No Cover Image

Journal article 543 views 268 downloads

Detrimental effect of silver doping in spiro-MeOTAD on the device performance of perovskite solar cells

Jing-Jing Liang, Meng Li, Jun-Yi Zhu, Hao Zong, Yue Zhang, Sagar Jain, Zhao-Kui Wang

Organic Electronics, Volume: 69, Pages: 343 - 347

Swansea University Author: Sagar Jain

Check full text

DOI (Published version): 10.1016/j.orgel.2019.03.036

Abstract

Despite hybrid organic-inorganic perovskite solar cells (PSCs) have reached a rapid improvement in solar cell efficiency. The long-term operational stability of PSCs is still under course of development. Here, we investigated the infiltration effects of Ag+ into the adjacent hole transporting layer...

Full description

Published in: Organic Electronics
ISSN: 1566-1199
Published: 2019
Online Access: Check full text

URI: https://cronfa.swan.ac.uk/Record/cronfa49780
first_indexed 2019-03-29T11:16:13Z
last_indexed 2019-05-01T11:39:50Z
id cronfa49780
recordtype SURis
fullrecord <?xml version="1.0"?><rfc1807><datestamp>2019-05-01T09:30:37.2874661</datestamp><bib-version>v2</bib-version><id>49780</id><entry>2019-03-28</entry><title>Detrimental effect of silver doping in spiro-MeOTAD on the device performance of perovskite solar cells</title><swanseaauthors><author><sid>7073e179bb5b82db3e3efd3a8cd07139</sid><firstname>Sagar</firstname><surname>Jain</surname><name>Sagar Jain</name><active>true</active><ethesisStudent>false</ethesisStudent></author></swanseaauthors><date>2019-03-28</date><abstract>Despite hybrid organic-inorganic perovskite solar cells (PSCs) have reached a rapid improvement in solar cell efficiency. The long-term operational stability of PSCs is still under course of development. Here, we investigated the infiltration effects of Ag+ into the adjacent hole transporting layer (HTL) in the PSCs, by directly doping Ag+ into the conventional Spiro-MeOTAD layer (HTL) and the essential characterization analysis were also applied. The result distinctly demonstrated that the Ag-ion migration potentially triggers the performance degradation in PSCs. The incorporation of Ag+ brought deep-level defects in the Spiro-MeOTAD layer and consequently caused a deterioration of the hole-transporting ability of Spiro-MeOTAD leading to degradation of solar cell performance. Understanding the impacts of the metal electrode penetration in the HTL will promote advancing in the overall stability performance of PSCs.</abstract><type>Journal Article</type><journal>Organic Electronics</journal><volume>69</volume><paginationStart>343</paginationStart><paginationEnd>347</paginationEnd><publisher/><issnPrint>1566-1199</issnPrint><keywords>Perovskite solar cells, Hole-transporting layer, Spiro-OMeTAD, Stability</keywords><publishedDay>30</publishedDay><publishedMonth>6</publishedMonth><publishedYear>2019</publishedYear><publishedDate>2019-06-30</publishedDate><doi>10.1016/j.orgel.2019.03.036</doi><url/><notes/><college>COLLEGE NANME</college><CollegeCode>COLLEGE CODE</CollegeCode><institution>Swansea University</institution><apcterm/><lastEdited>2019-05-01T09:30:37.2874661</lastEdited><Created>2019-03-28T09:22:16.2384708</Created><path><level id="1">Faculty of Science and Engineering</level><level id="2">School of Engineering and Applied Sciences - Uncategorised</level></path><authors><author><firstname>Jing-Jing</firstname><surname>Liang</surname><order>1</order></author><author><firstname>Meng</firstname><surname>Li</surname><order>2</order></author><author><firstname>Jun-Yi</firstname><surname>Zhu</surname><order>3</order></author><author><firstname>Hao</firstname><surname>Zong</surname><order>4</order></author><author><firstname>Yue</firstname><surname>Zhang</surname><order>5</order></author><author><firstname>Sagar</firstname><surname>Jain</surname><order>6</order></author><author><firstname>Zhao-Kui</firstname><surname>Wang</surname><order>7</order></author></authors><documents><document><filename>0049780-28032019092627.pdf</filename><originalFilename>liang2019v2.pdf</originalFilename><uploaded>2019-03-28T09:26:27.7500000</uploaded><type>Output</type><contentLength>4883513</contentLength><contentType>application/pdf</contentType><version>Accepted Manuscript</version><cronfaStatus>true</cronfaStatus><embargoDate>2020-03-23T00:00:00.0000000</embargoDate><copyrightCorrect>true</copyrightCorrect><language>eng</language></document></documents><OutputDurs/></rfc1807>
spelling 2019-05-01T09:30:37.2874661 v2 49780 2019-03-28 Detrimental effect of silver doping in spiro-MeOTAD on the device performance of perovskite solar cells 7073e179bb5b82db3e3efd3a8cd07139 Sagar Jain Sagar Jain true false 2019-03-28 Despite hybrid organic-inorganic perovskite solar cells (PSCs) have reached a rapid improvement in solar cell efficiency. The long-term operational stability of PSCs is still under course of development. Here, we investigated the infiltration effects of Ag+ into the adjacent hole transporting layer (HTL) in the PSCs, by directly doping Ag+ into the conventional Spiro-MeOTAD layer (HTL) and the essential characterization analysis were also applied. The result distinctly demonstrated that the Ag-ion migration potentially triggers the performance degradation in PSCs. The incorporation of Ag+ brought deep-level defects in the Spiro-MeOTAD layer and consequently caused a deterioration of the hole-transporting ability of Spiro-MeOTAD leading to degradation of solar cell performance. Understanding the impacts of the metal electrode penetration in the HTL will promote advancing in the overall stability performance of PSCs. Journal Article Organic Electronics 69 343 347 1566-1199 Perovskite solar cells, Hole-transporting layer, Spiro-OMeTAD, Stability 30 6 2019 2019-06-30 10.1016/j.orgel.2019.03.036 COLLEGE NANME COLLEGE CODE Swansea University 2019-05-01T09:30:37.2874661 2019-03-28T09:22:16.2384708 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised Jing-Jing Liang 1 Meng Li 2 Jun-Yi Zhu 3 Hao Zong 4 Yue Zhang 5 Sagar Jain 6 Zhao-Kui Wang 7 0049780-28032019092627.pdf liang2019v2.pdf 2019-03-28T09:26:27.7500000 Output 4883513 application/pdf Accepted Manuscript true 2020-03-23T00:00:00.0000000 true eng
title Detrimental effect of silver doping in spiro-MeOTAD on the device performance of perovskite solar cells
spellingShingle Detrimental effect of silver doping in spiro-MeOTAD on the device performance of perovskite solar cells
Sagar Jain
title_short Detrimental effect of silver doping in spiro-MeOTAD on the device performance of perovskite solar cells
title_full Detrimental effect of silver doping in spiro-MeOTAD on the device performance of perovskite solar cells
title_fullStr Detrimental effect of silver doping in spiro-MeOTAD on the device performance of perovskite solar cells
title_full_unstemmed Detrimental effect of silver doping in spiro-MeOTAD on the device performance of perovskite solar cells
title_sort Detrimental effect of silver doping in spiro-MeOTAD on the device performance of perovskite solar cells
author_id_str_mv 7073e179bb5b82db3e3efd3a8cd07139
author_id_fullname_str_mv 7073e179bb5b82db3e3efd3a8cd07139_***_Sagar Jain
author Sagar Jain
author2 Jing-Jing Liang
Meng Li
Jun-Yi Zhu
Hao Zong
Yue Zhang
Sagar Jain
Zhao-Kui Wang
format Journal article
container_title Organic Electronics
container_volume 69
container_start_page 343
publishDate 2019
institution Swansea University
issn 1566-1199
doi_str_mv 10.1016/j.orgel.2019.03.036
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
document_store_str 1
active_str 0
description Despite hybrid organic-inorganic perovskite solar cells (PSCs) have reached a rapid improvement in solar cell efficiency. The long-term operational stability of PSCs is still under course of development. Here, we investigated the infiltration effects of Ag+ into the adjacent hole transporting layer (HTL) in the PSCs, by directly doping Ag+ into the conventional Spiro-MeOTAD layer (HTL) and the essential characterization analysis were also applied. The result distinctly demonstrated that the Ag-ion migration potentially triggers the performance degradation in PSCs. The incorporation of Ag+ brought deep-level defects in the Spiro-MeOTAD layer and consequently caused a deterioration of the hole-transporting ability of Spiro-MeOTAD leading to degradation of solar cell performance. Understanding the impacts of the metal electrode penetration in the HTL will promote advancing in the overall stability performance of PSCs.
published_date 2019-06-30T07:32:09Z
_version_ 1829539811556327424
score 11.058138

Similar Items