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Mechanistic investigation on the influence of coating weights on the corrosion behaviour of hot-dip-galvanised Zn-Mg-Al coatings

Amar Malla Orcid Logo, James Sullivan Orcid Logo, David Penney Orcid Logo, M. Goldsworthy, D. Britton Orcid Logo, Geraint Williams Orcid Logo, F. Goodwin Orcid Logo, A. P. Cardoso Orcid Logo

npj Materials Degradation, Volume: 8, Issue: 1

Swansea University Authors: Amar Malla Orcid Logo, James Sullivan Orcid Logo, David Penney Orcid Logo, Geraint Williams Orcid Logo

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Abstract

Time-lapse Microscopy, scanning vibrating electrode technique and potentiodynamic methods were used to study the influence of increasing coating weight (80–310 gm–2) on microstructure, cut-edge and surface corrosion of Zn-Mg-Al coatings in 0.17 M NaCl. Cut-edge corrosion was similar for all coatings...

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Published in: npj Materials Degradation
ISSN: 2397-2106
Published: Springer Science and Business Media LLC 2024
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa67467
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Abstract: Time-lapse Microscopy, scanning vibrating electrode technique and potentiodynamic methods were used to study the influence of increasing coating weight (80–310 gm–2) on microstructure, cut-edge and surface corrosion of Zn-Mg-Al coatings in 0.17 M NaCl. Cut-edge corrosion was similar for all coatings due to the oxygen reduction reaction becoming diffusion-limited. A 64% reduction in surface corrosion was observed for high coating weights through increases in eutectic volume fraction. Spatial and temporal corrosion mechanisms were controlled by microstructural morphological differences as coating weight varied. 80 g.m–2 coatings demonstrated lateral anodic spreading potentially reducing coating penetration rates despite their higher surface corrosion rate.
College: Faculty of Science and Engineering
Funders: We would like to thank the Galvanized Autobody Partnership programme for funding and its associated members for their valuable input. The authors would also like to thank Tata Steel UK for providing samples.
Issue: 1