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On the role of non-covalent interactions in the assembly of 3D zirconium methyl- and ethyl-N,N-bis phosphonates

M. Taddei, R. Vivani, F. Costantino, Marco Taddei Orcid Logo

Dalton Transactions, Volume: 42, Issue: 26, Start page: 9671

Swansea University Author: Marco Taddei Orcid Logo

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DOI (Published version): 10.1039/c3dt50400j

Abstract

Novel Zr methyl- and ethyl-N,N-bis(methylphosphonates), with formula ZrF2[(O3PCH2)2NHCH3] and Zr[(HO3PCH2)(O3PCH2)NHC2H5]2, respectively, were prepared in mild solvothermal conditions and their structures were solved ab initio by laboratory X-ray powder diffraction data. Despite the chemical homolog...

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Published in: Dalton Transactions
ISSN: 1477-9226 1477-9234
Published: Royal Society of Chemistry (RSC) 2013
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URI: https://cronfa.swan.ac.uk/Record/cronfa32754
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first_indexed 2017-03-29T13:47:17Z
last_indexed 2018-02-09T05:21:01Z
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spelling 2017-04-03T12:04:03.0046627 v2 32754 2017-03-29 On the role of non-covalent interactions in the assembly of 3D zirconium methyl- and ethyl-N,N-bis phosphonates 5cffd1038508554d8596dee8b4e51052 0000-0003-2805-6375 Marco Taddei Marco Taddei true false 2017-03-29 EEN Novel Zr methyl- and ethyl-N,N-bis(methylphosphonates), with formula ZrF2[(O3PCH2)2NHCH3] and Zr[(HO3PCH2)(O3PCH2)NHC2H5]2, respectively, were prepared in mild solvothermal conditions and their structures were solved ab initio by laboratory X-ray powder diffraction data. Despite the chemical homology between the molecular building blocks, and the similar synthetic conditions, the two compounds showed different stoichiometry and crystal structure. A comparative analysis of these structures and that of homologous longer chain Zr phosphonates, previously reported, revealed the important contribution of the hydrophobic groups in the building of the crystal structure, in a way that can be compared to that observed in the assembly of amphiphilic systems. Journal Article Dalton Transactions 42 26 9671 Royal Society of Chemistry (RSC) 1477-9226 1477-9234 31 12 2013 2013-12-31 10.1039/c3dt50400j COLLEGE NANME Engineering COLLEGE CODE EEN Swansea University 2017-04-03T12:04:03.0046627 2017-03-29T09:52:47.8434324 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised M. Taddei 1 R. Vivani 2 F. Costantino 3 Marco Taddei 0000-0003-2805-6375 4
title On the role of non-covalent interactions in the assembly of 3D zirconium methyl- and ethyl-N,N-bis phosphonates
spellingShingle On the role of non-covalent interactions in the assembly of 3D zirconium methyl- and ethyl-N,N-bis phosphonates
Marco Taddei
title_short On the role of non-covalent interactions in the assembly of 3D zirconium methyl- and ethyl-N,N-bis phosphonates
title_full On the role of non-covalent interactions in the assembly of 3D zirconium methyl- and ethyl-N,N-bis phosphonates
title_fullStr On the role of non-covalent interactions in the assembly of 3D zirconium methyl- and ethyl-N,N-bis phosphonates
title_full_unstemmed On the role of non-covalent interactions in the assembly of 3D zirconium methyl- and ethyl-N,N-bis phosphonates
title_sort On the role of non-covalent interactions in the assembly of 3D zirconium methyl- and ethyl-N,N-bis phosphonates
author_id_str_mv 5cffd1038508554d8596dee8b4e51052
author_id_fullname_str_mv 5cffd1038508554d8596dee8b4e51052_***_Marco Taddei
author Marco Taddei
author2 M. Taddei
R. Vivani
F. Costantino
Marco Taddei
format Journal article
container_title Dalton Transactions
container_volume 42
container_issue 26
container_start_page 9671
publishDate 2013
institution Swansea University
issn 1477-9226
1477-9234
doi_str_mv 10.1039/c3dt50400j
publisher Royal Society of Chemistry (RSC)
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
document_store_str 0
active_str 0
description Novel Zr methyl- and ethyl-N,N-bis(methylphosphonates), with formula ZrF2[(O3PCH2)2NHCH3] and Zr[(HO3PCH2)(O3PCH2)NHC2H5]2, respectively, were prepared in mild solvothermal conditions and their structures were solved ab initio by laboratory X-ray powder diffraction data. Despite the chemical homology between the molecular building blocks, and the similar synthetic conditions, the two compounds showed different stoichiometry and crystal structure. A comparative analysis of these structures and that of homologous longer chain Zr phosphonates, previously reported, revealed the important contribution of the hydrophobic groups in the building of the crystal structure, in a way that can be compared to that observed in the assembly of amphiphilic systems.
published_date 2013-12-31T03:40:14Z
_version_ 1763751823932391424
score 11.013731

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