Investigation into the Re-Arrangement of Copper Foams Pre- and Post-CO2 Electrocatalysis

Rudd, Jennifer; Aldave, Sandra Hernandez; Kazimierska, Ewa; Hamdy, Louise; Bain, Odin; Barron, Andrew; Andreoli, Enrico

doi:10.3390/chemistry3030048

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Investigation into the Re-Arrangement of Copper Foams Pre- and Post-CO2 Electrocatalysis

Jennifer Rudd

, Sandra Hernandez Aldave, Ewa Kazimierska, Louise Hamdy, Odin Bain, Andrew Barron

, Enrico Andreoli

Chemistry, Volume: 3, Issue: 3, Pages: 687 - 703

Swansea University Authors: Jennifer Rudd , Sandra Hernandez Aldave, Ewa Kazimierska, Louise Hamdy, Odin Bain, Andrew Barron , Enrico Andreoli

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DOI (Published version): 10.3390/chemistry3030048

Abstract

The utilization of carbon dioxide is a major incentive for the growing field of carbon capture. Carbon dioxide could be an abundant building block to generate higher-value chemical products. Herein, we fabricated a porous copper electrode capable of catalyzing the reduction of carbon dioxide into hi...

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Published in:	Chemistry
ISSN:	2624-8549
Published:	MDPI AG 2021
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URI:	https://cronfa.swan.ac.uk/Record/cronfa57951
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We found that alterations in the morphology, crystallinity and surface composition of the catalyst were conducive to the deactivation of the copper foams.</abstract><type>Journal Article</type><journal>Chemistry</journal><volume>3</volume><journalNumber>3</journalNumber><paginationStart>687</paginationStart><paginationEnd>703</paginationEnd><publisher>MDPI AG</publisher><placeOfPublication/><isbnPrint/><isbnElectronic/><issnPrint/><issnElectronic>2624-8549</issnElectronic><keywords>copper foam; CO2 reduction; electrocatalysis; heterogeneous catalyst; modified electrodes</keywords><publishedDay>28</publishedDay><publishedMonth>6</publishedMonth><publishedYear>2021</publishedYear><publishedDate>2021-06-28</publishedDate><doi>10.3390/chemistry3030048</doi><url/><notes/><college>COLLEGE NANME</college><department>Business</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>BBU</DepartmentCode><institution>Swansea University</institution><apcterm/><funders>This work is part of the Reducing Industrial Carbon Emissions (RICE) and Flexible Integrated Energy Systems (FLEXIS) research operations funded by the Welsh European Funding Office (WEFO) through the Welsh Government. 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spelling	2021-10-18T13:19:38.5963176 v2 57951 2021-09-18 Investigation into the Re-Arrangement of Copper Foams Pre- and Post-CO2 Electrocatalysis c2e4cf0f048a86b5ca2f331e6c566aff 0000-0002-5209-477X Jennifer Rudd Jennifer Rudd true false 3c2500b52ca560852fb4b9b1d2cbf4a2 Sandra Hernandez Aldave Sandra Hernandez Aldave true false acd104d55246ee2d03420795510359e9 Ewa Kazimierska Ewa Kazimierska true false 7f3a162e82c925cadead8a3b8d37dc81 Louise Hamdy Louise Hamdy true false 328aa757157b337db2b6b53817031a77 Odin Bain Odin Bain true false 92e452f20936d688d36f91c78574241d 0000-0002-2018-8288 Andrew Barron Andrew Barron true false cbd843daab780bb55698a3daccd74df8 0000-0002-1207-2314 Enrico Andreoli Enrico Andreoli true false 2021-09-18 BBU The utilization of carbon dioxide is a major incentive for the growing field of carbon capture. Carbon dioxide could be an abundant building block to generate higher-value chemical products. Herein, we fabricated a porous copper electrode capable of catalyzing the reduction of carbon dioxide into higher-value products, such as ethylene, ethanol and propanol. We investigated the formation of the foams under different conditions, not only analyzing their morphological and crystal structure, but also documenting their performance as a catalyst. In particular, we studied the response of the foams to CO2 electrolysis, including the effect of urea as a potential additive to enhance CO2 catalysis. Before electrolysis, the pristine and urea-modified foam copper electrodes consisted of a mixture of cuboctahedra and dendrites. After 35 min of electrolysis, the cuboctahedra and dendrites underwent structural rearrangement affecting catalysis performance. We found that alterations in the morphology, crystallinity and surface composition of the catalyst were conducive to the deactivation of the copper foams. Journal Article Chemistry 3 3 687 703 MDPI AG 2624-8549 copper foam; CO2 reduction; electrocatalysis; heterogeneous catalyst; modified electrodes 28 6 2021 2021-06-28 10.3390/chemistry3030048 COLLEGE NANME Business COLLEGE CODE BBU Swansea University This work is part of the Reducing Industrial Carbon Emissions (RICE) and Flexible Integrated Energy Systems (FLEXIS) research operations funded by the Welsh European Funding Office (WEFO) through the Welsh Government. Financial support was also provided by the Engineering and Physical Sciences Research Council (EPSRC) through the SUSTAIN Manufacturing Hub (EP/S018107/1) and grant EP/N009525/1. The Welsh Government is also acknowledged for the Sêr Cymru II Recapturing Talent Fellowship partly funded by the European Regional Development Fund (ERDF). Swansea University College of Engineering AIM Facility, which was funded in part by the EPSRC (EP/M028267/1), the European Regional Development Fund through the Welsh Government (80708) and the Ser Solar project via the Welsh Government. 2021-10-18T13:19:38.5963176 2021-09-18T07:07:08.4838453 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemical Engineering Jennifer Rudd 0000-0002-5209-477X 1 Sandra Hernandez Aldave 2 Ewa Kazimierska 3 Louise Hamdy 4 Odin Bain 5 Andrew Barron 0000-0002-2018-8288 6 Enrico Andreoli 0000-0002-1207-2314 7 57951__21206__fe487578547a427ab2993b97be6d0ed9.pdf 57951.pdf 2021-10-18T11:41:52.7561582 Output 5805477 application/pdf Version of Record true © 2021 by the authors. This is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license true eng https://creativecommons.org/licenses/by/4.0/
title	Investigation into the Re-Arrangement of Copper Foams Pre- and Post-CO2 Electrocatalysis
spellingShingle	Investigation into the Re-Arrangement of Copper Foams Pre- and Post-CO2 Electrocatalysis Jennifer Rudd Sandra Hernandez Aldave Ewa Kazimierska Louise Hamdy Odin Bain Andrew Barron Enrico Andreoli
title_short	Investigation into the Re-Arrangement of Copper Foams Pre- and Post-CO2 Electrocatalysis
title_full	Investigation into the Re-Arrangement of Copper Foams Pre- and Post-CO2 Electrocatalysis
title_fullStr	Investigation into the Re-Arrangement of Copper Foams Pre- and Post-CO2 Electrocatalysis
title_full_unstemmed	Investigation into the Re-Arrangement of Copper Foams Pre- and Post-CO2 Electrocatalysis
title_sort	Investigation into the Re-Arrangement of Copper Foams Pre- and Post-CO2 Electrocatalysis
author_id_str_mv	c2e4cf0f048a86b5ca2f331e6c566aff 3c2500b52ca560852fb4b9b1d2cbf4a2 acd104d55246ee2d03420795510359e9 7f3a162e82c925cadead8a3b8d37dc81 328aa757157b337db2b6b53817031a77 92e452f20936d688d36f91c78574241d cbd843daab780bb55698a3daccd74df8
author_id_fullname_str_mv	c2e4cf0f048a86b5ca2f331e6c566aff_*_Jennifer Rudd 3c2500b52ca560852fb4b9b1d2cbf4a2__Sandra Hernandez Aldave acd104d55246ee2d03420795510359e9__Ewa Kazimierska 7f3a162e82c925cadead8a3b8d37dc81__Louise Hamdy 328aa757157b337db2b6b53817031a77__Odin Bain 92e452f20936d688d36f91c78574241d__Andrew Barron cbd843daab780bb55698a3daccd74df8_**_Enrico Andreoli
author	Jennifer Rudd Sandra Hernandez Aldave Ewa Kazimierska Louise Hamdy Odin Bain Andrew Barron Enrico Andreoli
author2	Jennifer Rudd Sandra Hernandez Aldave Ewa Kazimierska Louise Hamdy Odin Bain Andrew Barron Enrico Andreoli
format	Journal article
container_title	Chemistry
container_volume	3
container_issue	3
container_start_page	687
publishDate	2021
institution	Swansea University
issn	2624-8549
doi_str_mv	10.3390/chemistry3030048
publisher	MDPI AG
college_str	Faculty of Science and Engineering
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hierarchy_parent_title	Faculty of Science and Engineering
department_str	School of Engineering and Applied Sciences - Chemical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemical Engineering
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description	The utilization of carbon dioxide is a major incentive for the growing field of carbon capture. Carbon dioxide could be an abundant building block to generate higher-value chemical products. Herein, we fabricated a porous copper electrode capable of catalyzing the reduction of carbon dioxide into higher-value products, such as ethylene, ethanol and propanol. We investigated the formation of the foams under different conditions, not only analyzing their morphological and crystal structure, but also documenting their performance as a catalyst. In particular, we studied the response of the foams to CO2 electrolysis, including the effect of urea as a potential additive to enhance CO2 catalysis. Before electrolysis, the pristine and urea-modified foam copper electrodes consisted of a mixture of cuboctahedra and dendrites. After 35 min of electrolysis, the cuboctahedra and dendrites underwent structural rearrangement affecting catalysis performance. We found that alterations in the morphology, crystallinity and surface composition of the catalyst were conducive to the deactivation of the copper foams.
published_date	2021-06-28T04:14:04Z
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score	11.013731

Investigation into the Re-Arrangement of Copper Foams Pre- and Post-CO2 Electrocatalysis

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