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A piperidinium salt stabilizes efficient metal-halide perovskite solar cells

Yen-Hung Lin, Nobuya Sakai, Peimei Da, Jiaying Wu, Harry C. Sansom, Alexandra J. Ramadan, Suhas Mahesh, Junliang Liu, Robert D. J. Oliver, Jongchul Lim, Lee Aspitarte, Kshama Sharma, P. K. Madhu, Anna B. Morales‐Vilches, Pabitra K. Nayak, Sai Bai, Feng Gao, Chris R. M. Grovenor, Michael B. Johnston, John G. Labram, James Durrant Orcid Logo, James M. Ball, Bernard Wenger, Bernd Stannowski, Henry J. Snaith

Science, Volume: 369, Issue: 6499, Pages: 96 - 102

Swansea University Author: James Durrant Orcid Logo

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DOI (Published version): 10.1126/science.aba1628

Abstract

Longevity has been a long-standing concern for hybrid perovskite photovoltaics. We demonstrate high-resilience positive-intrinsic-negative perovskite solar cells by incorporating a piperidinium-based ionic compound into the formamidinium-cesium lead-trihalide perovskite absorber. With the bandgap tu...

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Published in: Science
ISSN: 0036-8075 1095-9203
Published: 2020
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URI: https://cronfa.swan.ac.uk/Record/cronfa54855
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With the bandgap tuned to be well suited for perovskite-on-silicon tandem cells, this piperidinium additive enhances the open-circuit voltage and cell efficiency. This additive also retards compositional segregation into impurity phases and pinhole formation in the perovskite absorber layer during aggressive aging. Under full-spectrum simulated sunlight in ambient atmosphere, our unencapsulated and encapsulated cells retain 80 and 95% of their peak and post-burn-in efficiencies for 1010 and 1200 hours at 60&#xB0; and 85&#xB0;C, respectively. 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M.</firstname><surname>Grovenor</surname><order>18</order></author><author><firstname>Michael B.</firstname><surname>Johnston</surname><order>19</order></author><author><firstname>John G.</firstname><surname>Labram</surname><order>20</order></author><author><firstname>James</firstname><surname>Durrant</surname><orcid>0000-0001-8353-7345</orcid><order>21</order></author><author><firstname>James M.</firstname><surname>Ball</surname><order>22</order></author><author><firstname>Bernard</firstname><surname>Wenger</surname><order>23</order></author><author><firstname>Bernd</firstname><surname>Stannowski</surname><order>24</order></author><author><firstname>Henry J.</firstname><surname>Snaith</surname><order>25</order></author></authors><documents><document><filename>54855__17834__56da1616101640a481cb01c071a91ebc.pdf</filename><originalFilename>54855.pdf</originalFilename><uploaded>2020-08-03T14:28:53.3465377</uploaded><type>Output</type><contentLength>4790368</contentLength><contentType>application/pdf</contentType><version>Accepted Manuscript</version><cronfaStatus>true</cronfaStatus><copyrightCorrect>true</copyrightCorrect><language>English</language></document></documents><OutputDurs/></rfc1807>
spelling 2021-01-15T10:24:29.5545197 v2 54855 2020-08-03 A piperidinium salt stabilizes efficient metal-halide perovskite solar cells f3dd64bc260e5c07adfa916c27dbd58a 0000-0001-8353-7345 James Durrant James Durrant true false 2020-08-03 MTLS Longevity has been a long-standing concern for hybrid perovskite photovoltaics. We demonstrate high-resilience positive-intrinsic-negative perovskite solar cells by incorporating a piperidinium-based ionic compound into the formamidinium-cesium lead-trihalide perovskite absorber. With the bandgap tuned to be well suited for perovskite-on-silicon tandem cells, this piperidinium additive enhances the open-circuit voltage and cell efficiency. This additive also retards compositional segregation into impurity phases and pinhole formation in the perovskite absorber layer during aggressive aging. Under full-spectrum simulated sunlight in ambient atmosphere, our unencapsulated and encapsulated cells retain 80 and 95% of their peak and post-burn-in efficiencies for 1010 and 1200 hours at 60° and 85°C, respectively. Our analysis reveals detailed degradation routes that contribute to the failure of aged cells. Journal Article Science 369 6499 96 102 0036-8075 1095-9203 3 7 2020 2020-07-03 10.1126/science.aba1628 COLLEGE NANME Materials Science and Engineering COLLEGE CODE MTLS Swansea University 2021-01-15T10:24:29.5545197 2020-08-03T14:09:41.7197357 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Yen-Hung Lin 1 Nobuya Sakai 2 Peimei Da 3 Jiaying Wu 4 Harry C. Sansom 5 Alexandra J. Ramadan 6 Suhas Mahesh 7 Junliang Liu 8 Robert D. J. Oliver 9 Jongchul Lim 10 Lee Aspitarte 11 Kshama Sharma 12 P. K. Madhu 13 Anna B. Morales‐Vilches 14 Pabitra K. Nayak 15 Sai Bai 16 Feng Gao 17 Chris R. M. Grovenor 18 Michael B. Johnston 19 John G. Labram 20 James Durrant 0000-0001-8353-7345 21 James M. Ball 22 Bernard Wenger 23 Bernd Stannowski 24 Henry J. Snaith 25 54855__17834__56da1616101640a481cb01c071a91ebc.pdf 54855.pdf 2020-08-03T14:28:53.3465377 Output 4790368 application/pdf Accepted Manuscript true true English
title A piperidinium salt stabilizes efficient metal-halide perovskite solar cells
spellingShingle A piperidinium salt stabilizes efficient metal-halide perovskite solar cells
James Durrant
title_short A piperidinium salt stabilizes efficient metal-halide perovskite solar cells
title_full A piperidinium salt stabilizes efficient metal-halide perovskite solar cells
title_fullStr A piperidinium salt stabilizes efficient metal-halide perovskite solar cells
title_full_unstemmed A piperidinium salt stabilizes efficient metal-halide perovskite solar cells
title_sort A piperidinium salt stabilizes efficient metal-halide perovskite solar cells
author_id_str_mv f3dd64bc260e5c07adfa916c27dbd58a
author_id_fullname_str_mv f3dd64bc260e5c07adfa916c27dbd58a_***_James Durrant
author James Durrant
author2 Yen-Hung Lin
Nobuya Sakai
Peimei Da
Jiaying Wu
Harry C. Sansom
Alexandra J. Ramadan
Suhas Mahesh
Junliang Liu
Robert D. J. Oliver
Jongchul Lim
Lee Aspitarte
Kshama Sharma
P. K. Madhu
Anna B. Morales‐Vilches
Pabitra K. Nayak
Sai Bai
Feng Gao
Chris R. M. Grovenor
Michael B. Johnston
John G. Labram
James Durrant
James M. Ball
Bernard Wenger
Bernd Stannowski
Henry J. Snaith
format Journal article
container_title Science
container_volume 369
container_issue 6499
container_start_page 96
publishDate 2020
institution Swansea University
issn 0036-8075
1095-9203
doi_str_mv 10.1126/science.aba1628
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
document_store_str 1
active_str 0
description Longevity has been a long-standing concern for hybrid perovskite photovoltaics. We demonstrate high-resilience positive-intrinsic-negative perovskite solar cells by incorporating a piperidinium-based ionic compound into the formamidinium-cesium lead-trihalide perovskite absorber. With the bandgap tuned to be well suited for perovskite-on-silicon tandem cells, this piperidinium additive enhances the open-circuit voltage and cell efficiency. This additive also retards compositional segregation into impurity phases and pinhole formation in the perovskite absorber layer during aggressive aging. Under full-spectrum simulated sunlight in ambient atmosphere, our unencapsulated and encapsulated cells retain 80 and 95% of their peak and post-burn-in efficiencies for 1010 and 1200 hours at 60° and 85°C, respectively. Our analysis reveals detailed degradation routes that contribute to the failure of aged cells.
published_date 2020-07-03T04:08:39Z
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score 11.036553

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