Investigating the effect of positional isomerism on the assembly of zirconium phosphonates based on tritopic linkers

Shearan, Steve; Taddei, Marco; I., Stephen J.; Donnadio, Anna; Casciola, Mario; Vivani, Riccardo; Costantino, Ferdinando

doi:10.1039/C9DT02463H

Journal article 464 views 250 downloads

Investigating the effect of positional isomerism on the assembly of zirconium phosphonates based on tritopic linkers

Steve Shearan

, Marco Taddei

, Stephen J. I. Shearan, Anna Donnadio, Mario Casciola, Riccardo Vivani, Ferdinando Costantino

Dalton Transactions

Swansea University Authors: Steve Shearan , Marco Taddei

PDF | Accepted Manuscript
Download (556.15KB)

Check full text

DOI (Published version): 10.1039/C9DT02463H

Abstract

We report on the use of a novel tritopic phosphonic linker, 2,4,6-tris[3-(phosphonomethyl)phenyl]-1,3,5-triazine, for the synthesis of a layered zirconium phosphonate, named UPG-2. Comparison with the structure of the permanently porous UPG-1, based on the related linker 2,4,6-tris[4-(phosphonomethy...

Full description

Published in:	Dalton Transactions
ISSN:	1477-9226 1477-9234
Published:	2020
Online Access:	Check full text
URI:	https://cronfa.swan.ac.uk/Record/cronfa51415
Tags:	Add Tag No Tags, Be the first to tag this record!

first_indexed	2019-08-15T21:29:47Z
last_indexed	2019-08-15T21:29:47Z
id	cronfa51415
recordtype	SURis
fullrecord	<?xml version="1.0"?><rfc1807><datestamp>2019-08-15T14:03:59.1791860</datestamp><bib-version>v2</bib-version><id>51415</id><entry>2019-08-15</entry><title>Investigating the effect of positional isomerism on the assembly of zirconium phosphonates based on tritopic linkers</title><swanseaauthors><author><sid>feed41db390519dc46cbc1365e86d35f</sid><ORCID>0000-0002-0605-016X</ORCID><firstname>Steve</firstname><surname>Shearan</surname><name>Steve Shearan</name><active>true</active><ethesisStudent>false</ethesisStudent></author><author><sid>5cffd1038508554d8596dee8b4e51052</sid><ORCID>0000-0003-2805-6375</ORCID><firstname>Marco</firstname><surname>Taddei</surname><name>Marco Taddei</name><active>true</active><ethesisStudent>false</ethesisStudent></author></swanseaauthors><date>2019-08-15</date><deptcode>MECH</deptcode><abstract>We report on the use of a novel tritopic phosphonic linker, 2,4,6-tris[3-(phosphonomethyl)phenyl]-1,3,5-triazine, for the synthesis of a layered zirconium phosphonate, named UPG-2. Comparison with the structure of the permanently porous UPG-1, based on the related linker 2,4,6-tris[4-(phosphonomethyl)phenyl]-1,3,5-triazine, reveals that positional isomerism disrupts the porous architecture in UPG-2 by preventing the formation of infinitely extended chains connected through Zr–O–P–O–Zr bonds. The presence of free, acidic P–OH groups and an extended network of hydrogen bonds makes UPG-2 a good proton conductor, reaching values as high as 5.7 × 10−4 S cm−1.</abstract><type>Journal Article</type><journal>Dalton Transactions</journal><publisher/><issnPrint>1477-9226</issnPrint><issnElectronic>1477-9234</issnElectronic><keywords/><publishedDay>31</publishedDay><publishedMonth>12</publishedMonth><publishedYear>2020</publishedYear><publishedDate>2020-12-31</publishedDate><doi>10.1039/C9DT02463H</doi><url/><notes/><college>COLLEGE NANME</college><department>Mechanical Engineering</department><CollegeCode>COLLEGE CODE</CollegeCode><DepartmentCode>MECH</DepartmentCode><institution>Swansea University</institution><apcterm/><lastEdited>2019-08-15T14:03:59.1791860</lastEdited><Created>2019-08-15T14:01:18.1394896</Created><authors><author><firstname>Steve</firstname><surname>Shearan</surname><orcid>0000-0002-0605-016X</orcid><order>1</order></author><author><firstname>Marco</firstname><surname>Taddei</surname><orcid>0000-0003-2805-6375</orcid><order>2</order></author><author><firstname>Stephen J. I.</firstname><surname>Shearan</surname><order>3</order></author><author><firstname>Anna</firstname><surname>Donnadio</surname><order>4</order></author><author><firstname>Mario</firstname><surname>Casciola</surname><order>5</order></author><author><firstname>Riccardo</firstname><surname>Vivani</surname><order>6</order></author><author><firstname>Ferdinando</firstname><surname>Costantino</surname><order>7</order></author></authors><documents><document><filename>0051415-15082019140330.pdf</filename><originalFilename>taddei2019.pdf</originalFilename><uploaded>2019-08-15T14:03:30.6430000</uploaded><type>Output</type><contentLength>555037</contentLength><contentType>application/pdf</contentType><version>Accepted Manuscript</version><cronfaStatus>true</cronfaStatus><embargoDate>2020-08-02T00:00:00.0000000</embargoDate><copyrightCorrect>false</copyrightCorrect><language>eng</language></document></documents><OutputDurs/></rfc1807>
spelling	2019-08-15T14:03:59.1791860 v2 51415 2019-08-15 Investigating the effect of positional isomerism on the assembly of zirconium phosphonates based on tritopic linkers feed41db390519dc46cbc1365e86d35f 0000-0002-0605-016X Steve Shearan Steve Shearan true false 5cffd1038508554d8596dee8b4e51052 0000-0003-2805-6375 Marco Taddei Marco Taddei true false 2019-08-15 MECH We report on the use of a novel tritopic phosphonic linker, 2,4,6-tris[3-(phosphonomethyl)phenyl]-1,3,5-triazine, for the synthesis of a layered zirconium phosphonate, named UPG-2. Comparison with the structure of the permanently porous UPG-1, based on the related linker 2,4,6-tris[4-(phosphonomethyl)phenyl]-1,3,5-triazine, reveals that positional isomerism disrupts the porous architecture in UPG-2 by preventing the formation of infinitely extended chains connected through Zr–O–P–O–Zr bonds. The presence of free, acidic P–OH groups and an extended network of hydrogen bonds makes UPG-2 a good proton conductor, reaching values as high as 5.7 × 10−4 S cm−1. Journal Article Dalton Transactions 1477-9226 1477-9234 31 12 2020 2020-12-31 10.1039/C9DT02463H COLLEGE NANME Mechanical Engineering COLLEGE CODE MECH Swansea University 2019-08-15T14:03:59.1791860 2019-08-15T14:01:18.1394896 Steve Shearan 0000-0002-0605-016X 1 Marco Taddei 0000-0003-2805-6375 2 Stephen J. I. Shearan 3 Anna Donnadio 4 Mario Casciola 5 Riccardo Vivani 6 Ferdinando Costantino 7 0051415-15082019140330.pdf taddei2019.pdf 2019-08-15T14:03:30.6430000 Output 555037 application/pdf Accepted Manuscript true 2020-08-02T00:00:00.0000000 false eng
title	Investigating the effect of positional isomerism on the assembly of zirconium phosphonates based on tritopic linkers
spellingShingle	Investigating the effect of positional isomerism on the assembly of zirconium phosphonates based on tritopic linkers Steve Shearan Marco Taddei
title_short	Investigating the effect of positional isomerism on the assembly of zirconium phosphonates based on tritopic linkers
title_full	Investigating the effect of positional isomerism on the assembly of zirconium phosphonates based on tritopic linkers
title_fullStr	Investigating the effect of positional isomerism on the assembly of zirconium phosphonates based on tritopic linkers
title_full_unstemmed	Investigating the effect of positional isomerism on the assembly of zirconium phosphonates based on tritopic linkers
title_sort	Investigating the effect of positional isomerism on the assembly of zirconium phosphonates based on tritopic linkers
author_id_str_mv	feed41db390519dc46cbc1365e86d35f 5cffd1038508554d8596dee8b4e51052
author_id_fullname_str_mv	feed41db390519dc46cbc1365e86d35f_*_Steve Shearan 5cffd1038508554d8596dee8b4e51052_*_Marco Taddei
author	Steve Shearan Marco Taddei
author2	Steve Shearan Marco Taddei Stephen J. I. Shearan Anna Donnadio Mario Casciola Riccardo Vivani Ferdinando Costantino
format	Journal article
container_title	Dalton Transactions
publishDate	2020
institution	Swansea University
issn	1477-9226 1477-9234
doi_str_mv	10.1039/C9DT02463H
document_store_str	1
active_str	0
description	We report on the use of a novel tritopic phosphonic linker, 2,4,6-tris[3-(phosphonomethyl)phenyl]-1,3,5-triazine, for the synthesis of a layered zirconium phosphonate, named UPG-2. Comparison with the structure of the permanently porous UPG-1, based on the related linker 2,4,6-tris[4-(phosphonomethyl)phenyl]-1,3,5-triazine, reveals that positional isomerism disrupts the porous architecture in UPG-2 by preventing the formation of infinitely extended chains connected through Zr–O–P–O–Zr bonds. The presence of free, acidic P–OH groups and an extended network of hydrogen bonds makes UPG-2 a good proton conductor, reaching values as high as 5.7 × 10−4 S cm−1.
published_date	2020-12-31T04:03:16Z
_version_	1763753273072812032
score	11.013731

Investigating the effect of positional isomerism on the assembly of zirconium phosphonates based on tritopic linkers

Similar Items