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Electrically conductive membranes for in situ fouling detection using impedance spectroscopy in membrane distillation

Farah Ahmed, Nidal Hilal, Raed Hashaikeh

Journal of Membrane Science, Volume: 556, Pages: 66 - 72

Swansea University Author: Nidal Hilal

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Abstract

Online monitoring of fouling in desalination processes enables early and appropriate action for fouling control. This study demonstrates the use of Electrochemical Impedance Spectroscopy (EIS) to electrically conductive membranes for online monitoring of fouling by eliminating the need for external...

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Published in: Journal of Membrane Science
ISSN: 0376-7388
Published: 2018
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URI: https://cronfa.swan.ac.uk/Record/cronfa39192
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first_indexed 2018-03-24T20:06:13Z
last_indexed 2021-01-15T04:01:04Z
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spelling 2021-01-14T12:58:52.5930443 v2 39192 2018-03-24 Electrically conductive membranes for in situ fouling detection using impedance spectroscopy in membrane distillation 3acba771241d878c8e35ff464aec0342 Nidal Hilal Nidal Hilal true false 2018-03-24 FGSEN Online monitoring of fouling in desalination processes enables early and appropriate action for fouling control. This study demonstrates the use of Electrochemical Impedance Spectroscopy (EIS) to electrically conductive membranes for online monitoring of fouling by eliminating the need for external electrodes and/or canary cells. Electrically conductive membranes are prepared by incorporation of silica in carbon nanostructures and subsequent fluorination to yield hydrophobic membranes. These membranes are applied to direct contact membrane distillation with 99.9% salt rejection and a flux of 4.3 LMH. EIS is used for online monitoring of inorganic fouling on the membrane surface during the MD process. Impedance spectra taken over a duration of 15 hours indicated that impedance in the low frequency (&#60;100 Hz) region gradually decreased with fouling early on, and increased towards the end. Impedance-based monitoring is more sensitive to changes in the system than monitoring of flux and permeate conductivity. It shows the capability of EIS as a sensitive online monitoring tool for fouling in MD. Journal Article Journal of Membrane Science 556 66 72 0376-7388 15 6 2018 2018-06-15 10.1016/j.memsci.2018.03.069 COLLEGE NANME Science and Engineering - Faculty COLLEGE CODE FGSEN Swansea University 2021-01-14T12:58:52.5930443 2018-03-24T14:15:51.5548238 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised Farah Ahmed 1 Nidal Hilal 2 Raed Hashaikeh 3 0039192-25032018192422.pdf Paperv11.pdf 2018-03-25T19:24:22.3070000 Output 1350120 application/pdf Accepted Manuscript true 2019-03-31T00:00:00.0000000 Released under the terms of a Creative Commons Attribution Non-Commercial No Derivatives License (CC-BY-NC-ND). true eng
title Electrically conductive membranes for in situ fouling detection using impedance spectroscopy in membrane distillation
spellingShingle Electrically conductive membranes for in situ fouling detection using impedance spectroscopy in membrane distillation
Nidal Hilal
title_short Electrically conductive membranes for in situ fouling detection using impedance spectroscopy in membrane distillation
title_full Electrically conductive membranes for in situ fouling detection using impedance spectroscopy in membrane distillation
title_fullStr Electrically conductive membranes for in situ fouling detection using impedance spectroscopy in membrane distillation
title_full_unstemmed Electrically conductive membranes for in situ fouling detection using impedance spectroscopy in membrane distillation
title_sort Electrically conductive membranes for in situ fouling detection using impedance spectroscopy in membrane distillation
author_id_str_mv 3acba771241d878c8e35ff464aec0342
author_id_fullname_str_mv 3acba771241d878c8e35ff464aec0342_***_Nidal Hilal
author Nidal Hilal
author2 Farah Ahmed
Nidal Hilal
Raed Hashaikeh
format Journal article
container_title Journal of Membrane Science
container_volume 556
container_start_page 66
publishDate 2018
institution Swansea University
issn 0376-7388
doi_str_mv 10.1016/j.memsci.2018.03.069
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
document_store_str 1
active_str 0
description Online monitoring of fouling in desalination processes enables early and appropriate action for fouling control. This study demonstrates the use of Electrochemical Impedance Spectroscopy (EIS) to electrically conductive membranes for online monitoring of fouling by eliminating the need for external electrodes and/or canary cells. Electrically conductive membranes are prepared by incorporation of silica in carbon nanostructures and subsequent fluorination to yield hydrophobic membranes. These membranes are applied to direct contact membrane distillation with 99.9% salt rejection and a flux of 4.3 LMH. EIS is used for online monitoring of inorganic fouling on the membrane surface during the MD process. Impedance spectra taken over a duration of 15 hours indicated that impedance in the low frequency (&#60;100 Hz) region gradually decreased with fouling early on, and increased towards the end. Impedance-based monitoring is more sensitive to changes in the system than monitoring of flux and permeate conductivity. It shows the capability of EIS as a sensitive online monitoring tool for fouling in MD.
published_date 2018-06-15T03:49:46Z
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score 11.01753