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A finite strain framework for the simulation of polymer curing. Part I: elasticity
Computational Mechanics, Volume: 44, Issue: 5, Pages: 621 - 630
Swansea University Author: Mokarram Hossain
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DOI (Published version): 10.1007/s00466-009-0397-0
Abstract
A phenomenologically motivated small strain model to simulate the curing of thermosets has been developed and discussed in a recently published paper (Hossain et al. in Comput Mech 43(6):769–779, 2009). Inspired by the concepts used there, this follow-up contribution presents an extension towards th...
Published in: | Computational Mechanics |
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ISSN: | 0178-7675 1432-0924 |
Published: |
Berlin
Springer-Verlag
2009
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Online Access: |
Check full text
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URI: | https://cronfa.swan.ac.uk/Record/cronfa38895 |
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Abstract: |
A phenomenologically motivated small strain model to simulate the curing of thermosets has been developed and discussed in a recently published paper (Hossain et al. in Comput Mech 43(6):769–779, 2009). Inspired by the concepts used there, this follow-up contribution presents an extension towards the finite strain regime. The thermodynamically consistent framework proposed here for the simulation of curing polymers particularly is independent of the choice of the free energy density, i.e. any phenomenological or micromechanical approach can be utilised. Both the governing equations for the curing simulation framework and the necessary details for the numerical implementation within the finite element method are derived. The curing of polymers is a very complex process involving a series of chemical reactions typically resulting in a conversion of low molecular weight monomer solutions into more or less cross-linked solid macromolecular structures. A material undergoing such a transition can be modelled by using an appropriate constitutive relation that is distinguished by prescribed temporal evolutions of its governing material parameters, which have to be determined experimentally. Part I of this work will deal with the elastic framework whereas the following Part II will focus on viscoelastic behaviour and shrinkage effects. Some numerical examples demonstrate the capability of our approach to correctly reproduce the behaviour of curing materials. |
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Keywords: |
Curing, Polymer, Finite strains, Elasticity |
College: |
Faculty of Science and Engineering |
Issue: |
5 |
Start Page: |
621 |
End Page: |
630 |