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Alternating stacking of ferromagnetic nanosheet and nanoparticle films: heteroassembly and magneto-optical Kerr effect

Baoping Jia, Waye Zhang Orcid Logo, Hui Liu, Bencai Lin, Jianning Ding

Journal of Nanoparticle Research, Volume: 18, Issue: 9

Swansea University Author: Waye Zhang Orcid Logo

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DOI (Published version): 10.1007/s11051-016-3571-2

Abstract

Heterostructured multilayer films of two different nanocrystals have been successfully fabricated by layer-by-layer stacking of Ti0.8Co0.2O2 nanosheet and Fe3O4 nanoparticle films. UV–Vis spectroscopy and AFM observation confirmed the successful alternating deposition in the multilayer buildup proce...

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Published in: Journal of Nanoparticle Research
ISSN: 1388-0764 1572-896X
Published: 2016
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URI: https://cronfa.swan.ac.uk/Record/cronfa44281
first_indexed 2018-09-18T12:57:29Z
last_indexed 2018-10-08T19:28:04Z
id cronfa44281
recordtype SURis
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spelling 2018-10-08T15:41:52.8517456 v2 44281 2018-09-18 Alternating stacking of ferromagnetic nanosheet and nanoparticle films: heteroassembly and magneto-optical Kerr effect 3ddabbb54b2cfa2ea10f590ea7da6520 0000-0003-3129-2918 Waye Zhang Waye Zhang true false 2018-09-18 EAAS Heterostructured multilayer films of two different nanocrystals have been successfully fabricated by layer-by-layer stacking of Ti0.8Co0.2O2 nanosheet and Fe3O4 nanoparticle films. UV–Vis spectroscopy and AFM observation confirmed the successful alternating deposition in the multilayer buildup process. The average thickness of both Ti0.8Co0.2O2 nanosheet and Fe3O4 nanoparticle layers was determined to be about 1.4–1.7 and 5 nm, which was in good agreement with TEM results. Magneto-optical Kerr effect measurements demonstrated that the heteroassemblies exhibit gigantic magnetic circular dichroism (MCD) (2 × 104 deg/cm) at 320–360 nm, deriving from strong interlayer [Co2+]t2g–[Fe3+]eg d–d charge transfer which was further confirmed by X-ray photoelectron spectroscopy. Their structure-dependent MCD showed high potential in rational design and construction of high-efficiency magneto-optical devices. Journal Article Journal of Nanoparticle Research 18 9 1388-0764 1572-896X Ferromagnetic, Nanosheet, Heteroassembly, Magneto-optical, Kerr effect 31 12 2016 2016-12-31 10.1007/s11051-016-3571-2 COLLEGE NANME Engineering and Applied Sciences School COLLEGE CODE EAAS Swansea University 2018-10-08T15:41:52.8517456 2018-09-18T12:15:08.2647578 Faculty of Science and Engineering School of Engineering and Applied Sciences - Chemical Engineering Baoping Jia 1 Waye Zhang 0000-0003-3129-2918 2 Hui Liu 3 Bencai Lin 4 Jianning Ding 5
title Alternating stacking of ferromagnetic nanosheet and nanoparticle films: heteroassembly and magneto-optical Kerr effect
spellingShingle Alternating stacking of ferromagnetic nanosheet and nanoparticle films: heteroassembly and magneto-optical Kerr effect
Waye Zhang
title_short Alternating stacking of ferromagnetic nanosheet and nanoparticle films: heteroassembly and magneto-optical Kerr effect
title_full Alternating stacking of ferromagnetic nanosheet and nanoparticle films: heteroassembly and magneto-optical Kerr effect
title_fullStr Alternating stacking of ferromagnetic nanosheet and nanoparticle films: heteroassembly and magneto-optical Kerr effect
title_full_unstemmed Alternating stacking of ferromagnetic nanosheet and nanoparticle films: heteroassembly and magneto-optical Kerr effect
title_sort Alternating stacking of ferromagnetic nanosheet and nanoparticle films: heteroassembly and magneto-optical Kerr effect
author_id_str_mv 3ddabbb54b2cfa2ea10f590ea7da6520
author_id_fullname_str_mv 3ddabbb54b2cfa2ea10f590ea7da6520_***_Waye Zhang
author Waye Zhang
author2 Baoping Jia
Waye Zhang
Hui Liu
Bencai Lin
Jianning Ding
format Journal article
container_title Journal of Nanoparticle Research
container_volume 18
container_issue 9
publishDate 2016
institution Swansea University
issn 1388-0764
1572-896X
doi_str_mv 10.1007/s11051-016-3571-2
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Chemical Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Chemical Engineering
document_store_str 0
active_str 0
description Heterostructured multilayer films of two different nanocrystals have been successfully fabricated by layer-by-layer stacking of Ti0.8Co0.2O2 nanosheet and Fe3O4 nanoparticle films. UV–Vis spectroscopy and AFM observation confirmed the successful alternating deposition in the multilayer buildup process. The average thickness of both Ti0.8Co0.2O2 nanosheet and Fe3O4 nanoparticle layers was determined to be about 1.4–1.7 and 5 nm, which was in good agreement with TEM results. Magneto-optical Kerr effect measurements demonstrated that the heteroassemblies exhibit gigantic magnetic circular dichroism (MCD) (2 × 104 deg/cm) at 320–360 nm, deriving from strong interlayer [Co2+]t2g–[Fe3+]eg d–d charge transfer which was further confirmed by X-ray photoelectron spectroscopy. Their structure-dependent MCD showed high potential in rational design and construction of high-efficiency magneto-optical devices.
published_date 2016-12-31T09:28:07Z
_version_ 1827104764322643968
score 11.055543

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