Journal article 1421 views 163 downloads
An enhanced rheometer inertia correction procedure (ERIC) for the study of gelling systems using combined motor-transducer rheometers
R. E. Hudson,
A. J. Holder,
Karl Hawkins 
,
Daniel Curtis ,
Rhodri Williams
,
Daniel Curtis ,
Rhodri Williams
Physics of Fluids, Volume: 29, Issue: 12
Swansea University Authors:
Karl Hawkins , Daniel Curtis , Rhodri Williams
-
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DOI (Published version): 10.1063/1.4993308
Abstract
The rheological characterisation of viscoelastic materials undergoing a sol-gel transition at the Gel Point (GP) has important applications in a wide range of industrial, biological, and clinical environments and can provide information regarding both kinetic and microstructural aspects of gelation....
| Published in: | Physics of Fluids |
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| ISSN: | 1070-6631 1089-7666 |
| Published: |
2017
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| Online Access: |
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| URI: | https://cronfa.swan.ac.uk/Record/cronfa35940 |
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| Abstract: |
The rheological characterisation of viscoelastic materials undergoing a sol-gel transition at the Gel Point (GP) has important applications in a wide range of industrial, biological, and clinical environments and can provide information regarding both kinetic and microstructural aspects of gelation. The most rigorous basis for identifying the GP involves exploiting the frequency dependence of the real and imaginary parts of the complex shear modulus of the critical gel (the system at the GP) measured under small amplitude oscillatory shear conditions. This approach to GP identification requires that rheological data be obtained over a range of oscillatory shear frequencies. Such measurements are limited by sample mutation considerations (at low frequencies) and, when experiments are conducted using combined motor-transducer (CMT) rheometers, by instrument inertia considerations (at high frequencies). Together, sample mutation and inertia induced artefacts can lead to significant errors in the determination of the GP. Overcoming such artefacts is important, however, as the extension of the range of frequencies available to the experimentalist promises both more accurate GP determination and the ability to study rapidly gelling samples. Herein, we exploit the frequency independent viscoelastic properties of the critical gel to develop and evaluate an enhanced rheometer inertia correction procedure. The procedure allows acquisition of valid GP data at previously inaccessible frequencies (using CMT rheometers) and is applied in a study of the concentration dependence of bovine gelatin gelation GP parameters. A previously unreported concentration dependence of the stress relaxation exponent (α) for critical gelatin gels has been identified, which approaches a limiting value (α = 0.7) at low gelatin concentrations, this being in agreement with previous studies and theoretical predictions for percolating systems at the GP. |
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| Keywords: |
Gels, Mechanical stress, Oscillatory shear measurements, Shear modulus, Solgels |
| College: |
Faculty of Science and Engineering |
| Issue: |
12 |