti
Ashkan Kavei
Qilei Song
Anthony R. Kucernak
Nigel P. Brandon
format Journal article
container_title Nature Communications
container_volume 13
container_issue 1
publishDate 2022
institution Swansea University
issn 2041-1723
doi_str_mv 10.1038/s41467-022-30044-w
publisher Springer Science and Business Media LLC
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Chemical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemical Engineering
document_store_str 0
active_str 0
description With the rapid development of renewable energy harvesting technologies, there is a significant demand for long-duration energy storage technologies that can be deployed at grid scale. In this regard, polysulfide-air redox flow batteries demonstrated great potential. However, the crossover of polysulfide is one significant challenge. Here, we report a stable and cost-effective alkaline-based hybrid polysulfide-air redox flow battery where a dual-membrane-structured flow cell design mitigates the sulfur crossover issue. Moreover, combining manganese/carbon catalysed air electrodes with sulfidised Ni foam polysulfide electrodes, the redox flow battery achieves a maximum power density of 5.8 mW cm−2 at 50% state of charge and 55 °C. An average round-trip energy efficiency of 40% is also achieved over 80 cycles at 1 mA cm−2. Based on the performance reported, techno-economic analyses suggested that energy and power costs of about 2.5 US$/kWh and 1600 US$/kW, respectively, has be achieved for this type of alkaline polysulfide-air redox flow battery, with significant scope for further reduction.
published_date 2022-05-02T08:34:49Z
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score 11.04748

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