No Cover Image

E-Thesis 21920 views

Synthesis and characterisation of novel phosphonate-based linkers and metal-organic frameworks based on tetravalent metals / Steve Shearan

Swansea University Author: Steve Shearan

Full text not available from this repository: check for access using links below.

DOI (Published version): 10.23889/SUthesis.60848

Abstract

The interest in metal-organic frameworks (MOFs) has skyrocketed in the past two decades, owing mainly to their tunable structures and properties. The main approach for this thesis is to explore the synthesis of novel metal(IV) phosphonate frameworks, mainly based on zirconium(IV). Exploring the effe...

Full description

Published: Swansea 2022
Institution: Swansea University
Degree level: Doctoral
Degree name: Ph.D
Supervisor: Andreoli, Enrico ; Taddei, Marco
URI: https://cronfa.swan.ac.uk/Record/cronfa60848
Tags: Add Tag
No Tags, Be the first to tag this record!
first_indexed 2022-08-17T16:06:19Z
last_indexed 2023-01-13T19:21:17Z
id cronfa60848
recordtype RisThesis
fullrecord <?xml version="1.0"?><rfc1807><datestamp>2022-08-17T17:23:25.8100311</datestamp><bib-version>v2</bib-version><id>60848</id><entry>2022-08-17</entry><title>Synthesis and characterisation of novel phosphonate-based linkers and metal-organic frameworks based on tetravalent metals</title><swanseaauthors><author><sid>feed41db390519dc46cbc1365e86d35f</sid><ORCID>0000-0002-0605-016X</ORCID><firstname>Steve</firstname><surname>Shearan</surname><name>Steve Shearan</name><active>true</active><ethesisStudent>false</ethesisStudent></author></swanseaauthors><date>2022-08-17</date><deptcode>MECH</deptcode><abstract>The interest in metal-organic frameworks (MOFs) has skyrocketed in the past two decades, owing mainly to their tunable structures and properties. The main approach for this thesis is to explore the synthesis of novel metal(IV) phosphonate frameworks, mainly based on zirconium(IV). Exploring the effect of linker geometry on the structure of MOFs, a series of non-linear linkers were synthesised and assessed on their effectiveness in forcing the structure away from the conventional pillared-layered structures observed in a large portion of metal phosphonate literature. The subsequent structures were then assessed for their suitability in applications such as carbon capture and photocatalysis. With the interest in crystallisation evident, an in-depth in situ XRD crystallisation study was also carried out on two existing Ce(IV)-based MOFs, one of which had been identified for its promising carbon capture properties, and was also subject to a scale-up study to assess the potential for commercial deployment.</abstract><type>E-Thesis</type><journal/><volume/><journalNumber/><paginationStart/><paginationEnd/><publisher/><placeOfPublication>Swansea</placeOfPublication><isbnPrint/><isbnElectronic/><issnPrint/><issnElectronic/><keywords>Metal-organic frameworks, phosphonates, metal phosphonates, in situ XRD</keywords><publishedDay>29</publishedDay><publishedMonth>7</publishedMonth><publishedYear>2022</publishedYear><publishedDate>2022-07-29</publishedDate><doi>10.23889/SUthesis.60848</doi><url/><notes>ORCiD identifier: https://orcid.org/0000-0002-0605-016X</notes><college>COLLEGE NANME</college><department>Mechanical Engineering</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>MECH</DepartmentCode><institution>Swansea University</institution><supervisor>Andreoli, Enrico ; Taddei, Marco</supervisor><degreelevel>Doctoral</degreelevel><degreename>Ph.D</degreename><degreesponsorsfunders>College of Engineering Scholarship</degreesponsorsfunders><apcterm/><funders/><projectreference/><lastEdited>2022-08-17T17:23:25.8100311</lastEdited><Created>2022-08-17T17:01:03.8417878</Created><path><level id="1">Faculty of Science and Engineering</level><level id="2">School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Mechanical Engineering</level></path><authors><author><firstname>Steve</firstname><surname>Shearan</surname><orcid>0000-0002-0605-016X</orcid><order>1</order></author></authors><documents><document><filename>Under embargo</filename><originalFilename>Under embargo</originalFilename><uploaded>2022-08-17T17:19:07.6503586</uploaded><type>Output</type><contentLength>7876277</contentLength><contentType>application/pdf</contentType><version>E-Thesis &#x2013; open access</version><cronfaStatus>true</cronfaStatus><embargoDate>2023-07-29T00:00:00.0000000</embargoDate><documentNotes>Copyright: The author, Stephen J. I. Shearan, 2022.</documentNotes><copyrightCorrect>true</copyrightCorrect><language>eng</language></document></documents><OutputDurs/></rfc1807>
spelling 2022-08-17T17:23:25.8100311 v2 60848 2022-08-17 Synthesis and characterisation of novel phosphonate-based linkers and metal-organic frameworks based on tetravalent metals feed41db390519dc46cbc1365e86d35f 0000-0002-0605-016X Steve Shearan Steve Shearan true false 2022-08-17 MECH The interest in metal-organic frameworks (MOFs) has skyrocketed in the past two decades, owing mainly to their tunable structures and properties. The main approach for this thesis is to explore the synthesis of novel metal(IV) phosphonate frameworks, mainly based on zirconium(IV). Exploring the effect of linker geometry on the structure of MOFs, a series of non-linear linkers were synthesised and assessed on their effectiveness in forcing the structure away from the conventional pillared-layered structures observed in a large portion of metal phosphonate literature. The subsequent structures were then assessed for their suitability in applications such as carbon capture and photocatalysis. With the interest in crystallisation evident, an in-depth in situ XRD crystallisation study was also carried out on two existing Ce(IV)-based MOFs, one of which had been identified for its promising carbon capture properties, and was also subject to a scale-up study to assess the potential for commercial deployment. E-Thesis Swansea Metal-organic frameworks, phosphonates, metal phosphonates, in situ XRD 29 7 2022 2022-07-29 10.23889/SUthesis.60848 ORCiD identifier: https://orcid.org/0000-0002-0605-016X COLLEGE NANME Mechanical Engineering COLLEGE CODE MECH Swansea University Andreoli, Enrico ; Taddei, Marco Doctoral Ph.D College of Engineering Scholarship 2022-08-17T17:23:25.8100311 2022-08-17T17:01:03.8417878 Faculty of Science and Engineering School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Mechanical Engineering Steve Shearan 0000-0002-0605-016X 1 Under embargo Under embargo 2022-08-17T17:19:07.6503586 Output 7876277 application/pdf E-Thesis – open access true 2023-07-29T00:00:00.0000000 Copyright: The author, Stephen J. I. Shearan, 2022. true eng
title Synthesis and characterisation of novel phosphonate-based linkers and metal-organic frameworks based on tetravalent metals
spellingShingle Synthesis and characterisation of novel phosphonate-based linkers and metal-organic frameworks based on tetravalent metals
Steve Shearan
title_short Synthesis and characterisation of novel phosphonate-based linkers and metal-organic frameworks based on tetravalent metals
title_full Synthesis and characterisation of novel phosphonate-based linkers and metal-organic frameworks based on tetravalent metals
title_fullStr Synthesis and characterisation of novel phosphonate-based linkers and metal-organic frameworks based on tetravalent metals
title_full_unstemmed Synthesis and characterisation of novel phosphonate-based linkers and metal-organic frameworks based on tetravalent metals
title_sort Synthesis and characterisation of novel phosphonate-based linkers and metal-organic frameworks based on tetravalent metals
author_id_str_mv feed41db390519dc46cbc1365e86d35f
author_id_fullname_str_mv feed41db390519dc46cbc1365e86d35f_***_Steve Shearan
author Steve Shearan
author2 Steve Shearan
format E-Thesis
publishDate 2022
institution Swansea University
doi_str_mv 10.23889/SUthesis.60848
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Mechanical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Aerospace, Civil, Electrical, General and Mechanical Engineering - Mechanical Engineering
document_store_str 0
active_str 0
description The interest in metal-organic frameworks (MOFs) has skyrocketed in the past two decades, owing mainly to their tunable structures and properties. The main approach for this thesis is to explore the synthesis of novel metal(IV) phosphonate frameworks, mainly based on zirconium(IV). Exploring the effect of linker geometry on the structure of MOFs, a series of non-linear linkers were synthesised and assessed on their effectiveness in forcing the structure away from the conventional pillared-layered structures observed in a large portion of metal phosphonate literature. The subsequent structures were then assessed for their suitability in applications such as carbon capture and photocatalysis. With the interest in crystallisation evident, an in-depth in situ XRD crystallisation study was also carried out on two existing Ce(IV)-based MOFs, one of which had been identified for its promising carbon capture properties, and was also subject to a scale-up study to assess the potential for commercial deployment.
published_date 2022-07-29T04:19:18Z
_version_ 1763754281283878912
score 11.013731

Similar Items