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Enhancing Fullerene-Based Solar Cell Lifetimes by Addition of a Fullerene Dumbbell

Bob C. Schroeder, Zhe Li Orcid Logo, Michael A. Brady, Gregório Couto Faria, Raja Shahid Ashraf, Christopher J. Takacs, John S. Cowart, Duc T. Duong, Kar Ho Chiu, Ching-Hong Tan, João T. Cabral, Alberto Salleo, Michael L. Chabinyc, James R. Durrant, Iain McCulloch

Angewandte Chemie International Edition, Volume: 53, Issue: 47, Pages: 12870 - 12875

Swansea University Author: Zhe Li Orcid Logo

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DOI (Published version): 10.1002/anie.201407310

Abstract

Cost-effective, solution-processable organic photovoltaics (OPV) present an interesting alternative to inorganic silicon-based solar cells. However, one of the major remaining challenges of OPV devices is their lack of long-term operational stability, especially at elevated temperatures. The synthes...

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Published in: Angewandte Chemie International Edition
ISSN: 1433-7851
Published: 2014
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URI: https://cronfa.swan.ac.uk/Record/cronfa32084
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spelling 2017-02-28T14:40:08.7461787 v2 32084 2017-02-23 Enhancing Fullerene-Based Solar Cell Lifetimes by Addition of a Fullerene Dumbbell 56be57cc8dd661dfdbb921608cf93ded 0000-0002-7404-7448 Zhe Li Zhe Li true false 2017-02-23 EEN Cost-effective, solution-processable organic photovoltaics (OPV) present an interesting alternative to inorganic silicon-based solar cells. However, one of the major remaining challenges of OPV devices is their lack of long-term operational stability, especially at elevated temperatures. The synthesis of a fullerene dumbbell and its use as an additive in the active layer of a PCDTBT:PCBM-based OPV device is reported. The addition of only 20 % of this novel fullerene not only leads to improved device efficiencies, but more importantly also to a dramatic increase in morphological stability under simulated operating conditions. Dynamic secondary ion mass spectrometry (DSIMS) and TEM are used, amongst other techniques, to elucidate the origins of the improved morphological stability. Journal Article Angewandte Chemie International Edition 53 47 12870 12875 1433-7851 17 11 2014 2014-11-17 10.1002/anie.201407310 COLLEGE NANME Engineering COLLEGE CODE EEN Swansea University 2017-02-28T14:40:08.7461787 2017-02-23T16:14:15.2850268 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised Bob C. Schroeder 1 Zhe Li 0000-0002-7404-7448 2 Michael A. Brady 3 Gregório Couto Faria 4 Raja Shahid Ashraf 5 Christopher J. Takacs 6 John S. Cowart 7 Duc T. Duong 8 Kar Ho Chiu 9 Ching-Hong Tan 10 João T. Cabral 11 Alberto Salleo 12 Michael L. Chabinyc 13 James R. Durrant 14 Iain McCulloch 15 0032084-28022017143929.pdf Schroeder2014.pdf 2017-02-28T14:39:29.6370000 Output 741277 application/pdf Version of Record true 2017-02-28T00:00:00.0000000 false eng
title Enhancing Fullerene-Based Solar Cell Lifetimes by Addition of a Fullerene Dumbbell
spellingShingle Enhancing Fullerene-Based Solar Cell Lifetimes by Addition of a Fullerene Dumbbell
Zhe Li
title_short Enhancing Fullerene-Based Solar Cell Lifetimes by Addition of a Fullerene Dumbbell
title_full Enhancing Fullerene-Based Solar Cell Lifetimes by Addition of a Fullerene Dumbbell
title_fullStr Enhancing Fullerene-Based Solar Cell Lifetimes by Addition of a Fullerene Dumbbell
title_full_unstemmed Enhancing Fullerene-Based Solar Cell Lifetimes by Addition of a Fullerene Dumbbell
title_sort Enhancing Fullerene-Based Solar Cell Lifetimes by Addition of a Fullerene Dumbbell
author_id_str_mv 56be57cc8dd661dfdbb921608cf93ded
author_id_fullname_str_mv 56be57cc8dd661dfdbb921608cf93ded_***_Zhe Li
author Zhe Li
author2 Bob C. Schroeder
Zhe Li
Michael A. Brady
Gregório Couto Faria
Raja Shahid Ashraf
Christopher J. Takacs
John S. Cowart
Duc T. Duong
Kar Ho Chiu
Ching-Hong Tan
João T. Cabral
Alberto Salleo
Michael L. Chabinyc
James R. Durrant
Iain McCulloch
format Journal article
container_title Angewandte Chemie International Edition
container_volume 53
container_issue 47
container_start_page 12870
publishDate 2014
institution Swansea University
issn 1433-7851
doi_str_mv 10.1002/anie.201407310
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised
document_store_str 1
active_str 0
description Cost-effective, solution-processable organic photovoltaics (OPV) present an interesting alternative to inorganic silicon-based solar cells. However, one of the major remaining challenges of OPV devices is their lack of long-term operational stability, especially at elevated temperatures. The synthesis of a fullerene dumbbell and its use as an additive in the active layer of a PCDTBT:PCBM-based OPV device is reported. The addition of only 20 % of this novel fullerene not only leads to improved device efficiencies, but more importantly also to a dramatic increase in morphological stability under simulated operating conditions. Dynamic secondary ion mass spectrometry (DSIMS) and TEM are used, amongst other techniques, to elucidate the origins of the improved morphological stability.
published_date 2014-11-17T03:39:16Z
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score 11.013371

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