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Sub-ppm level high energy resolution fluorescence detected X-ray absorption spectroscopy of selenium in articular cartilage

C. Bissardon, O. Proux, S. Bureau, E. Suess, L. H. E. Winkel, Steve Conlan Orcid Logo, Lewis Francis Orcid Logo, Ilyas Khan Orcid Logo, L. Charlet, J. L. Hazemann, S. Bohic

The Analyst, Volume: 144, Issue: 11, Pages: 3488 - 3493

Swansea University Authors: Steve Conlan Orcid Logo, Lewis Francis Orcid Logo, Ilyas Khan Orcid Logo

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DOI (Published version): 10.1039/c9an00207c

Abstract

The speciation of highly-diluted elements by X-ray absorption spectroscopy in a diverse range of materials is extremely challenging, especially in biological matrices such as articular cartilage. Here we show that using a high energy resolution fluorescence detected X-ray absorption spectroscopy (HE...

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Published in: The Analyst
ISSN: 0003-2654 1364-5528
Published: Royal Society of Chemistry (RSC) 2019
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URI: https://cronfa.swan.ac.uk/Record/cronfa49778
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first_indexed 2019-03-29T11:16:13Z
last_indexed 2020-06-09T19:03:30Z
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spelling 2020-06-09T15:17:15.4229832 v2 49778 2019-03-27 Sub-ppm level high energy resolution fluorescence detected X-ray absorption spectroscopy of selenium in articular cartilage 0bb6bd247e32fb4249de62c0013b51cb 0000-0002-2562-3461 Steve Conlan Steve Conlan true false 10f61f9c1248951c1a33f6a89498f37d 0000-0002-7803-7714 Lewis Francis Lewis Francis true false 2536d955ff70e7b77063a8efe9103161 0000-0002-3886-1987 Ilyas Khan Ilyas Khan true false 2019-03-27 BMS The speciation of highly-diluted elements by X-ray absorption spectroscopy in a diverse range of materials is extremely challenging, especially in biological matrices such as articular cartilage. Here we show that using a high energy resolution fluorescence detected X-ray absorption spectroscopy (HERFD-XAS) technique coupled to an array of crystal analyzers, selenium speciation down to 400 ppb (μg kg-1) within articular cartilage can be demonstrated. This is a major advance in the speciation of highly-diluted elements through X-ray absorption spectroscopy and opens new possibilities to study the metabolic role of selenium and other elements in biological samples. Journal Article The Analyst 144 11 3488 3493 Royal Society of Chemistry (RSC) 0003-2654 1364-5528 31 12 2019 2019-12-31 10.1039/c9an00207c http://dx.doi.org/10.1039/c9an00207c COLLEGE NANME Biomedical Sciences COLLEGE CODE BMS Swansea University 2020-06-09T15:17:15.4229832 2019-03-27T19:35:55.0519174 C. Bissardon 1 O. Proux 2 S. Bureau 3 E. Suess 4 L. H. E. Winkel 5 Steve Conlan 0000-0002-2562-3461 6 Lewis Francis 0000-0002-7803-7714 7 Ilyas Khan 0000-0002-3886-1987 8 L. Charlet 9 J. L. Hazemann 10 S. Bohic 11 0049778-09042019141421.pdf 49778.pdf 2019-04-09T14:14:21.4630000 Output 1450942 application/pdf Accepted Manuscript true 2020-03-28T00:00:00.0000000 true eng
title Sub-ppm level high energy resolution fluorescence detected X-ray absorption spectroscopy of selenium in articular cartilage
spellingShingle Sub-ppm level high energy resolution fluorescence detected X-ray absorption spectroscopy of selenium in articular cartilage
Steve Conlan
Lewis Francis
Ilyas Khan
title_short Sub-ppm level high energy resolution fluorescence detected X-ray absorption spectroscopy of selenium in articular cartilage
title_full Sub-ppm level high energy resolution fluorescence detected X-ray absorption spectroscopy of selenium in articular cartilage
title_fullStr Sub-ppm level high energy resolution fluorescence detected X-ray absorption spectroscopy of selenium in articular cartilage
title_full_unstemmed Sub-ppm level high energy resolution fluorescence detected X-ray absorption spectroscopy of selenium in articular cartilage
title_sort Sub-ppm level high energy resolution fluorescence detected X-ray absorption spectroscopy of selenium in articular cartilage
author_id_str_mv 0bb6bd247e32fb4249de62c0013b51cb
10f61f9c1248951c1a33f6a89498f37d
2536d955ff70e7b77063a8efe9103161
author_id_fullname_str_mv 0bb6bd247e32fb4249de62c0013b51cb_***_Steve Conlan
10f61f9c1248951c1a33f6a89498f37d_***_Lewis Francis
2536d955ff70e7b77063a8efe9103161_***_Ilyas Khan
author Steve Conlan
Lewis Francis
Ilyas Khan
author2 C. Bissardon
O. Proux
S. Bureau
E. Suess
L. H. E. Winkel
Steve Conlan
Lewis Francis
Ilyas Khan
L. Charlet
J. L. Hazemann
S. Bohic
format Journal article
container_title The Analyst
container_volume 144
container_issue 11
container_start_page 3488
publishDate 2019
institution Swansea University
issn 0003-2654
1364-5528
doi_str_mv 10.1039/c9an00207c
publisher Royal Society of Chemistry (RSC)
url http://dx.doi.org/10.1039/c9an00207c
document_store_str 1
active_str 0
description The speciation of highly-diluted elements by X-ray absorption spectroscopy in a diverse range of materials is extremely challenging, especially in biological matrices such as articular cartilage. Here we show that using a high energy resolution fluorescence detected X-ray absorption spectroscopy (HERFD-XAS) technique coupled to an array of crystal analyzers, selenium speciation down to 400 ppb (μg kg-1) within articular cartilage can be demonstrated. This is a major advance in the speciation of highly-diluted elements through X-ray absorption spectroscopy and opens new possibilities to study the metabolic role of selenium and other elements in biological samples.
published_date 2019-12-31T04:01:00Z
_version_ 1763753129517514752
score 11.037581

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