Development of dense solid state thin-film electrolyte for fluoride ion batteries

Zhang, Le; Reddy, M. Anji; Gao, Ping; Fichtner, Maximilian; Munnangi, Anji

doi:10.1016/j.jallcom.2016.04.196

Journal article 695 views

Development of dense solid state thin-film electrolyte for fluoride ion batteries

Le Zhang, M. Anji Reddy, Ping Gao, Maximilian Fichtner, Anji Munnangi

Journal of Alloys and Compounds, Volume: 684, Pages: 733 - 738

Swansea University Author: Anji Munnangi

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DOI (Published version): 10.1016/j.jallcom.2016.04.196

Abstract

Dense thin-film electrolyte of La0.9Ba0.1F2.9 has been fabricated on stainless steel substrates by spin coating of a complex and sintering. The resulting layers had a thickness of 4–5 μm. The effect of sintering temperature (400, 450 and 500 °C) and time (0.5, 2 and 4 h) was studied in order to cont...

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Published in:	Journal of Alloys and Compounds
ISSN:	0925-8388
Published:	2016
Online Access:	Check full text
URI:	https://cronfa.swan.ac.uk/Record/cronfa51574
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first_indexed	2019-08-27T15:30:58Z
last_indexed	2019-09-04T14:49:34Z
id	cronfa51574
recordtype	SURis
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spelling	2019-09-04T11:46:48.6395591 v2 51574 2019-08-27 Development of dense solid state thin-film electrolyte for fluoride ion batteries 3ed0b4f2ff4fb9e87c7a73e7a3c39da7 0000-0001-9101-0252 Anji Munnangi Anji Munnangi true false 2019-08-27 MTLS Dense thin-film electrolyte of La0.9Ba0.1F2.9 has been fabricated on stainless steel substrates by spin coating of a complex and sintering. The resulting layers had a thickness of 4–5 μm. The effect of sintering temperature (400, 450 and 500 °C) and time (0.5, 2 and 4 h) was studied in order to control the morphology and the ionic conductivity of the films. The composition and morphology of the fabricated films were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Tysonite type structure was retained when the films were sintered at 450 °C or below while an impurity of LaOF was formed when the films were sintered at 500 °C. SEM results indicate that higher temperature and longer time of sintering resulted in dense films. Ionic conductivities of the fabricated films were determined by electrochemical impedance spectroscopy (EIS). The thin films sintered at 450 °C for 4 h exhibited high ionic conductivity of 1.6 × 10−4 S cm−1 at 170 °C. The optimal preparation condition of La0.9Ba0.1F2.9 films was sintering at 450 °C for 4 h. Journal Article Journal of Alloys and Compounds 684 733 738 0925-8388 Fluoride ion battery, Thin film battery, Solid state electrolyte, Tysonite structure, Fluoride ion conductor 5 11 2016 2016-11-05 10.1016/j.jallcom.2016.04.196 COLLEGE NANME Materials Science and Engineering COLLEGE CODE MTLS Swansea University 2019-09-04T11:46:48.6395591 2019-08-27T12:20:45.8961905 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Le Zhang 1 M. Anji Reddy 2 Ping Gao 3 Maximilian Fichtner 4 Anji Munnangi 0000-0001-9101-0252 5
title	Development of dense solid state thin-film electrolyte for fluoride ion batteries
spellingShingle	Development of dense solid state thin-film electrolyte for fluoride ion batteries Anji Munnangi
title_short	Development of dense solid state thin-film electrolyte for fluoride ion batteries
title_full	Development of dense solid state thin-film electrolyte for fluoride ion batteries
title_fullStr	Development of dense solid state thin-film electrolyte for fluoride ion batteries
title_full_unstemmed	Development of dense solid state thin-film electrolyte for fluoride ion batteries
title_sort	Development of dense solid state thin-film electrolyte for fluoride ion batteries
author_id_str_mv	3ed0b4f2ff4fb9e87c7a73e7a3c39da7
author_id_fullname_str_mv	3ed0b4f2ff4fb9e87c7a73e7a3c39da7_***_Anji Munnangi
author	Anji Munnangi
author2	Le Zhang M. Anji Reddy Ping Gao Maximilian Fichtner Anji Munnangi
format	Journal article
container_title	Journal of Alloys and Compounds
container_volume	684
container_start_page	733
publishDate	2016
institution	Swansea University
issn	0925-8388
doi_str_mv	10.1016/j.jallcom.2016.04.196
college_str	Faculty of Science and Engineering
hierarchytype
hierarchy_top_id	facultyofscienceandengineering
hierarchy_top_title	Faculty of Science and Engineering
hierarchy_parent_id	facultyofscienceandengineering
hierarchy_parent_title	Faculty of Science and Engineering
department_str	School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
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description	Dense thin-film electrolyte of La0.9Ba0.1F2.9 has been fabricated on stainless steel substrates by spin coating of a complex and sintering. The resulting layers had a thickness of 4–5 μm. The effect of sintering temperature (400, 450 and 500 °C) and time (0.5, 2 and 4 h) was studied in order to control the morphology and the ionic conductivity of the films. The composition and morphology of the fabricated films were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Tysonite type structure was retained when the films were sintered at 450 °C or below while an impurity of LaOF was formed when the films were sintered at 500 °C. SEM results indicate that higher temperature and longer time of sintering resulted in dense films. Ionic conductivities of the fabricated films were determined by electrochemical impedance spectroscopy (EIS). The thin films sintered at 450 °C for 4 h exhibited high ionic conductivity of 1.6 × 10−4 S cm−1 at 170 °C. The optimal preparation condition of La0.9Ba0.1F2.9 films was sintering at 450 °C for 4 h.
published_date	2016-11-05T04:03:31Z
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score	11.016593

Development of dense solid state thin-film electrolyte for fluoride ion batteries

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