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Highly efficient p-i-n perovskite solar cells that endure temperature variations

Guixiang Li Orcid Logo, Zhenhuang Su Orcid Logo, Laura Canil Orcid Logo, Declan Hughes Orcid Logo, Mahmoud H. Aldamasy Orcid Logo, Janardan Dagar Orcid Logo, Sergei Trofimov Orcid Logo, Luyao Wang Orcid Logo, Weiwei Zuo Orcid Logo, José J. Jerónimo-Rendon Orcid Logo, Mahdi Malekshahi Byranvand Orcid Logo, Chenyue Wang, Rui Zhu, Zuhong Zhang, Feng Yang Orcid Logo, Giuseppe Nasti Orcid Logo, Boris Naydenov Orcid Logo, Wing Chung Tsoi Orcid Logo, Zhe Li, Xingyu Gao Orcid Logo, Zhaokui Wang Orcid Logo, Yu Jia, Eva Unger Orcid Logo, Michael Saliba Orcid Logo, Meng Li Orcid Logo, Antonio Abate Orcid Logo

Science, Volume: 379, Issue: 6630, Pages: 399 - 403

Swansea University Authors: Declan Hughes Orcid Logo, Wing Chung Tsoi Orcid Logo

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DOI (Published version): 10.1126/science.add7331

Abstract

Daily temperature variations induce phase transitions and lattice strains in halide perovskites, challenging their stability in solar cells. We stabilised the perovskite black phase and improved the solar cell performance using the ordered dipolar structure of β-poly(1,1-difluoroethylene) to control...

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Published in: Science
ISSN: 0036-8075 1095-9203
Published: American Association for the Advancement of Science (AAAS) 2023
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URI: https://cronfa.swan.ac.uk/Record/cronfa62477
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We stabilised the perovskite black phase and improved the solar cell performance using the ordered dipolar structure of &#x3B2;-poly(1,1-difluoroethylene) to control the perovskite film crystallisation and the energy alignment. We demonstrated p-i-n perovskite solar cells with a record power conversion efficiency of 24.6% over 18 square millimetres and 23.1% over 1 square centimetre, which retained 96% and 88% of the efficiency after 1000-hours 1-sun maximum power point tracking at 25 and 75 &#xB0;C, respectively. Devices under rapid thermal cycling between &#x2212;60 &#xB0;C and +80 &#xB0;C showed no sign of fatigue, demonstrating the impact of the ordered dipolar structure on the operational stability of perovskite solar cells.</abstract><type>Journal Article</type><journal>Science</journal><volume>379</volume><journalNumber>6630</journalNumber><paginationStart>399</paginationStart><paginationEnd>403</paginationEnd><publisher>American Association for the Advancement of Science (AAAS)</publisher><placeOfPublication/><isbnPrint/><isbnElectronic/><issnPrint>0036-8075</issnPrint><issnElectronic>1095-9203</issnElectronic><keywords/><publishedDay>27</publishedDay><publishedMonth>1</publishedMonth><publishedYear>2023</publishedYear><publishedDate>2023-01-27</publishedDate><doi>10.1126/science.add7331</doi><url/><notes/><college>COLLEGE NANME</college><department>Materials Science and Engineering</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>MTLS</DepartmentCode><institution>Swansea University</institution><apcterm/><funders>The authors acknowledge the support of all the technicians at Helmholtz-Zentrum Berlin (HZB). The authors thank beamline BL14B1 at the Shanghai Synchrotron Radiation Facility (SSRF) for providing the beam time. G.L., L.C., and M.H.A. thank the support from HyPerCells graduate school at HZB. R.Z. was supported by the National Natural Science Foundation of China (22103022). G.L. thanks the Chinese Scholarship Council (CSC) for its financial support (201906150131). M.S. and W.Z. thank the German Research Foundation (DFG) for funding (SPP2196, 431314977/GRK 2642). M.S. acknowledges funding by ProperPhotoMile. Project ProperPhotoMile is supported under the umbrella of SOLAR-ERA.NET Cofund 2 by the Spanish Ministry of Science and Education and the AEI under the project PCI2020-112185 and CDTI project number IDI-20210171; the Federal Ministry for Economic Affairs and Energy based on a decision by the German Bundestag project number FKZ 03EE1070B and FKZ 03EE1070A and the Israel Ministry of Energy with project number 220-11-031. The European Commission supports SOLAR-ERA.NET within the EU Framework Programme for Research and Innovation HORIZON 2020 (Cofund ERA-NET Action, 786483). This work has received funding from the European Research Council (ERC) under the European Union&#x2019;s Horizon 2020 research and innovation programme (grant agreement 804519).</funders><projectreference/><lastEdited>2023-03-03T14:49:22.9308867</lastEdited><Created>2023-02-01T11:30:01.4086226</Created><path><level id="1">Faculty of Science and Engineering</level><level id="2">School of Engineering and Applied Sciences - Materials Science and Engineering</level></path><authors><author><firstname>Guixiang</firstname><surname>Li</surname><orcid>0000-0002-8730-0713</orcid><order>1</order></author><author><firstname>Zhenhuang</firstname><surname>Su</surname><orcid>0000-0003-0026-2601</orcid><order>2</order></author><author><firstname>Laura</firstname><surname>Canil</surname><orcid>0000-0003-4151-756x</orcid><order>3</order></author><author><firstname>Declan</firstname><surname>Hughes</surname><orcid>0000-0001-6415-3717</orcid><order>4</order></author><author><firstname>Mahmoud H.</firstname><surname>Aldamasy</surname><orcid>0000-0003-3331-5570</orcid><order>5</order></author><author><firstname>Janardan</firstname><surname>Dagar</surname><orcid>0000-0003-4102-3818</orcid><order>6</order></author><author><firstname>Sergei</firstname><surname>Trofimov</surname><orcid>0000-0002-9718-2845</orcid><order>7</order></author><author><firstname>Luyao</firstname><surname>Wang</surname><orcid>0000-0003-0917-1749</orcid><order>8</order></author><author><firstname>Weiwei</firstname><surname>Zuo</surname><orcid>0000-0002-9135-1628</orcid><order>9</order></author><author><firstname>Jos&#xE9; J.</firstname><surname>Jer&#xF3;nimo-Rendon</surname><orcid>0000-0003-3981-2412</orcid><order>10</order></author><author><firstname>Mahdi Malekshahi</firstname><surname>Byranvand</surname><orcid>0000-0001-6250-6005</orcid><order>11</order></author><author><firstname>Chenyue</firstname><surname>Wang</surname><order>12</order></author><author><firstname>Rui</firstname><surname>Zhu</surname><order>13</order></author><author><firstname>Zuhong</firstname><surname>Zhang</surname><order>14</order></author><author><firstname>Feng</firstname><surname>Yang</surname><orcid>0000-0003-0189-8038</orcid><order>15</order></author><author><firstname>Giuseppe</firstname><surname>Nasti</surname><orcid>0000-0003-0867-2402</orcid><order>16</order></author><author><firstname>Boris</firstname><surname>Naydenov</surname><orcid>0000-0002-5215-3880</orcid><order>17</order></author><author><firstname>Wing Chung</firstname><surname>Tsoi</surname><orcid>0000-0003-3836-5139</orcid><order>18</order></author><author><firstname>Zhe</firstname><surname>Li</surname><order>19</order></author><author><firstname>Xingyu</firstname><surname>Gao</surname><orcid>0000-0003-1477-0092</orcid><order>20</order></author><author><firstname>Zhaokui</firstname><surname>Wang</surname><orcid>0000-0003-1707-499x</orcid><order>21</order></author><author><firstname>Yu</firstname><surname>Jia</surname><order>22</order></author><author><firstname>Eva</firstname><surname>Unger</surname><orcid>0000-0002-3343-867x</orcid><order>23</order></author><author><firstname>Michael</firstname><surname>Saliba</surname><orcid>0000-0002-6818-9781</orcid><order>24</order></author><author><firstname>Meng</firstname><surname>Li</surname><orcid>0000-0003-0360-7791</orcid><order>25</order></author><author><firstname>Antonio</firstname><surname>Abate</surname><orcid>0000-0002-3012-3541</orcid><order>26</order></author></authors><documents><document><filename>62477__26444__eb1b921aa7ef44fd8aefd71b14400751.pdf</filename><originalFilename>62477_supp.pdf</originalFilename><uploaded>2023-02-01T11:40:08.9530937</uploaded><type>Output</type><contentLength>3578514</contentLength><contentType>application/pdf</contentType><version>Supplemental material</version><cronfaStatus>true</cronfaStatus><copyrightCorrect>true</copyrightCorrect><language>eng</language></document><document><filename>62477__26443__16b7308393db4a17b0a3288b49fc5b93.pdf</filename><originalFilename>62477.pdf</originalFilename><uploaded>2023-02-01T11:39:49.6922494</uploaded><type>Output</type><contentLength>1553545</contentLength><contentType>application/pdf</contentType><version>Accepted Manuscript</version><cronfaStatus>true</cronfaStatus><copyrightCorrect>true</copyrightCorrect><language>eng</language></document></documents><OutputDurs/></rfc1807>
spelling 2023-03-03T14:49:22.9308867 v2 62477 2023-02-01 Highly efficient p-i-n perovskite solar cells that endure temperature variations 5590b62d833b89a43926267b2b7a5c29 0000-0001-6415-3717 Declan Hughes Declan Hughes true false 7e5f541df6635a9a8e1a579ff2de5d56 0000-0003-3836-5139 Wing Chung Tsoi Wing Chung Tsoi true false 2023-02-01 MTLS Daily temperature variations induce phase transitions and lattice strains in halide perovskites, challenging their stability in solar cells. We stabilised the perovskite black phase and improved the solar cell performance using the ordered dipolar structure of β-poly(1,1-difluoroethylene) to control the perovskite film crystallisation and the energy alignment. We demonstrated p-i-n perovskite solar cells with a record power conversion efficiency of 24.6% over 18 square millimetres and 23.1% over 1 square centimetre, which retained 96% and 88% of the efficiency after 1000-hours 1-sun maximum power point tracking at 25 and 75 °C, respectively. Devices under rapid thermal cycling between −60 °C and +80 °C showed no sign of fatigue, demonstrating the impact of the ordered dipolar structure on the operational stability of perovskite solar cells. Journal Article Science 379 6630 399 403 American Association for the Advancement of Science (AAAS) 0036-8075 1095-9203 27 1 2023 2023-01-27 10.1126/science.add7331 COLLEGE NANME Materials Science and Engineering COLLEGE CODE MTLS Swansea University The authors acknowledge the support of all the technicians at Helmholtz-Zentrum Berlin (HZB). The authors thank beamline BL14B1 at the Shanghai Synchrotron Radiation Facility (SSRF) for providing the beam time. G.L., L.C., and M.H.A. thank the support from HyPerCells graduate school at HZB. R.Z. was supported by the National Natural Science Foundation of China (22103022). G.L. thanks the Chinese Scholarship Council (CSC) for its financial support (201906150131). M.S. and W.Z. thank the German Research Foundation (DFG) for funding (SPP2196, 431314977/GRK 2642). M.S. acknowledges funding by ProperPhotoMile. Project ProperPhotoMile is supported under the umbrella of SOLAR-ERA.NET Cofund 2 by the Spanish Ministry of Science and Education and the AEI under the project PCI2020-112185 and CDTI project number IDI-20210171; the Federal Ministry for Economic Affairs and Energy based on a decision by the German Bundestag project number FKZ 03EE1070B and FKZ 03EE1070A and the Israel Ministry of Energy with project number 220-11-031. The European Commission supports SOLAR-ERA.NET within the EU Framework Programme for Research and Innovation HORIZON 2020 (Cofund ERA-NET Action, 786483). This work has received funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement 804519). 2023-03-03T14:49:22.9308867 2023-02-01T11:30:01.4086226 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Guixiang Li 0000-0002-8730-0713 1 Zhenhuang Su 0000-0003-0026-2601 2 Laura Canil 0000-0003-4151-756x 3 Declan Hughes 0000-0001-6415-3717 4 Mahmoud H. Aldamasy 0000-0003-3331-5570 5 Janardan Dagar 0000-0003-4102-3818 6 Sergei Trofimov 0000-0002-9718-2845 7 Luyao Wang 0000-0003-0917-1749 8 Weiwei Zuo 0000-0002-9135-1628 9 José J. Jerónimo-Rendon 0000-0003-3981-2412 10 Mahdi Malekshahi Byranvand 0000-0001-6250-6005 11 Chenyue Wang 12 Rui Zhu 13 Zuhong Zhang 14 Feng Yang 0000-0003-0189-8038 15 Giuseppe Nasti 0000-0003-0867-2402 16 Boris Naydenov 0000-0002-5215-3880 17 Wing Chung Tsoi 0000-0003-3836-5139 18 Zhe Li 19 Xingyu Gao 0000-0003-1477-0092 20 Zhaokui Wang 0000-0003-1707-499x 21 Yu Jia 22 Eva Unger 0000-0002-3343-867x 23 Michael Saliba 0000-0002-6818-9781 24 Meng Li 0000-0003-0360-7791 25 Antonio Abate 0000-0002-3012-3541 26 62477__26444__eb1b921aa7ef44fd8aefd71b14400751.pdf 62477_supp.pdf 2023-02-01T11:40:08.9530937 Output 3578514 application/pdf Supplemental material true true eng 62477__26443__16b7308393db4a17b0a3288b49fc5b93.pdf 62477.pdf 2023-02-01T11:39:49.6922494 Output 1553545 application/pdf Accepted Manuscript true true eng
title Highly efficient p-i-n perovskite solar cells that endure temperature variations
spellingShingle Highly efficient p-i-n perovskite solar cells that endure temperature variations
Declan Hughes
Wing Chung Tsoi
title_short Highly efficient p-i-n perovskite solar cells that endure temperature variations
title_full Highly efficient p-i-n perovskite solar cells that endure temperature variations
title_fullStr Highly efficient p-i-n perovskite solar cells that endure temperature variations
title_full_unstemmed Highly efficient p-i-n perovskite solar cells that endure temperature variations
title_sort Highly efficient p-i-n perovskite solar cells that endure temperature variations
author_id_str_mv 5590b62d833b89a43926267b2b7a5c29
7e5f541df6635a9a8e1a579ff2de5d56
author_id_fullname_str_mv 5590b62d833b89a43926267b2b7a5c29_***_Declan Hughes
7e5f541df6635a9a8e1a579ff2de5d56_***_Wing Chung Tsoi
author Declan Hughes
Wing Chung Tsoi
author2 Guixiang Li
Zhenhuang Su
Laura Canil
Declan Hughes
Mahmoud H. Aldamasy
Janardan Dagar
Sergei Trofimov
Luyao Wang
Weiwei Zuo
José J. Jerónimo-Rendon
Mahdi Malekshahi Byranvand
Chenyue Wang
Rui Zhu
Zuhong Zhang
Feng Yang
Giuseppe Nasti
Boris Naydenov
Wing Chung Tsoi
Zhe Li
Xingyu Gao
Zhaokui Wang
Yu Jia
Eva Unger
Michael Saliba
Meng Li
Antonio Abate
format Journal article
container_title Science
container_volume 379
container_issue 6630
container_start_page 399
publishDate 2023
institution Swansea University
issn 0036-8075
1095-9203
doi_str_mv 10.1126/science.add7331
publisher American Association for the Advancement of Science (AAAS)
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
document_store_str 1
active_str 0
description Daily temperature variations induce phase transitions and lattice strains in halide perovskites, challenging their stability in solar cells. We stabilised the perovskite black phase and improved the solar cell performance using the ordered dipolar structure of β-poly(1,1-difluoroethylene) to control the perovskite film crystallisation and the energy alignment. We demonstrated p-i-n perovskite solar cells with a record power conversion efficiency of 24.6% over 18 square millimetres and 23.1% over 1 square centimetre, which retained 96% and 88% of the efficiency after 1000-hours 1-sun maximum power point tracking at 25 and 75 °C, respectively. Devices under rapid thermal cycling between −60 °C and +80 °C showed no sign of fatigue, demonstrating the impact of the ordered dipolar structure on the operational stability of perovskite solar cells.
published_date 2023-01-27T04:22:07Z
_version_ 1763754458807795712
score 10.998093

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