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Reversible Chelate-to-Bridge Ligand Exchange in Co2(CO)4(.mu.-PhC.tplbond.CPh)(bma) and Alkyne-Diphosphine Ligand Coupling. Synthesis, Reactivity, and Molecular Structures of Co2(CO)4(.mu.-PhC.tplbond.CPh)(bma), Co2(CO)4(.mu.-PhC....

Organometallics, Volume: 13, Issue: 10, Pages: 3788 - 3799

Swansea University Author: Simon Bott

Abstract

Reversible Chelate-to-Bridge Ligand Exchange in Co2(CO)4(.mu.-PhC.tplbond.CPh)(bma) and Alkyne-Diphosphine Ligand Coupling. Synthesis, Reactivity, and Molecular Structures of Co2(CO)4(.mu.-PhC.tplbond.CPh)(bma), Co2(CO)4(.mu.-PhC.tplbond.CPh){(Z)-Ph2PCH:CHPPh2}, and Co2(CO)4{.eta.2,.eta.2,.eta.1,.eta.1-(Z)-Ph2PC(Ph):(Ph)CC:C(PPh2)C(O)OC(O)}

Published in:	Organometallics
ISSN:	0276-7333 1520-6041
Published:	1994
Online Access:	Check full text
URI:	https://cronfa.swan.ac.uk/Record/cronfa33487
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