No Cover Image

Journal article 558 views 28 downloads

Stable dispersions of double-walled carbon nanotubes for carbon nanotube/copper co-deposition

Mauricio Pavía Orcid Logo, Mélanie Emo Orcid Logo, Fahad Alnjiman, Enrico Andreoli Orcid Logo, Jean-François Pierson, Emmanuel Flahaut Orcid Logo, Ewa Kazimierska Orcid Logo, Brigitte Vigolo Orcid Logo

Materials Chemistry and Physics, Volume: 299, Start page: 127491

Swansea University Author: Enrico Andreoli Orcid Logo

  • 62677.pdf

    PDF | Accepted Manuscript

    ©2023 All rights reserved. All article content, except where otherwise noted, is licensed under a Creative Commons Attribution Non-Commercial No Derivatives License (CC-BY-NC-ND)

    Download (2.38MB)

Check full text

DOI (Published version): 10.1016/j.matchemphys.2023.127491

Abstract

This work explores a novel approach to disperse purified double-walled carbon nanotubes in high ionic strength aqueous media, i.e. a copper ion solution to further prepare double-walled carbon nanotubes/Cu composites by co-electrodeposition. Firstly, the metal catalyst impurities in the tube samples...

Full description

Published in: Materials Chemistry and Physics
ISSN: 0254-0584
Published: Elsevier BV 2023
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa62677
first_indexed 2023-02-16T13:36:00Z
last_indexed 2024-11-14T12:21:24Z
id cronfa62677
recordtype SURis
fullrecord <?xml version="1.0"?><rfc1807><datestamp>2024-07-29T13:36:41.7985372</datestamp><bib-version>v2</bib-version><id>62677</id><entry>2023-02-16</entry><title>Stable dispersions of double-walled carbon nanotubes for carbon nanotube/copper co-deposition</title><swanseaauthors><author><sid>cbd843daab780bb55698a3daccd74df8</sid><ORCID>0000-0002-1207-2314</ORCID><firstname>Enrico</firstname><surname>Andreoli</surname><name>Enrico Andreoli</name><active>true</active><ethesisStudent>false</ethesisStudent></author></swanseaauthors><date>2023-02-16</date><deptcode>EAAS</deptcode><abstract>This work explores a novel approach to disperse purified double-walled carbon nanotubes in high ionic strength aqueous media, i.e. a copper ion solution to further prepare double-walled carbon nanotubes/Cu composites by co-electrodeposition. Firstly, the metal catalyst impurities in the tube samples are selectively removed by a one-pot gas-phase purification treatment. Two non-ionic (Triton X-100 and Pluronic-P123) and one anionic (sodium dodecyl sulfate) surfactant were used to disperse the purified samples by varying the carbon nanotubes/surfactant ratio and the surfactant content. Triton X-100 is a poly(ethylene glycol) in which one of the terminal hydroxy groups has been converted into the corresponding p-(2,4,4-trimethylpentan-3-yl)phenyl ether. Pluronic-P123 is a triblock copolymer comprising poly(ethylene oxide) (PEO) and poly(propylene oxide) (PPO) leading to PEO-PPO-PEO. Sodium dodecyl sulfate of chemical formula C12H25OSO2ONa possesses a sulfate head and a hydrocarbon tail. The capability of each surfactant to disperse the double-walled carbon nanotubes in the copper ion solution is analyzed and later discussed based on the nature of the inter-tube forces. Among the employed surfactants, Pluronic-P123 exhibits the best dispersive level since stable and homogenous suspensions of double-walled carbon nanotubes are obtained. The dispersion mechanism proposes that the hydrophobic nature of Pluronic-P123 promotes efficient steric repulsions allowing the stable dispersion in the copper electrolyte. The samples dispersed by this way are successfully co-deposited and they form well-distributed double-walled carbon nanotubes within the copper matrix. The obtained results are an important step on the way to achieving an efficient double-walled carbon nanotubes/Cu composite synthesized by electrodeposition means.</abstract><type>Journal Article</type><journal>Materials Chemistry and Physics</journal><volume>299</volume><journalNumber/><paginationStart>127491</paginationStart><paginationEnd/><publisher>Elsevier BV</publisher><placeOfPublication/><isbnPrint/><isbnElectronic/><issnPrint>0254-0584</issnPrint><issnElectronic/><keywords>Double-walled carbon nanotube; Dispersion; Surfactant; Co-electrodeposition; CNT-Cu composites</keywords><publishedDay>15</publishedDay><publishedMonth>4</publishedMonth><publishedYear>2023</publishedYear><publishedDate>2023-04-15</publishedDate><doi>10.1016/j.matchemphys.2023.127491</doi><url/><notes/><college>COLLEGE NANME</college><department>Engineering and Applied Sciences School</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>EAAS</DepartmentCode><institution>Swansea University</institution><apcterm/><funders>Partenariats Hubert Curien (PHC)/Campus France, PHC ALLIANCE - 2019 43237NB</funders><projectreference/><lastEdited>2024-07-29T13:36:41.7985372</lastEdited><Created>2023-02-16T13:31:56.3528990</Created><path><level id="1">Faculty of Science and Engineering</level><level id="2">School of Engineering and Applied Sciences - Chemical Engineering</level></path><authors><author><firstname>Mauricio</firstname><surname>Pav&#xED;a</surname><orcid>0000-0002-2776-126x</orcid><order>1</order></author><author><firstname>M&#xE9;lanie</firstname><surname>Emo</surname><orcid>0000-0003-3599-6824</orcid><order>2</order></author><author><firstname>Fahad</firstname><surname>Alnjiman</surname><order>3</order></author><author><firstname>Enrico</firstname><surname>Andreoli</surname><orcid>0000-0002-1207-2314</orcid><order>4</order></author><author><firstname>Jean-Fran&#xE7;ois</firstname><surname>Pierson</surname><order>5</order></author><author><firstname>Emmanuel</firstname><surname>Flahaut</surname><orcid>0000-0001-8344-6902</orcid><order>6</order></author><author><firstname>Ewa</firstname><surname>Kazimierska</surname><orcid>0000-0002-1915-1998</orcid><order>7</order></author><author><firstname>Brigitte</firstname><surname>Vigolo</surname><orcid>0000-0002-1463-0121</orcid><order>8</order></author></authors><documents><document><filename>62677__26598__8a1bce83fb8742f6bad6b797e2e740c6.pdf</filename><originalFilename>62677.pdf</originalFilename><uploaded>2023-02-16T13:34:23.9495456</uploaded><type>Output</type><contentLength>2492260</contentLength><contentType>application/pdf</contentType><version>Accepted Manuscript</version><cronfaStatus>true</cronfaStatus><embargoDate>2024-02-13T00:00:00.0000000</embargoDate><documentNotes>&#xA9;2023 All rights reserved. All article content, except where otherwise noted, is licensed under a Creative Commons Attribution Non-Commercial No Derivatives License (CC-BY-NC-ND)</documentNotes><copyrightCorrect>true</copyrightCorrect><language>eng</language><licence>https://creativecommons.org/licenses/by-nc-nd/4.0/</licence></document></documents><OutputDurs/></rfc1807>
spelling 2024-07-29T13:36:41.7985372 v2 62677 2023-02-16 Stable dispersions of double-walled carbon nanotubes for carbon nanotube/copper co-deposition cbd843daab780bb55698a3daccd74df8 0000-0002-1207-2314 Enrico Andreoli Enrico Andreoli true false 2023-02-16 EAAS This work explores a novel approach to disperse purified double-walled carbon nanotubes in high ionic strength aqueous media, i.e. a copper ion solution to further prepare double-walled carbon nanotubes/Cu composites by co-electrodeposition. Firstly, the metal catalyst impurities in the tube samples are selectively removed by a one-pot gas-phase purification treatment. Two non-ionic (Triton X-100 and Pluronic-P123) and one anionic (sodium dodecyl sulfate) surfactant were used to disperse the purified samples by varying the carbon nanotubes/surfactant ratio and the surfactant content. Triton X-100 is a poly(ethylene glycol) in which one of the terminal hydroxy groups has been converted into the corresponding p-(2,4,4-trimethylpentan-3-yl)phenyl ether. Pluronic-P123 is a triblock copolymer comprising poly(ethylene oxide) (PEO) and poly(propylene oxide) (PPO) leading to PEO-PPO-PEO. Sodium dodecyl sulfate of chemical formula C12H25OSO2ONa possesses a sulfate head and a hydrocarbon tail. The capability of each surfactant to disperse the double-walled carbon nanotubes in the copper ion solution is analyzed and later discussed based on the nature of the inter-tube forces. Among the employed surfactants, Pluronic-P123 exhibits the best dispersive level since stable and homogenous suspensions of double-walled carbon nanotubes are obtained. The dispersion mechanism proposes that the hydrophobic nature of Pluronic-P123 promotes efficient steric repulsions allowing the stable dispersion in the copper electrolyte. The samples dispersed by this way are successfully co-deposited and they form well-distributed double-walled carbon nanotubes within the copper matrix. The obtained results are an important step on the way to achieving an efficient double-walled carbon nanotubes/Cu composite synthesized by electrodeposition means. Journal Article Materials Chemistry and Physics 299 127491 Elsevier BV 0254-0584 Double-walled carbon nanotube; Dispersion; Surfactant; Co-electrodeposition; CNT-Cu composites 15 4 2023 2023-04-15 10.1016/j.matchemphys.2023.127491 COLLEGE NANME Engineering and Applied Sciences School COLLEGE CODE EAAS Swansea University Partenariats Hubert Curien (PHC)/Campus France, PHC ALLIANCE - 2019 43237NB 2024-07-29T13:36:41.7985372 2023-02-16T13:31:56.3528990 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemical Engineering Mauricio Pavía 0000-0002-2776-126x 1 Mélanie Emo 0000-0003-3599-6824 2 Fahad Alnjiman 3 Enrico Andreoli 0000-0002-1207-2314 4 Jean-François Pierson 5 Emmanuel Flahaut 0000-0001-8344-6902 6 Ewa Kazimierska 0000-0002-1915-1998 7 Brigitte Vigolo 0000-0002-1463-0121 8 62677__26598__8a1bce83fb8742f6bad6b797e2e740c6.pdf 62677.pdf 2023-02-16T13:34:23.9495456 Output 2492260 application/pdf Accepted Manuscript true 2024-02-13T00:00:00.0000000 ©2023 All rights reserved. All article content, except where otherwise noted, is licensed under a Creative Commons Attribution Non-Commercial No Derivatives License (CC-BY-NC-ND) true eng https://creativecommons.org/licenses/by-nc-nd/4.0/
title Stable dispersions of double-walled carbon nanotubes for carbon nanotube/copper co-deposition
spellingShingle Stable dispersions of double-walled carbon nanotubes for carbon nanotube/copper co-deposition
Enrico Andreoli
title_short Stable dispersions of double-walled carbon nanotubes for carbon nanotube/copper co-deposition
title_full Stable dispersions of double-walled carbon nanotubes for carbon nanotube/copper co-deposition
title_fullStr Stable dispersions of double-walled carbon nanotubes for carbon nanotube/copper co-deposition
title_full_unstemmed Stable dispersions of double-walled carbon nanotubes for carbon nanotube/copper co-deposition
title_sort Stable dispersions of double-walled carbon nanotubes for carbon nanotube/copper co-deposition
author_id_str_mv cbd843daab780bb55698a3daccd74df8
author_id_fullname_str_mv cbd843daab780bb55698a3daccd74df8_***_Enrico Andreoli
author Enrico Andreoli
author2 Mauricio Pavía
Mélanie Emo
Fahad Alnjiman
Enrico Andreoli
Jean-François Pierson
Emmanuel Flahaut
Ewa Kazimierska
Brigitte Vigolo
format Journal article
container_title Materials Chemistry and Physics
container_volume 299
container_start_page 127491
publishDate 2023
institution Swansea University
issn 0254-0584
doi_str_mv 10.1016/j.matchemphys.2023.127491
publisher Elsevier BV
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Chemical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemical Engineering
document_store_str 1
active_str 0
description This work explores a novel approach to disperse purified double-walled carbon nanotubes in high ionic strength aqueous media, i.e. a copper ion solution to further prepare double-walled carbon nanotubes/Cu composites by co-electrodeposition. Firstly, the metal catalyst impurities in the tube samples are selectively removed by a one-pot gas-phase purification treatment. Two non-ionic (Triton X-100 and Pluronic-P123) and one anionic (sodium dodecyl sulfate) surfactant were used to disperse the purified samples by varying the carbon nanotubes/surfactant ratio and the surfactant content. Triton X-100 is a poly(ethylene glycol) in which one of the terminal hydroxy groups has been converted into the corresponding p-(2,4,4-trimethylpentan-3-yl)phenyl ether. Pluronic-P123 is a triblock copolymer comprising poly(ethylene oxide) (PEO) and poly(propylene oxide) (PPO) leading to PEO-PPO-PEO. Sodium dodecyl sulfate of chemical formula C12H25OSO2ONa possesses a sulfate head and a hydrocarbon tail. The capability of each surfactant to disperse the double-walled carbon nanotubes in the copper ion solution is analyzed and later discussed based on the nature of the inter-tube forces. Among the employed surfactants, Pluronic-P123 exhibits the best dispersive level since stable and homogenous suspensions of double-walled carbon nanotubes are obtained. The dispersion mechanism proposes that the hydrophobic nature of Pluronic-P123 promotes efficient steric repulsions allowing the stable dispersion in the copper electrolyte. The samples dispersed by this way are successfully co-deposited and they form well-distributed double-walled carbon nanotubes within the copper matrix. The obtained results are an important step on the way to achieving an efficient double-walled carbon nanotubes/Cu composite synthesized by electrodeposition means.
published_date 2023-04-15T12:27:00Z
_version_ 1827206616499355648
score 10.905153

Similar Items