Role of Smart-Release Pigments in Preventing Corrosion Driven Cathodic Disbondment of Organically Coated Hot Dip Galvanised Steel

Ansell, Philip; Berry, Lewis; McGettrick, James; Searle, Justin; Wint, Natalie; McMurray, Hamilton; Williams, Geraint

doi:10.1149/1945-7111/aca8d2

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Role of Smart-Release Pigments in Preventing Corrosion Driven Cathodic Disbondment of Organically Coated Hot Dip Galvanised Steel

Philip Ansell, Lewis Berry, James McGettrick

, Justin Searle

, Natalie Wint, Hamilton McMurray, Geraint Williams

Journal of The Electrochemical Society, Volume: 170, Issue: 1, Start page: 011502

Swansea University Authors: Philip Ansell, Lewis Berry, James McGettrick , Justin Searle , Natalie Wint, Hamilton McMurray, Geraint Williams

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DOI (Published version): 10.1149/1945-7111/aca8d2

Abstract

The role of smart-release corrosion inhibitive pigments in preventing cathodic delamination of organically coated hot-dip galvanized steel (HDG) is investigated. The pigments consisted of hydrotalcite (HT) exchanged with a range of inorganic and organic anionic species and were dispersed in a model...

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Published in:	Journal of The Electrochemical Society
ISSN:	0013-4651 1945-7111
Published:	The Electrochemical Society 2023
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URI:	https://cronfa.swan.ac.uk/Record/cronfa62641
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The pigments consisted of hydrotalcite (HT) exchanged with a range of inorganic and organic anionic species and were dispersed in a model PVB coating. A scanning Kelvin probe (SKP) technique was used to determine cathodic delamination rates, and the inhibition efficiencies obtained for inorganic ions increased in the order ${{{\rm{CO}}}_{3}}^{2-}$ < ${{{\rm{MoO}}}_{4}}^{2-}$ < ${{{\rm{NO}}}_{3}}^{-}$ < ${{{\rm{VO}}}_{4}}^{3-}$ < ${{{\rm{WO}}}_{4}}^{2-}$ < ${{{\rm{PO}}}_{4}}^{3-}$ < ${{{\rm{CrO}}}_{4}}^{2-}.$ The inhibition efficiencies for organic-based pigments increased in the order triazole <phenylphosphonate <trans-cinnamate <benzoate <salicylate <benzotriazole. The inhibition efficiency afforded by the best performing organic inhibitor, benzotriazole (BTA), rivalled that of HT containing stored chromate anions. Findings are consistent with HT-BTA acting to sequester anions from the underfilm electrolyte, releasing BTA− which subsequently strongly adsorbs on the underfilm metal surface but can also form an insoluble Zn-BTA precipitate at the coating-defect boundary.</abstract><type>Journal Article</type><journal>Journal of The Electrochemical Society</journal><volume>170</volume><journalNumber>1</journalNumber><paginationStart>011502</paginationStart><paginationEnd/><publisher>The Electrochemical Society</publisher><placeOfPublication/><isbnPrint/><isbnElectronic/><issnPrint>0013-4651</issnPrint><issnElectronic>1945-7111</issnElectronic><keywords/><publishedDay>20</publishedDay><publishedMonth>1</publishedMonth><publishedYear>2023</publishedYear><publishedDate>2023-01-20</publishedDate><doi>10.1149/1945-7111/aca8d2</doi><url/><notes/><college>COLLEGE NANME</college><department>Materials Science and Engineering</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>MTLS</DepartmentCode><institution>Swansea University</institution><apcterm/><funders>The authors would like to thank TATA Steel for providing the samples and EPSRC for the funding of the EngD studentships via the Collaborate Training Account (GR/T11333/01). 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spelling	2023-03-06T14:10:38.8512222 v2 62641 2023-02-09 Role of Smart-Release Pigments in Preventing Corrosion Driven Cathodic Disbondment of Organically Coated Hot Dip Galvanised Steel 8889433e9478f045d656ce784a9d79ed Philip Ansell Philip Ansell true false 48265de72365e3eca788ec3cc1209ab4 Lewis Berry Lewis Berry true false bdbacc591e2de05180e0fd3cc13fa480 0000-0002-7719-2958 James McGettrick James McGettrick true false 0e3f2c3812f181eaed11c45554d4cdd0 0000-0003-1101-075X Justin Searle Justin Searle true false 5be5dcc4b97c78b3063e258add4fff5c Natalie Wint Natalie Wint true false 56fc1b17ffc3bdf6039dc05c6eba7f2a Hamilton McMurray Hamilton McMurray true false 0d8fc8d44e2a3c88ce61832f66f20d82 0000-0002-3399-5142 Geraint Williams Geraint Williams true false 2023-02-09 MTLS The role of smart-release corrosion inhibitive pigments in preventing cathodic delamination of organically coated hot-dip galvanized steel (HDG) is investigated. The pigments consisted of hydrotalcite (HT) exchanged with a range of inorganic and organic anionic species and were dispersed in a model PVB coating. A scanning Kelvin probe (SKP) technique was used to determine cathodic delamination rates, and the inhibition efficiencies obtained for inorganic ions increased in the order ${{{\rm{CO}}}_{3}}^{2-}$ < ${{{\rm{MoO}}}_{4}}^{2-}$ < ${{{\rm{NO}}}_{3}}^{-}$ < ${{{\rm{VO}}}_{4}}^{3-}$ < ${{{\rm{WO}}}_{4}}^{2-}$ < ${{{\rm{PO}}}_{4}}^{3-}$ < ${{{\rm{CrO}}}_{4}}^{2-}.$ The inhibition efficiencies for organic-based pigments increased in the order triazole <phenylphosphonate <trans-cinnamate <benzoate <salicylate <benzotriazole. The inhibition efficiency afforded by the best performing organic inhibitor, benzotriazole (BTA), rivalled that of HT containing stored chromate anions. Findings are consistent with HT-BTA acting to sequester anions from the underfilm electrolyte, releasing BTA− which subsequently strongly adsorbs on the underfilm metal surface but can also form an insoluble Zn-BTA precipitate at the coating-defect boundary. Journal Article Journal of The Electrochemical Society 170 1 011502 The Electrochemical Society 0013-4651 1945-7111 20 1 2023 2023-01-20 10.1149/1945-7111/aca8d2 COLLEGE NANME Materials Science and Engineering COLLEGE CODE MTLS Swansea University The authors would like to thank TATA Steel for providing the samples and EPSRC for the funding of the EngD studentships via the Collaborate Training Account (GR/T11333/01). We would also like to acknowledge the assistance provided by Swansea University College of Engineering AIM Facility, which was funded in part by the EPSRC (EP/M028267/1), the European Regional Development Fund through the Welsh Government (80708) and the Ser Solar project via Welsh Government. Furthermore, we would like to thank everyone at SPECIFIC IKC which was funded by WEFO (c80892) and EPSRC (EP/N020863/1) for their help support and guidance. 2023-03-06T14:10:38.8512222 2023-02-09T15:08:21.6300171 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Philip Ansell 1 Lewis Berry 2 James McGettrick 0000-0002-7719-2958 3 Justin Searle 0000-0003-1101-075X 4 Natalie Wint 5 Hamilton McMurray 6 Geraint Williams 0000-0002-3399-5142 7 62641__26516__3680e381f3a741f8a95129966da175b9.pdf 62641.pdf 2023-02-09T15:12:46.0339238 Output 2229702 application/pdf Version of Record true This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License true eng http://creativecommons.org/licenses/by/4.0/
title	Role of Smart-Release Pigments in Preventing Corrosion Driven Cathodic Disbondment of Organically Coated Hot Dip Galvanised Steel
spellingShingle	Role of Smart-Release Pigments in Preventing Corrosion Driven Cathodic Disbondment of Organically Coated Hot Dip Galvanised Steel Philip Ansell Lewis Berry James McGettrick Justin Searle Natalie Wint Hamilton McMurray Geraint Williams
title_short	Role of Smart-Release Pigments in Preventing Corrosion Driven Cathodic Disbondment of Organically Coated Hot Dip Galvanised Steel
title_full	Role of Smart-Release Pigments in Preventing Corrosion Driven Cathodic Disbondment of Organically Coated Hot Dip Galvanised Steel
title_fullStr	Role of Smart-Release Pigments in Preventing Corrosion Driven Cathodic Disbondment of Organically Coated Hot Dip Galvanised Steel
title_full_unstemmed	Role of Smart-Release Pigments in Preventing Corrosion Driven Cathodic Disbondment of Organically Coated Hot Dip Galvanised Steel
title_sort	Role of Smart-Release Pigments in Preventing Corrosion Driven Cathodic Disbondment of Organically Coated Hot Dip Galvanised Steel
author_id_str_mv	8889433e9478f045d656ce784a9d79ed 48265de72365e3eca788ec3cc1209ab4 bdbacc591e2de05180e0fd3cc13fa480 0e3f2c3812f181eaed11c45554d4cdd0 5be5dcc4b97c78b3063e258add4fff5c 56fc1b17ffc3bdf6039dc05c6eba7f2a 0d8fc8d44e2a3c88ce61832f66f20d82
author_id_fullname_str_mv	8889433e9478f045d656ce784a9d79ed_*_Philip Ansell 48265de72365e3eca788ec3cc1209ab4__Lewis Berry bdbacc591e2de05180e0fd3cc13fa480__James McGettrick 0e3f2c3812f181eaed11c45554d4cdd0__Justin Searle 5be5dcc4b97c78b3063e258add4fff5c__Natalie Wint 56fc1b17ffc3bdf6039dc05c6eba7f2a__Hamilton McMurray 0d8fc8d44e2a3c88ce61832f66f20d82_**_Geraint Williams
author	Philip Ansell Lewis Berry James McGettrick Justin Searle Natalie Wint Hamilton McMurray Geraint Williams
author2	Philip Ansell Lewis Berry James McGettrick Justin Searle Natalie Wint Hamilton McMurray Geraint Williams
format	Journal article
container_title	Journal of The Electrochemical Society
container_volume	170
container_issue	1
container_start_page	011502
publishDate	2023
institution	Swansea University
issn	0013-4651 1945-7111
doi_str_mv	10.1149/1945-7111/aca8d2
publisher	The Electrochemical Society
college_str	Faculty of Science and Engineering
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hierarchy_top_id	facultyofscienceandengineering
hierarchy_top_title	Faculty of Science and Engineering
hierarchy_parent_id	facultyofscienceandengineering
hierarchy_parent_title	Faculty of Science and Engineering
department_str	School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
document_store_str	1
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description	The role of smart-release corrosion inhibitive pigments in preventing cathodic delamination of organically coated hot-dip galvanized steel (HDG) is investigated. The pigments consisted of hydrotalcite (HT) exchanged with a range of inorganic and organic anionic species and were dispersed in a model PVB coating. A scanning Kelvin probe (SKP) technique was used to determine cathodic delamination rates, and the inhibition efficiencies obtained for inorganic ions increased in the order ${{{\rm{CO}}}_{3}}^{2-}$ < ${{{\rm{MoO}}}_{4}}^{2-}$ < ${{{\rm{NO}}}_{3}}^{-}$ < ${{{\rm{VO}}}_{4}}^{3-}$ < ${{{\rm{WO}}}_{4}}^{2-}$ < ${{{\rm{PO}}}_{4}}^{3-}$ < ${{{\rm{CrO}}}_{4}}^{2-}.$ The inhibition efficiencies for organic-based pigments increased in the order triazole <phenylphosphonate <trans-cinnamate <benzoate <salicylate <benzotriazole. The inhibition efficiency afforded by the best performing organic inhibitor, benzotriazole (BTA), rivalled that of HT containing stored chromate anions. Findings are consistent with HT-BTA acting to sequester anions from the underfilm electrolyte, releasing BTA− which subsequently strongly adsorbs on the underfilm metal surface but can also form an insoluble Zn-BTA precipitate at the coating-defect boundary.
published_date	2023-01-20T04:22:25Z
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score	11.013037

Role of Smart-Release Pigments in Preventing Corrosion Driven Cathodic Disbondment of Organically Coated Hot Dip Galvanised Steel

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