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Alternative Hydrogen Source for Asymmetric Transfer Hydrogenation in the Reduction of Ketones

R. Wakeham, J. Morris, J. Williams, Russell Wakeham Orcid Logo

ChemCatChem, Volume: 7, Issue: 24, Pages: 4039 - 4041

Swansea University Author: Russell Wakeham Orcid Logo

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DOI (Published version): 10.1002/cctc.201500886

Abstract

cis-1,4-Butenediol is shown to be a highly active hydrogen source for asymmetric transfer hydrogenation in the reduction of ketones. With the use of a ruthenium catalyst, cis-1,4-butenediol is isomerised and subsequently oxidised to a lactone as an irreversible step, which provides the driving force...

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Published in: ChemCatChem
ISSN: 1867-3880
Published: Wiley-Blackwell 2015
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URI: https://cronfa.swan.ac.uk/Record/cronfa32707
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first_indexed 2017-03-27T12:57:27Z
last_indexed 2018-02-09T05:20:55Z
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spelling 2017-03-28T10:53:35.1420374 v2 32707 2017-03-27 Alternative Hydrogen Source for Asymmetric Transfer Hydrogenation in the Reduction of Ketones 28c45bbeeba294da7042950705b98e0a 0000-0002-4304-0243 Russell Wakeham Russell Wakeham true false 2017-03-27 EEN cis-1,4-Butenediol is shown to be a highly active hydrogen source for asymmetric transfer hydrogenation in the reduction of ketones. With the use of a ruthenium catalyst, cis-1,4-butenediol is isomerised and subsequently oxidised to a lactone as an irreversible step, which provides the driving force for the asymmetric reduction of ketones. Journal Article ChemCatChem 7 24 4039 4041 Wiley-Blackwell 1867-3880 14 12 2015 2015-12-14 10.1002/cctc.201500886 COLLEGE NANME Engineering COLLEGE CODE EEN Swansea University 2017-03-28T10:53:35.1420374 2017-03-27T11:03:21.7516544 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised R. Wakeham 1 J. Morris 2 J. Williams 3 Russell Wakeham 0000-0002-4304-0243 4
title Alternative Hydrogen Source for Asymmetric Transfer Hydrogenation in the Reduction of Ketones
spellingShingle Alternative Hydrogen Source for Asymmetric Transfer Hydrogenation in the Reduction of Ketones
Russell Wakeham
title_short Alternative Hydrogen Source for Asymmetric Transfer Hydrogenation in the Reduction of Ketones
title_full Alternative Hydrogen Source for Asymmetric Transfer Hydrogenation in the Reduction of Ketones
title_fullStr Alternative Hydrogen Source for Asymmetric Transfer Hydrogenation in the Reduction of Ketones
title_full_unstemmed Alternative Hydrogen Source for Asymmetric Transfer Hydrogenation in the Reduction of Ketones
title_sort Alternative Hydrogen Source for Asymmetric Transfer Hydrogenation in the Reduction of Ketones
author_id_str_mv 28c45bbeeba294da7042950705b98e0a
author_id_fullname_str_mv 28c45bbeeba294da7042950705b98e0a_***_Russell Wakeham
author Russell Wakeham
author2 R. Wakeham
J. Morris
J. Williams
Russell Wakeham
format Journal article
container_title ChemCatChem
container_volume 7
container_issue 24
container_start_page 4039
publishDate 2015
institution Swansea University
issn 1867-3880
doi_str_mv 10.1002/cctc.201500886
publisher Wiley-Blackwell
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
document_store_str 0
active_str 0
description cis-1,4-Butenediol is shown to be a highly active hydrogen source for asymmetric transfer hydrogenation in the reduction of ketones. With the use of a ruthenium catalyst, cis-1,4-butenediol is isomerised and subsequently oxidised to a lactone as an irreversible step, which provides the driving force for the asymmetric reduction of ketones.
published_date 2015-12-14T03:40:10Z
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score 11.014067

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