Robust Magnetic γ-Fe2O3/Al–ZnO Adsorbent for Chlorpyriphos Removal in Water

Boulares, Miryam; Chamam, Baha; Mejri, Amal; Wahab, Mohamed Ali; Haddouk, Amani; Mir, Lassaad El; Hamzaoui, Ahmed Hichem; Kallel, Amjad; Tizaoui, Chedly; Trabelsi, Ismail

doi:10.3390/w14071160

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Robust Magnetic γ-Fe2O3/Al–ZnO Adsorbent for Chlorpyriphos Removal in Water

Miryam Boulares, Baha Chamam, Amal Mejri, Mohamed Ali Wahab, Amani Haddouk, Lassaad El Mir, Ahmed Hichem Hamzaoui, Amjad Kallel

, Chedly Tizaoui

, Ismail Trabelsi

Water, Volume: 14, Issue: 7, Start page: 1160

Swansea University Author: Chedly Tizaoui

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DOI (Published version): 10.3390/w14071160

Abstract

In this research, the removal of the pesticide chlorpyriphos (CPE) from water by adsorption using a novel adsorbent made of γ-Fe2O3/Al-ZnO nanocomposite was studied. The adsorbent was characterized using Fourier-transformed infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), Brunauer-E...

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Published in:	Water
ISSN:	2073-4441
Published:	MDPI AG 2022
Online Access:	Check full text
URI:	https://cronfa.swan.ac.uk/Record/cronfa59778

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The main parameters affecting the adsorption process, including the initial pH (2–12), the concentration of pesticide (10–70 ppm), the %Fe2O3 of the adsorbent, and the adsorption time (≤60 min), were studied. The results demonstrated that the adsorption of CPE depended on the pH, with a maximum removal of 92.3% achieved at around neutral pH. The adsorption isotherm was modelled and the results showed that the Freundlich model fitted the experimental data better than the Langmuir and Temkin models. The kinetics of adsorption were also studied and modelled using the pseudo-first-order and pseudo-second-order models, with the former being found more suitable. Energy dispersive X-ray (EDX) analysis confirmed the adsorption of CPE on γ-Fe2O3/Al-ZnO, while FTIR analysis suggested that the hydroxyl, N-pyridine, and chloro functional groups governed the adsorption mechanism. Furthermore, VSM analysis revealed that the magnetization saturation of γ-Fe2O3/Al-ZnO nanocomposite, after CPE adsorption, was slightly lower than that of fresh γ-Fe2O3/Al-ZnO but remained adequate for the efficient separation of the adsorbent simply using a magnet. 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spelling	2023-04-28T15:57:18.4905724 v2 59778 2022-04-07 Robust Magnetic γ-Fe2O3/Al–ZnO Adsorbent for Chlorpyriphos Removal in Water 4b34a0286d3c0b0b081518fa6987031d 0000-0003-2159-7881 Chedly Tizaoui Chedly Tizaoui true false 2022-04-07 EAAS In this research, the removal of the pesticide chlorpyriphos (CPE) from water by adsorption using a novel adsorbent made of γ-Fe2O3/Al-ZnO nanocomposite was studied. The adsorbent was characterized using Fourier-transformed infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) surface area, and vibrating sample magnetometry (VSM). The main parameters affecting the adsorption process, including the initial pH (2–12), the concentration of pesticide (10–70 ppm), the %Fe2O3 of the adsorbent, and the adsorption time (≤60 min), were studied. The results demonstrated that the adsorption of CPE depended on the pH, with a maximum removal of 92.3% achieved at around neutral pH. The adsorption isotherm was modelled and the results showed that the Freundlich model fitted the experimental data better than the Langmuir and Temkin models. The kinetics of adsorption were also studied and modelled using the pseudo-first-order and pseudo-second-order models, with the former being found more suitable. Energy dispersive X-ray (EDX) analysis confirmed the adsorption of CPE on γ-Fe2O3/Al-ZnO, while FTIR analysis suggested that the hydroxyl, N-pyridine, and chloro functional groups governed the adsorption mechanism. Furthermore, VSM analysis revealed that the magnetization saturation of γ-Fe2O3/Al-ZnO nanocomposite, after CPE adsorption, was slightly lower than that of fresh γ-Fe2O3/Al-ZnO but remained adequate for the efficient separation of the adsorbent simply using a magnet. This study demonstrates that binary γ-Fe2O3/Al-ZnO magnetic nanocomposites are effective for the removal of chlorpyriphos and could be highly promising materials for the removal of emerging pollutants in wastewater. Journal Article Water 14 7 1160 MDPI AG 2073-4441 nanocomposites; magnetic adsorption; chlorpyriphos; pesticides; isotherm and kinetic 4 4 2022 2022-04-04 10.3390/w14071160 COLLEGE NANME Engineering and Applied Sciences School COLLEGE CODE EAAS Swansea University 2023-04-28T15:57:18.4905724 2022-04-07T16:13:30.0252688 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemical Engineering Miryam Boulares 1 Baha Chamam 2 Amal Mejri 3 Mohamed Ali Wahab 4 Amani Haddouk 5 Lassaad El Mir 6 Ahmed Hichem Hamzaoui 7 Amjad Kallel 0000-0003-0167-0228 8 Chedly Tizaoui 0000-0003-2159-7881 9 Ismail Trabelsi 10 59778__23791__6974f44c5f6146aba9e1d9af82f29f00.pdf 59778.pdf 2022-04-07T16:17:02.0749485 Output 4158467 application/pdf Version of Record true © 2022 by the authors.This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license true eng https://creativecommons.org/licenses/by/4.0/
title	Robust Magnetic γ-Fe2O3/Al–ZnO Adsorbent for Chlorpyriphos Removal in Water
spellingShingle	Robust Magnetic γ-Fe2O3/Al–ZnO Adsorbent for Chlorpyriphos Removal in Water Chedly Tizaoui
title_short	Robust Magnetic γ-Fe2O3/Al–ZnO Adsorbent for Chlorpyriphos Removal in Water
title_full	Robust Magnetic γ-Fe2O3/Al–ZnO Adsorbent for Chlorpyriphos Removal in Water
title_fullStr	Robust Magnetic γ-Fe2O3/Al–ZnO Adsorbent for Chlorpyriphos Removal in Water
title_full_unstemmed	Robust Magnetic γ-Fe2O3/Al–ZnO Adsorbent for Chlorpyriphos Removal in Water
title_sort	Robust Magnetic γ-Fe2O3/Al–ZnO Adsorbent for Chlorpyriphos Removal in Water
author_id_str_mv	4b34a0286d3c0b0b081518fa6987031d
author_id_fullname_str_mv	4b34a0286d3c0b0b081518fa6987031d_***_Chedly Tizaoui
author	Chedly Tizaoui
author2	Miryam Boulares Baha Chamam Amal Mejri Mohamed Ali Wahab Amani Haddouk Lassaad El Mir Ahmed Hichem Hamzaoui Amjad Kallel Chedly Tizaoui Ismail Trabelsi
format	Journal article
container_title	Water
container_volume	14
container_issue	7
container_start_page	1160
publishDate	2022
institution	Swansea University
issn	2073-4441
doi_str_mv	10.3390/w14071160
publisher	MDPI AG
college_str	Faculty of Science and Engineering
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hierarchy_top_title	Faculty of Science and Engineering
hierarchy_parent_id	facultyofscienceandengineering
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department_str	School of Engineering and Applied Sciences - Chemical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemical Engineering
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description	In this research, the removal of the pesticide chlorpyriphos (CPE) from water by adsorption using a novel adsorbent made of γ-Fe2O3/Al-ZnO nanocomposite was studied. The adsorbent was characterized using Fourier-transformed infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) surface area, and vibrating sample magnetometry (VSM). The main parameters affecting the adsorption process, including the initial pH (2–12), the concentration of pesticide (10–70 ppm), the %Fe2O3 of the adsorbent, and the adsorption time (≤60 min), were studied. The results demonstrated that the adsorption of CPE depended on the pH, with a maximum removal of 92.3% achieved at around neutral pH. The adsorption isotherm was modelled and the results showed that the Freundlich model fitted the experimental data better than the Langmuir and Temkin models. The kinetics of adsorption were also studied and modelled using the pseudo-first-order and pseudo-second-order models, with the former being found more suitable. Energy dispersive X-ray (EDX) analysis confirmed the adsorption of CPE on γ-Fe2O3/Al-ZnO, while FTIR analysis suggested that the hydroxyl, N-pyridine, and chloro functional groups governed the adsorption mechanism. Furthermore, VSM analysis revealed that the magnetization saturation of γ-Fe2O3/Al-ZnO nanocomposite, after CPE adsorption, was slightly lower than that of fresh γ-Fe2O3/Al-ZnO but remained adequate for the efficient separation of the adsorbent simply using a magnet. This study demonstrates that binary γ-Fe2O3/Al-ZnO magnetic nanocomposites are effective for the removal of chlorpyriphos and could be highly promising materials for the removal of emerging pollutants in wastewater.
published_date	2022-04-04T20:10:55Z
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score	11.04748

Robust Magnetic γ-Fe2O3/Al–ZnO Adsorbent for Chlorpyriphos Removal in Water

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