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Toluene Alkylation with Methanol to p-Xylene over Heteropoly Acids Supported by Clay

V.V. Bokade, S.S. Deshpande, R. Patil, S. Jain, G.D. Yadav, Sagar Jain

Journal of Natural Gas Chemistry, Volume: 16, Issue: 1, Pages: 42 - 45

Swansea University Author: Sagar Jain

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DOI (Published version): 10.1016/S1003-9953(07)60024-3

Abstract

The alkylation of toluene with methanol for the selective formation of p-xylene was systematically studied. Very few studies have been reported on the use of superacids such as heteropolyacids on cheap supports, such as clay. This article deals with the use of different heteropoly acids (HPAs), viz,...

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Published in: Journal of Natural Gas Chemistry
ISSN: 1003-9953
Published: 2007
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URI: https://cronfa.swan.ac.uk/Record/cronfa32902
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spelling 2017-04-06T11:55:30.8308774 v2 32902 2017-04-02 Toluene Alkylation with Methanol to p-Xylene over Heteropoly Acids Supported by Clay 7073e179bb5b82db3e3efd3a8cd07139 Sagar Jain Sagar Jain true false 2017-04-02 The alkylation of toluene with methanol for the selective formation of p-xylene was systematically studied. Very few studies have been reported on the use of superacids such as heteropolyacids on cheap supports, such as clay. This article deals with the use of different heteropoly acids (HPAs), viz, Dodeca-Tungstophosphoric acid [H3PO4·12WO3·xH2O] (TPA), Dodeca-Molybdo phosphoric acid ammonium salt hydrate [H12Mo12N3O40P+aq] (DMAA), Dodeca-Molybdo Phosphoric acid (PMA) on clay (Montmorillonite, K-10) and as such plain clay. This comparative study reveals that 20%PMA/Clay shows 62% toluene conversion and 100% selectivity toward p-xylene. Toluene Alkylation with Methanol to p-Xylene over Heteropoly Acids Supported by Clay. Available from: https://www.researchgate.net/publication/229294275_Toluene_Alkylation_with_Methanol_to_p-Xylene_over_Heteropoly_Acids_Supported_by_Clay [accessed Apr 2, 2017]. Journal Article Journal of Natural Gas Chemistry 16 1 42 45 1003-9953 31 12 2007 2007-12-31 10.1016/S1003-9953(07)60024-3 COLLEGE NANME COLLEGE CODE Swansea University 2017-04-06T11:55:30.8308774 2017-04-02T00:48:07.1075318 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised V.V. Bokade 1 S.S. Deshpande 2 R. Patil 3 S. Jain 4 G.D. Yadav 5 Sagar Jain 6
title Toluene Alkylation with Methanol to p-Xylene over Heteropoly Acids Supported by Clay
spellingShingle Toluene Alkylation with Methanol to p-Xylene over Heteropoly Acids Supported by Clay
Sagar Jain
title_short Toluene Alkylation with Methanol to p-Xylene over Heteropoly Acids Supported by Clay
title_full Toluene Alkylation with Methanol to p-Xylene over Heteropoly Acids Supported by Clay
title_fullStr Toluene Alkylation with Methanol to p-Xylene over Heteropoly Acids Supported by Clay
title_full_unstemmed Toluene Alkylation with Methanol to p-Xylene over Heteropoly Acids Supported by Clay
title_sort Toluene Alkylation with Methanol to p-Xylene over Heteropoly Acids Supported by Clay
author_id_str_mv 7073e179bb5b82db3e3efd3a8cd07139
author_id_fullname_str_mv 7073e179bb5b82db3e3efd3a8cd07139_***_Sagar Jain
author Sagar Jain
author2 V.V. Bokade
S.S. Deshpande
R. Patil
S. Jain
G.D. Yadav
Sagar Jain
format Journal article
container_title Journal of Natural Gas Chemistry
container_volume 16
container_issue 1
container_start_page 42
publishDate 2007
institution Swansea University
issn 1003-9953
doi_str_mv 10.1016/S1003-9953(07)60024-3
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
document_store_str 0
active_str 0
description The alkylation of toluene with methanol for the selective formation of p-xylene was systematically studied. Very few studies have been reported on the use of superacids such as heteropolyacids on cheap supports, such as clay. This article deals with the use of different heteropoly acids (HPAs), viz, Dodeca-Tungstophosphoric acid [H3PO4·12WO3·xH2O] (TPA), Dodeca-Molybdo phosphoric acid ammonium salt hydrate [H12Mo12N3O40P+aq] (DMAA), Dodeca-Molybdo Phosphoric acid (PMA) on clay (Montmorillonite, K-10) and as such plain clay. This comparative study reveals that 20%PMA/Clay shows 62% toluene conversion and 100% selectivity toward p-xylene. Toluene Alkylation with Methanol to p-Xylene over Heteropoly Acids Supported by Clay. Available from: https://www.researchgate.net/publication/229294275_Toluene_Alkylation_with_Methanol_to_p-Xylene_over_Heteropoly_Acids_Supported_by_Clay [accessed Apr 2, 2017].
published_date 2007-12-31T04:01:38Z
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score 11.090091

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