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Narrowband light detection via internal quantum efficiency manipulation of organic photodiodes

Ardalan Armin Orcid Logo, Ross D. Jansen-van Vuuren, Nikos Kopidakis, Paul L. Burn, Paul Meredith Orcid Logo

Nature Communications, Volume: 6, Issue: 1, Start page: 6343

Swansea University Authors: Ardalan Armin Orcid Logo, Paul Meredith Orcid Logo

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DOI (Published version): 10.1038/ncomms7343

Abstract

Spectrally selective, narrowband light detection is vital for full-color and Near Infrared (NIR) imaging, intelligent monitoring and machine vision. This is not possible using traditional broadband absorbing inorganic semiconductors without input filtering, nor narrowband absorbing organic semicondu...

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Published in: Nature Communications
ISSN: 2041-1723
Published: Springer Science and Business Media LLC 2015
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URI: https://cronfa.swan.ac.uk/Record/cronfa33783
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spelling 2022-12-05T12:34:15.3102869 v2 33783 2017-05-19 Narrowband light detection via internal quantum efficiency manipulation of organic photodiodes 22b270622d739d81e131bec7a819e2fd 0000-0002-6129-5354 Ardalan Armin Ardalan Armin true false 31e8fe57fa180d418afd48c3af280c2e 0000-0002-9049-7414 Paul Meredith Paul Meredith true false 2017-05-19 SPH Spectrally selective, narrowband light detection is vital for full-color and Near Infrared (NIR) imaging, intelligent monitoring and machine vision. This is not possible using traditional broadband absorbing inorganic semiconductors without input filtering, nor narrowband absorbing organic semiconductors particularly for the red and NIR. We demonstrate the first sub-100nm FWHM (Full-Width-at-Half-Maximum) visible-blind red and NIR photodetectors with state-of-the-art performance across critical response metrics. These devices are based upon organic photodiodes with optically thick junctions. Paradoxically, we use broadband absorbing organic semiconductors and utilize the electro-optical properties of the junction to create the narrowest band photoresponses yet demonstrated. In this context, these photodiodes outperfrom the encumbent technology (input filtered inorganic semiconductor diodes) and emerging technologies such as narrow absorber organic semiconductors or quantum nanocrystals. The design concept allows for response tuning and is generic for other spectral window. Furthermore, it is materials agnostic and applicable to disordered semiconductors such as perovskites. Journal Article Nature Communications 6 1 6343 Springer Science and Business Media LLC 2041-1723 organic photodiodes, narrowband, charge collection narrowing 1 5 2015 2015-05-01 10.1038/ncomms7343 COLLEGE NANME Physics COLLEGE CODE SPH Swansea University 2022-12-05T12:34:15.3102869 2017-05-19T15:25:40.1698167 Faculty of Science and Engineering School of Biosciences, Geography and Physics - Physics Ardalan Armin 0000-0002-6129-5354 1 Ross D. Jansen-van Vuuren 2 Nikos Kopidakis 3 Paul L. Burn 4 Paul Meredith 0000-0002-9049-7414 5
title Narrowband light detection via internal quantum efficiency manipulation of organic photodiodes
spellingShingle Narrowband light detection via internal quantum efficiency manipulation of organic photodiodes
Ardalan Armin
Paul Meredith
title_short Narrowband light detection via internal quantum efficiency manipulation of organic photodiodes
title_full Narrowband light detection via internal quantum efficiency manipulation of organic photodiodes
title_fullStr Narrowband light detection via internal quantum efficiency manipulation of organic photodiodes
title_full_unstemmed Narrowband light detection via internal quantum efficiency manipulation of organic photodiodes
title_sort Narrowband light detection via internal quantum efficiency manipulation of organic photodiodes
author_id_str_mv 22b270622d739d81e131bec7a819e2fd
31e8fe57fa180d418afd48c3af280c2e
author_id_fullname_str_mv 22b270622d739d81e131bec7a819e2fd_***_Ardalan Armin
31e8fe57fa180d418afd48c3af280c2e_***_Paul Meredith
author Ardalan Armin
Paul Meredith
author2 Ardalan Armin
Ross D. Jansen-van Vuuren
Nikos Kopidakis
Paul L. Burn
Paul Meredith
format Journal article
container_title Nature Communications
container_volume 6
container_issue 1
container_start_page 6343
publishDate 2015
institution Swansea University
issn 2041-1723
doi_str_mv 10.1038/ncomms7343
publisher Springer Science and Business Media LLC
college_str Faculty of Science and Engineering
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hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Biosciences, Geography and Physics - Physics{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Biosciences, Geography and Physics - Physics
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description Spectrally selective, narrowband light detection is vital for full-color and Near Infrared (NIR) imaging, intelligent monitoring and machine vision. This is not possible using traditional broadband absorbing inorganic semiconductors without input filtering, nor narrowband absorbing organic semiconductors particularly for the red and NIR. We demonstrate the first sub-100nm FWHM (Full-Width-at-Half-Maximum) visible-blind red and NIR photodetectors with state-of-the-art performance across critical response metrics. These devices are based upon organic photodiodes with optically thick junctions. Paradoxically, we use broadband absorbing organic semiconductors and utilize the electro-optical properties of the junction to create the narrowest band photoresponses yet demonstrated. In this context, these photodiodes outperfrom the encumbent technology (input filtered inorganic semiconductor diodes) and emerging technologies such as narrow absorber organic semiconductors or quantum nanocrystals. The design concept allows for response tuning and is generic for other spectral window. Furthermore, it is materials agnostic and applicable to disordered semiconductors such as perovskites.
published_date 2015-05-01T03:41:52Z
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score 11.017105