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Engineered charge transport layers for improving indoor perovskite photovoltaic performance

Ram Datt Orcid Logo, Pietro Caprioglio Orcid Logo, Saqlain Choudhary Orcid Logo, Weixia Lan Orcid Logo, Henry Snaith Orcid Logo, Wing Chung Tsoi Orcid Logo

Journal of Physics: Energy, Volume: 6, Issue: 2, Start page: 025014

Swansea University Authors: Ram Datt Orcid Logo, Wing Chung Tsoi Orcid Logo

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Abstract

The developing Internet of Things market is attracting the indoor photovoltaic (IPV) as an essential power source. Perovskite photovoltaics (PPVs) are a fascinating candidate for IPV in solution-processable photovoltaics. Recent developments in PPVs can deliver power conversion efficiency (PCE) up t...

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Published in: Journal of Physics: Energy
ISSN: 2515-7655
Published: IOP Publishing 2024
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URI: https://cronfa.swan.ac.uk/Record/cronfa66415
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Perovskite photovoltaics (PPVs) are a fascinating candidate for IPV in solution-processable photovoltaics. Recent developments in PPVs can deliver power conversion efficiency (PCE) up to 25% outdoor (AM 1.5 G) and over 40% under indoor (1000 lux) light. The selection of charge transport layers (CTLs) has played an essential role in improving PPVs indoor performance. Herein, formamidinium-caesium-based mixed-cation (FACsPb(I,Br)3) PPV devices are fabricated, and evaluated their outdoor and indoor performances by changing the different CTL combinations such as PTAA-PCBM and SAM-C60. Outdoor PCEs were 13.76% and 15.27% achieved for PTAA-PCBM and SAM-C60-based devices, respectively. Meanwhile, under LED (4000 K) 1000 lux, the PCEs were 26.32% and 31.92% for PTAA-PCBM and SAM-C60-based PPV, respectively. The short circuit current (Jsc) (116.8–122.5 µA cm−2) and fill factor (FF) (0.724–0.817) were the main parameters which improved for SAM-C60-based devices under indoor light. This study points to the importance of CTL combination and indicates the promising potential of SAM-C60 interlayers in PPV indoor applications.</abstract><type>Journal Article</type><journal>Journal of Physics: Energy</journal><volume>6</volume><journalNumber>2</journalNumber><paginationStart>025014</paginationStart><paginationEnd/><publisher>IOP Publishing</publisher><placeOfPublication/><isbnPrint/><isbnElectronic/><issnPrint/><issnElectronic>2515-7655</issnElectronic><keywords>perovskite solar cells, indoor photovoltaic, self-assembled monolayer, charge transport layers</keywords><publishedDay>1</publishedDay><publishedMonth>4</publishedMonth><publishedYear>2024</publishedYear><publishedDate>2024-04-01</publishedDate><doi>10.1088/2515-7655/ad31bb</doi><url/><notes/><college>COLLEGE NANME</college><department>Engineering and Applied Sciences School</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>EAAS</DepartmentCode><institution>Swansea University</institution><apcterm/><funders>R D sincerely acknowledges the SPECIFIC Innovation and Knowledge Centre (EP/N020863/1). W C T, H S, R D and P C acknowledged Engineering and Physics Science Research Council (EPSRC) Application Targeted And Integrated Photovoltaics (ATIP) (EP/T028513/1) Grant for providing financial support. 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spelling v2 66415 2024-05-14 Engineered charge transport layers for improving indoor perovskite photovoltaic performance 350d1f64ddd9787a6eda98611dcbb8d2 0000-0003-3109-1278 Ram Datt Ram Datt true false 7e5f541df6635a9a8e1a579ff2de5d56 0000-0003-3836-5139 Wing Chung Tsoi Wing Chung Tsoi true false 2024-05-14 EAAS The developing Internet of Things market is attracting the indoor photovoltaic (IPV) as an essential power source. Perovskite photovoltaics (PPVs) are a fascinating candidate for IPV in solution-processable photovoltaics. Recent developments in PPVs can deliver power conversion efficiency (PCE) up to 25% outdoor (AM 1.5 G) and over 40% under indoor (1000 lux) light. The selection of charge transport layers (CTLs) has played an essential role in improving PPVs indoor performance. Herein, formamidinium-caesium-based mixed-cation (FACsPb(I,Br)3) PPV devices are fabricated, and evaluated their outdoor and indoor performances by changing the different CTL combinations such as PTAA-PCBM and SAM-C60. Outdoor PCEs were 13.76% and 15.27% achieved for PTAA-PCBM and SAM-C60-based devices, respectively. Meanwhile, under LED (4000 K) 1000 lux, the PCEs were 26.32% and 31.92% for PTAA-PCBM and SAM-C60-based PPV, respectively. The short circuit current (Jsc) (116.8–122.5 µA cm−2) and fill factor (FF) (0.724–0.817) were the main parameters which improved for SAM-C60-based devices under indoor light. This study points to the importance of CTL combination and indicates the promising potential of SAM-C60 interlayers in PPV indoor applications. Journal Article Journal of Physics: Energy 6 2 025014 IOP Publishing 2515-7655 perovskite solar cells, indoor photovoltaic, self-assembled monolayer, charge transport layers 1 4 2024 2024-04-01 10.1088/2515-7655/ad31bb COLLEGE NANME Engineering and Applied Sciences School COLLEGE CODE EAAS Swansea University R D sincerely acknowledges the SPECIFIC Innovation and Knowledge Centre (EP/N020863/1). W C T, H S, R D and P C acknowledged Engineering and Physics Science Research Council (EPSRC) Application Targeted And Integrated Photovoltaics (ATIP) (EP/T028513/1) Grant for providing financial support. W C T and W L would like to acknowledge the Foreign Expert Foundation of China funding (G2023013014L). 2024-06-19T12:25:03.3870318 2024-05-14T12:42:32.8277856 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Ram Datt 0000-0003-3109-1278 1 Pietro Caprioglio 0000-0002-3465-2475 2 Saqlain Choudhary 0000-0002-6567-3121 3 Weixia Lan 0000-0003-0580-1715 4 Henry Snaith 0000-0001-8511-790x 5 Wing Chung Tsoi 0000-0003-3836-5139 6 66415__30357__d406aa3860e34cd081813149d8003947.pdf 66415.pdf 2024-05-14T12:44:26.3199378 Output 1118101 application/pdf Version of Record true Released under the terms of a Creative Commons Attribution License (CC-BY). true eng https://creativecommons.org/licenses/by/4.0/
title Engineered charge transport layers for improving indoor perovskite photovoltaic performance
spellingShingle Engineered charge transport layers for improving indoor perovskite photovoltaic performance
Ram Datt
Wing Chung Tsoi
title_short Engineered charge transport layers for improving indoor perovskite photovoltaic performance
title_full Engineered charge transport layers for improving indoor perovskite photovoltaic performance
title_fullStr Engineered charge transport layers for improving indoor perovskite photovoltaic performance
title_full_unstemmed Engineered charge transport layers for improving indoor perovskite photovoltaic performance
title_sort Engineered charge transport layers for improving indoor perovskite photovoltaic performance
author_id_str_mv 350d1f64ddd9787a6eda98611dcbb8d2
7e5f541df6635a9a8e1a579ff2de5d56
author_id_fullname_str_mv 350d1f64ddd9787a6eda98611dcbb8d2_***_Ram Datt
7e5f541df6635a9a8e1a579ff2de5d56_***_Wing Chung Tsoi
author Ram Datt
Wing Chung Tsoi
author2 Ram Datt
Pietro Caprioglio
Saqlain Choudhary
Weixia Lan
Henry Snaith
Wing Chung Tsoi
format Journal article
container_title Journal of Physics: Energy
container_volume 6
container_issue 2
container_start_page 025014
publishDate 2024
institution Swansea University
issn 2515-7655
doi_str_mv 10.1088/2515-7655/ad31bb
publisher IOP Publishing
college_str Faculty of Science and Engineering
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hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
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description The developing Internet of Things market is attracting the indoor photovoltaic (IPV) as an essential power source. Perovskite photovoltaics (PPVs) are a fascinating candidate for IPV in solution-processable photovoltaics. Recent developments in PPVs can deliver power conversion efficiency (PCE) up to 25% outdoor (AM 1.5 G) and over 40% under indoor (1000 lux) light. The selection of charge transport layers (CTLs) has played an essential role in improving PPVs indoor performance. Herein, formamidinium-caesium-based mixed-cation (FACsPb(I,Br)3) PPV devices are fabricated, and evaluated their outdoor and indoor performances by changing the different CTL combinations such as PTAA-PCBM and SAM-C60. Outdoor PCEs were 13.76% and 15.27% achieved for PTAA-PCBM and SAM-C60-based devices, respectively. Meanwhile, under LED (4000 K) 1000 lux, the PCEs were 26.32% and 31.92% for PTAA-PCBM and SAM-C60-based PPV, respectively. The short circuit current (Jsc) (116.8–122.5 µA cm−2) and fill factor (FF) (0.724–0.817) were the main parameters which improved for SAM-C60-based devices under indoor light. This study points to the importance of CTL combination and indicates the promising potential of SAM-C60 interlayers in PPV indoor applications.
published_date 2024-04-01T12:25:02Z
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