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Activated carbon from Nauclea diderrichii agricultural waste–a promising adsorbent for ibuprofen, methylene blue and CO2

Martins Omorogie, Jonathan O. Babalola, Muhsinah O. Ismaeel, James McGettrick Orcid Logo, Trystan Watson Orcid Logo, Daniel M. Dawson, Mariolino Carta Orcid Logo, Moritz Kuehnel

Advanced Powder Technology, Volume: 32, Issue: 3, Pages: 866 - 874

Swansea University Authors: Martins Omorogie, James McGettrick Orcid Logo, Trystan Watson Orcid Logo, Mariolino Carta Orcid Logo, Moritz Kuehnel

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DOI (Published version): 10.1016/j.apt.2021.01.031

Abstract

The adsorption potential of activated carbon derived from Nauclea diderrichii biomass (NDAC) was scrupulously harnessed as a low cost and ubiquitous adsorbent for the removal of greenhouse gas (CO2), and organic pollutants such as methylene blue (MB) and ibuprofen (IB) from water. NDAC was fully cha...

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Published in: Advanced Powder Technology
ISSN: 0921-8831
Published: Elsevier BV 2021
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URI: https://cronfa.swan.ac.uk/Record/cronfa56331
first_indexed 2021-02-26T10:15:33Z
last_indexed 2021-06-10T03:21:50Z
id cronfa56331
recordtype SURis
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spelling 2021-06-09T10:06:53.2953546 v2 56331 2021-02-26 Activated carbon from Nauclea diderrichii agricultural waste–a promising adsorbent for ibuprofen, methylene blue and CO2 75d7584515a2f4014de240d8d6497393 Martins Omorogie Martins Omorogie true false bdbacc591e2de05180e0fd3cc13fa480 0000-0002-7719-2958 James McGettrick James McGettrick true false a210327b52472cfe8df9b8108d661457 0000-0002-8015-1436 Trystan Watson Trystan Watson true false 56aebf2bba457f395149bbecbfa6d3eb 0000-0003-0718-6971 Mariolino Carta Mariolino Carta true false 210dbad181ce095d6f8bf2bd1d616d4e Moritz Kuehnel Moritz Kuehnel true false 2021-02-26 The adsorption potential of activated carbon derived from Nauclea diderrichii biomass (NDAC) was scrupulously harnessed as a low cost and ubiquitous adsorbent for the removal of greenhouse gas (CO2), and organic pollutants such as methylene blue (MB) and ibuprofen (IB) from water. NDAC was fully characterized by scanning electron microscopy (SEM), thermo-gravimetric analysis (TGA), X-ray diffraction (XRD), universal attenuated total reflectance-infra red (UATR-IR), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), solid state nuclear magnetic resonance (NMR) and nitrogen gas adsorption–desorption by Brunauer-Emmett-Teller (BET) technique. This study showed that NDAC comprises graphitic carbons that had some surface functional groups such as Cdouble bondC, Cdouble bondO, etc, which adsorbed these environmental contaminants. The adsorption equilibrium and kinetic data that the adsorption of these environmental contaminants formed multilayers (homogeneous surfaces) with the surface of NDAC. The adsorption mechanism of CO2, MB and IB onto NDAC occurred by via electrostatic attractions and π-π conjugal interactions. The adsorption capacity of NDAC for CO2 was ca. 3.2 cm3.g−1 at 298 K. The Langmuir maximum adsorption capacity, of NDAC for MB and IB was obtained as 35.09 mg.g−1 and 70.92 mg.g−1 at 328 K respectively. Journal Article Advanced Powder Technology 32 3 866 874 Elsevier BV 0921-8831 Nauclea diderrichii, Agricultural waste, Methylene blue, Ibuprofen, CO2 1 3 2021 2021-03-01 10.1016/j.apt.2021.01.031 http://dx.doi.org/10.1016/j.apt.2021.01.031 COLLEGE NANME COLLEGE CODE Swansea University 2021-06-09T10:06:53.2953546 2021-02-26T10:14:02.7525718 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Martins Omorogie 1 Jonathan O. Babalola 2 Muhsinah O. Ismaeel 3 James McGettrick 0000-0002-7719-2958 4 Trystan Watson 0000-0002-8015-1436 5 Daniel M. Dawson 6 Mariolino Carta 0000-0003-0718-6971 7 Moritz Kuehnel 8
title Activated carbon from Nauclea diderrichii agricultural waste–a promising adsorbent for ibuprofen, methylene blue and CO2
spellingShingle Activated carbon from Nauclea diderrichii agricultural waste–a promising adsorbent for ibuprofen, methylene blue and CO2
Martins Omorogie
James McGettrick
Trystan Watson
Mariolino Carta
Moritz Kuehnel
title_short Activated carbon from Nauclea diderrichii agricultural waste–a promising adsorbent for ibuprofen, methylene blue and CO2
title_full Activated carbon from Nauclea diderrichii agricultural waste–a promising adsorbent for ibuprofen, methylene blue and CO2
title_fullStr Activated carbon from Nauclea diderrichii agricultural waste–a promising adsorbent for ibuprofen, methylene blue and CO2
title_full_unstemmed Activated carbon from Nauclea diderrichii agricultural waste–a promising adsorbent for ibuprofen, methylene blue and CO2
title_sort Activated carbon from Nauclea diderrichii agricultural waste–a promising adsorbent for ibuprofen, methylene blue and CO2
author_id_str_mv 75d7584515a2f4014de240d8d6497393
bdbacc591e2de05180e0fd3cc13fa480
a210327b52472cfe8df9b8108d661457
56aebf2bba457f395149bbecbfa6d3eb
210dbad181ce095d6f8bf2bd1d616d4e
author_id_fullname_str_mv 75d7584515a2f4014de240d8d6497393_***_Martins Omorogie
bdbacc591e2de05180e0fd3cc13fa480_***_James McGettrick
a210327b52472cfe8df9b8108d661457_***_Trystan Watson
56aebf2bba457f395149bbecbfa6d3eb_***_Mariolino Carta
210dbad181ce095d6f8bf2bd1d616d4e_***_Moritz Kuehnel
author Martins Omorogie
James McGettrick
Trystan Watson
Mariolino Carta
Moritz Kuehnel
author2 Martins Omorogie
Jonathan O. Babalola
Muhsinah O. Ismaeel
James McGettrick
Trystan Watson
Daniel M. Dawson
Mariolino Carta
Moritz Kuehnel
format Journal article
container_title Advanced Powder Technology
container_volume 32
container_issue 3
container_start_page 866
publishDate 2021
institution Swansea University
issn 0921-8831
doi_str_mv 10.1016/j.apt.2021.01.031
publisher Elsevier BV
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
url http://dx.doi.org/10.1016/j.apt.2021.01.031
document_store_str 0
active_str 0
description The adsorption potential of activated carbon derived from Nauclea diderrichii biomass (NDAC) was scrupulously harnessed as a low cost and ubiquitous adsorbent for the removal of greenhouse gas (CO2), and organic pollutants such as methylene blue (MB) and ibuprofen (IB) from water. NDAC was fully characterized by scanning electron microscopy (SEM), thermo-gravimetric analysis (TGA), X-ray diffraction (XRD), universal attenuated total reflectance-infra red (UATR-IR), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), solid state nuclear magnetic resonance (NMR) and nitrogen gas adsorption–desorption by Brunauer-Emmett-Teller (BET) technique. This study showed that NDAC comprises graphitic carbons that had some surface functional groups such as Cdouble bondC, Cdouble bondO, etc, which adsorbed these environmental contaminants. The adsorption equilibrium and kinetic data that the adsorption of these environmental contaminants formed multilayers (homogeneous surfaces) with the surface of NDAC. The adsorption mechanism of CO2, MB and IB onto NDAC occurred by via electrostatic attractions and π-π conjugal interactions. The adsorption capacity of NDAC for CO2 was ca. 3.2 cm3.g−1 at 298 K. The Langmuir maximum adsorption capacity, of NDAC for MB and IB was obtained as 35.09 mg.g−1 and 70.92 mg.g−1 at 328 K respectively.
published_date 2021-03-01T08:00:03Z
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score 11.048171

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