Journal article 1267 views 208 downloads
Humidity resistant fabrication of CH3NH3PbI3 perovskite solar cells and modules
Nano Energy, Volume: 39, Pages: 60 - 68
Swansea University Author: Trystan Watson
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DOI (Published version): 10.1016/j.nanoen.2017.06.039
Abstract
A humidity resistant and versatile fabrication method for the production of very high quality, organic-inorganic perovskite films, solar cells and solar modules is presented. By using ethyl acetate as an anti-solvent during deposition, perovskite solar cells with power conversion efficiencies (PCEs)...
Published in: | Nano Energy |
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ISSN: | 2211-2855 |
Published: |
2017
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Online Access: |
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URI: | https://cronfa.swan.ac.uk/Record/cronfa34490 |
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Abstract: |
A humidity resistant and versatile fabrication method for the production of very high quality, organic-inorganic perovskite films, solar cells and solar modules is presented. By using ethyl acetate as an anti-solvent during deposition, perovskite solar cells with power conversion efficiencies (PCEs) up to 15% were fabricated in a 75% relative humidity (RH) environment. Ethyl acetate acts as a moisture absorber during spin-coating, protecting sensitive perovskite intermediate phases from airborne water during film formation and annealing. We have demonstrated the manufacture of 50 mm x 50 mm series interconnected modules with PCEs in excess of 10% for 13.5 cm2 devices processed in air at 75%RH and 11.8% at 50%RH. To the best of our knowledge, these results represent the highest efficiency for perovskite solar modules processed under high humidity ambient conditions. This new deposition protocol allows for low-cost, efficient and consistent device fabrication in humid climates and uncontrolled laboratories. |
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Keywords: |
perovskite; humidity; anti-solvent; ethyl acetate; module |
College: |
Faculty of Science and Engineering |
Funders: |
UKRI, (EP/M015254/1) and the SPECIFIC Innovation and Knowledge Centre (EP/N020863/1) |
Start Page: |
60 |
End Page: |
68 |