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One Step Facile Synthesis of Novel Anthanthrone Dye Based, Dopant-Free Hole Transporting Material for Efficient and Stable Perovskite Solar Cells

Prashant Murlidhar Sonar, Hong Duc Pham, Kazumasa Kazumasa Hayasaka, Hiroyuki MATSUI, Shizuo Tokito, Jinhyun Kim, Sagar Jain, James Durrant Orcid Logo, Wing Tsoi, Trystan Watson Orcid Logo, Nunzio Motta, Thu Trang Do, Krishna Feron, Sergei Manzhos, Wing Chung Tsoi Orcid Logo

Journal of Materials Chemistry C

Swansea University Authors: Sagar Jain, James Durrant Orcid Logo, Trystan Watson Orcid Logo, Wing Chung Tsoi Orcid Logo

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DOI (Published version): 10.1039/C7TC05238C

Abstract

Perovskite solar cell (PSCs) technology has made a tremendous impact in the solar cell community due to their exceptional performance, as the power conversion efficiency (PCE) surged to world record 22% within just last few years. Despite this high efficiency value, the commercialization of PSCs for...

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Published in: Journal of Materials Chemistry C
ISSN: 2050-7526 2050-7534
Published: 2017
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URI: https://cronfa.swan.ac.uk/Record/cronfa37962
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Despite this high efficiency value, the commercialization of PSCs for large area applications at affordable prices is still pending due to the low stability of devices in ambient atmospheric conditions and a very high cost of the hole transporting materials (HTM) used as the charge transporting layer in such devices. To cope with these challenges, the use of cheap HTMs can play a dual role in terms of lowering the overall cost of the perovskite technology as well as protecting the perovskite layer to achieve higher stability. In order to achieve these goals, various new organic hole transporting materials (HTMs) have been proposed. In this work we use a unique and novel anthanthrone (ANT) dye as a conjugated core building block and an affordable moiety to synthesize a new HTM. The commercially available dye was functionalized with an extended diphenylamine (DPA) end capping group. The newly developed HTM, named DPA-ANT-DPA, was one-step synthesized and used successfully in mesoporous perovskite solar cell devices, achieving a PCE of 11.5% under 1 sun condition with impressive stability. The obtained device efficiency is amongst the highest, as per D-A-D molecular design and low band gap concern. 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spelling 2018-03-05T14:38:39.0754477 v2 37962 2018-01-08 One Step Facile Synthesis of Novel Anthanthrone Dye Based, Dopant-Free Hole Transporting Material for Efficient and Stable Perovskite Solar Cells 7073e179bb5b82db3e3efd3a8cd07139 Sagar Jain Sagar Jain true false f3dd64bc260e5c07adfa916c27dbd58a 0000-0001-8353-7345 James Durrant James Durrant true false a210327b52472cfe8df9b8108d661457 0000-0002-8015-1436 Trystan Watson Trystan Watson true false 7e5f541df6635a9a8e1a579ff2de5d56 0000-0003-3836-5139 Wing Chung Tsoi Wing Chung Tsoi true false 2018-01-08 EEN Perovskite solar cell (PSCs) technology has made a tremendous impact in the solar cell community due to their exceptional performance, as the power conversion efficiency (PCE) surged to world record 22% within just last few years. Despite this high efficiency value, the commercialization of PSCs for large area applications at affordable prices is still pending due to the low stability of devices in ambient atmospheric conditions and a very high cost of the hole transporting materials (HTM) used as the charge transporting layer in such devices. To cope with these challenges, the use of cheap HTMs can play a dual role in terms of lowering the overall cost of the perovskite technology as well as protecting the perovskite layer to achieve higher stability. In order to achieve these goals, various new organic hole transporting materials (HTMs) have been proposed. In this work we use a unique and novel anthanthrone (ANT) dye as a conjugated core building block and an affordable moiety to synthesize a new HTM. The commercially available dye was functionalized with an extended diphenylamine (DPA) end capping group. The newly developed HTM, named DPA-ANT-DPA, was one-step synthesized and used successfully in mesoporous perovskite solar cell devices, achieving a PCE of 11.5% under 1 sun condition with impressive stability. The obtained device efficiency is amongst the highest, as per D-A-D molecular design and low band gap concern. Such kind of low cost HTM based on inexpensive starting precursor anthanthrone dye paves the way for economical and large-scale production of stable perovskite solar cells. Journal Article Journal of Materials Chemistry C 2050-7526 2050-7534 31 12 2017 2017-12-31 10.1039/C7TC05238C COLLEGE NANME Engineering COLLEGE CODE EEN Swansea University 2018-03-05T14:38:39.0754477 2018-01-08T15:46:57.5582422 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering Prashant Murlidhar Sonar 1 Hong Duc Pham 2 Kazumasa Kazumasa Hayasaka 3 Hiroyuki MATSUI 4 Shizuo Tokito 5 Jinhyun Kim 6 Sagar Jain 7 James Durrant 0000-0001-8353-7345 8 Wing Tsoi 9 Trystan Watson 0000-0002-8015-1436 10 Nunzio Motta 11 Thu Trang Do 12 Krishna Feron 13 Sergei Manzhos 14 Wing Chung Tsoi 0000-0003-3836-5139 15 0037962-08012018154910.pdf sonar2017.pdf 2018-01-08T15:49:10.7230000 Output 2804704 application/pdf Accepted Manuscript true 2018-12-18T00:00:00.0000000 true eng
title One Step Facile Synthesis of Novel Anthanthrone Dye Based, Dopant-Free Hole Transporting Material for Efficient and Stable Perovskite Solar Cells
spellingShingle One Step Facile Synthesis of Novel Anthanthrone Dye Based, Dopant-Free Hole Transporting Material for Efficient and Stable Perovskite Solar Cells
Sagar Jain
James Durrant
Trystan Watson
Wing Chung Tsoi
title_short One Step Facile Synthesis of Novel Anthanthrone Dye Based, Dopant-Free Hole Transporting Material for Efficient and Stable Perovskite Solar Cells
title_full One Step Facile Synthesis of Novel Anthanthrone Dye Based, Dopant-Free Hole Transporting Material for Efficient and Stable Perovskite Solar Cells
title_fullStr One Step Facile Synthesis of Novel Anthanthrone Dye Based, Dopant-Free Hole Transporting Material for Efficient and Stable Perovskite Solar Cells
title_full_unstemmed One Step Facile Synthesis of Novel Anthanthrone Dye Based, Dopant-Free Hole Transporting Material for Efficient and Stable Perovskite Solar Cells
title_sort One Step Facile Synthesis of Novel Anthanthrone Dye Based, Dopant-Free Hole Transporting Material for Efficient and Stable Perovskite Solar Cells
author_id_str_mv 7073e179bb5b82db3e3efd3a8cd07139
f3dd64bc260e5c07adfa916c27dbd58a
a210327b52472cfe8df9b8108d661457
7e5f541df6635a9a8e1a579ff2de5d56
author_id_fullname_str_mv 7073e179bb5b82db3e3efd3a8cd07139_***_Sagar Jain
f3dd64bc260e5c07adfa916c27dbd58a_***_James Durrant
a210327b52472cfe8df9b8108d661457_***_Trystan Watson
7e5f541df6635a9a8e1a579ff2de5d56_***_Wing Chung Tsoi
author Sagar Jain
James Durrant
Trystan Watson
Wing Chung Tsoi
author2 Prashant Murlidhar Sonar
Hong Duc Pham
Kazumasa Kazumasa Hayasaka
Hiroyuki MATSUI
Shizuo Tokito
Jinhyun Kim
Sagar Jain
James Durrant
Wing Tsoi
Trystan Watson
Nunzio Motta
Thu Trang Do
Krishna Feron
Sergei Manzhos
Wing Chung Tsoi
format Journal article
container_title Journal of Materials Chemistry C
publishDate 2017
institution Swansea University
issn 2050-7526
2050-7534
doi_str_mv 10.1039/C7TC05238C
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
document_store_str 1
active_str 0
description Perovskite solar cell (PSCs) technology has made a tremendous impact in the solar cell community due to their exceptional performance, as the power conversion efficiency (PCE) surged to world record 22% within just last few years. Despite this high efficiency value, the commercialization of PSCs for large area applications at affordable prices is still pending due to the low stability of devices in ambient atmospheric conditions and a very high cost of the hole transporting materials (HTM) used as the charge transporting layer in such devices. To cope with these challenges, the use of cheap HTMs can play a dual role in terms of lowering the overall cost of the perovskite technology as well as protecting the perovskite layer to achieve higher stability. In order to achieve these goals, various new organic hole transporting materials (HTMs) have been proposed. In this work we use a unique and novel anthanthrone (ANT) dye as a conjugated core building block and an affordable moiety to synthesize a new HTM. The commercially available dye was functionalized with an extended diphenylamine (DPA) end capping group. The newly developed HTM, named DPA-ANT-DPA, was one-step synthesized and used successfully in mesoporous perovskite solar cell devices, achieving a PCE of 11.5% under 1 sun condition with impressive stability. The obtained device efficiency is amongst the highest, as per D-A-D molecular design and low band gap concern. Such kind of low cost HTM based on inexpensive starting precursor anthanthrone dye paves the way for economical and large-scale production of stable perovskite solar cells.
published_date 2017-12-31T03:47:55Z
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