Journal article 1815 views
Nanofiltration of treated digested agricultural wastewater for recovery of carboxylic acids
Journal of Cleaner Production, Volume: 112, Pages: 4749 - 4761
Swansea University Authors: Myrto-panagiota Zacharof, Paul Williams , Robert Lovitt
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DOI (Published version): 10.1016/j.jclepro.2015.07.004
Abstract
Synthetic solutions of varying concentrations of carboxylic acids, namely acetic and butyric acids (50 mM, 100 mM) and treated digested agricultural wastewater with a carboxylic acids concentration of 21.08 mM of acetic acid and 15.81 mM of butyric acid were processed with a range of nanofiltration...
Published in: | Journal of Cleaner Production |
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ISSN: | 0959-6526 |
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2016
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URI: | https://cronfa.swan.ac.uk/Record/cronfa28826 |
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2016-06-10T18:26:37Z |
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2018-02-09T05:13:21Z |
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2017-07-11T14:56:32.5753963 v2 28826 2016-06-10 Nanofiltration of treated digested agricultural wastewater for recovery of carboxylic acids 58dbbe00d55ca29ad8b9fb78ba86fe46 Myrto-panagiota Zacharof Myrto-panagiota Zacharof true false 3ed8f1e5d997e0fcb256fb6501605cec 0000-0003-0511-4659 Paul Williams Paul Williams true false 130c3c35f45826bb0f4836305e8e51c7 0000-0002-5587-2776 Robert Lovitt Robert Lovitt true false 2016-06-10 Synthetic solutions of varying concentrations of carboxylic acids, namely acetic and butyric acids (50 mM, 100 mM) and treated digested agricultural wastewater with a carboxylic acids concentration of 21.08 mM of acetic acid and 15.81 mM of butyric acid were processed with a range of nanofiltration membranes and enrichment schemes to concentrate carboxylic acids. The study was conducted with the scope of platform chemicals recovery from complex effluents, investigating the feasibility of nanofiltration as a method of choice. Membrane filtration is easily scalable into various arrangements, allowing versatility in operation and enrichment treatments, which other recovery practices such as liquid extraction do not allow. Among the five nanofiltration membranes used (NF270 (Dow Chemicals, USA), HL, DL, DK (Osmonics, USA), LF10 (Nitto Denko, Japan)) the DK, DL and NF270 were identified as the best candidates for carboxylic acids separation and concentration from these complex effluents, both in terms of retention and permeate flux. These membranes achieved retention ratios, up to 75% giving retentates up to 53.94 mM acetate and 28.38 mM butyrate for the agricultural wastewater. Effluents were modified by the addition of alkali and salts (sodium chloride and sodium bicarbonate), and it was found that highest productivity, retention and flux was achieved at pH 7 but at higher pH there was a significant reduction in flux. Journal Article Journal of Cleaner Production 112 4749 4761 0959-6526 20 1 2016 2016-01-20 10.1016/j.jclepro.2015.07.004 COLLEGE NANME COLLEGE CODE Swansea University 2017-07-11T14:56:32.5753963 2016-06-10T15:34:15.1327665 Faculty of Science and Engineering School of Engineering and Applied Sciences - Uncategorised Myrto-panagiota Zacharof 1 Stephen J. Mandale 2 Paul Williams 0000-0003-0511-4659 3 Robert Lovitt 0000-0002-5587-2776 4 |
title |
Nanofiltration of treated digested agricultural wastewater for recovery of carboxylic acids |
spellingShingle |
Nanofiltration of treated digested agricultural wastewater for recovery of carboxylic acids Myrto-panagiota Zacharof Paul Williams Robert Lovitt |
title_short |
Nanofiltration of treated digested agricultural wastewater for recovery of carboxylic acids |
title_full |
Nanofiltration of treated digested agricultural wastewater for recovery of carboxylic acids |
title_fullStr |
Nanofiltration of treated digested agricultural wastewater for recovery of carboxylic acids |
title_full_unstemmed |
Nanofiltration of treated digested agricultural wastewater for recovery of carboxylic acids |
title_sort |
Nanofiltration of treated digested agricultural wastewater for recovery of carboxylic acids |
author_id_str_mv |
58dbbe00d55ca29ad8b9fb78ba86fe46 3ed8f1e5d997e0fcb256fb6501605cec 130c3c35f45826bb0f4836305e8e51c7 |
author_id_fullname_str_mv |
58dbbe00d55ca29ad8b9fb78ba86fe46_***_Myrto-panagiota Zacharof 3ed8f1e5d997e0fcb256fb6501605cec_***_Paul Williams 130c3c35f45826bb0f4836305e8e51c7_***_Robert Lovitt |
author |
Myrto-panagiota Zacharof Paul Williams Robert Lovitt |
author2 |
Myrto-panagiota Zacharof Stephen J. Mandale Paul Williams Robert Lovitt |
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Journal article |
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Journal of Cleaner Production |
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112 |
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4749 |
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2016 |
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Swansea University |
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0959-6526 |
doi_str_mv |
10.1016/j.jclepro.2015.07.004 |
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Faculty of Science and Engineering |
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facultyofscienceandengineering |
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Faculty of Science and Engineering |
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Faculty of Science and Engineering |
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School of Engineering and Applied Sciences - Uncategorised{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Uncategorised |
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description |
Synthetic solutions of varying concentrations of carboxylic acids, namely acetic and butyric acids (50 mM, 100 mM) and treated digested agricultural wastewater with a carboxylic acids concentration of 21.08 mM of acetic acid and 15.81 mM of butyric acid were processed with a range of nanofiltration membranes and enrichment schemes to concentrate carboxylic acids. The study was conducted with the scope of platform chemicals recovery from complex effluents, investigating the feasibility of nanofiltration as a method of choice. Membrane filtration is easily scalable into various arrangements, allowing versatility in operation and enrichment treatments, which other recovery practices such as liquid extraction do not allow. Among the five nanofiltration membranes used (NF270 (Dow Chemicals, USA), HL, DL, DK (Osmonics, USA), LF10 (Nitto Denko, Japan)) the DK, DL and NF270 were identified as the best candidates for carboxylic acids separation and concentration from these complex effluents, both in terms of retention and permeate flux. These membranes achieved retention ratios, up to 75% giving retentates up to 53.94 mM acetate and 28.38 mM butyrate for the agricultural wastewater. Effluents were modified by the addition of alkali and salts (sodium chloride and sodium bicarbonate), and it was found that highest productivity, retention and flux was achieved at pH 7 but at higher pH there was a significant reduction in flux. |
published_date |
2016-01-20T19:03:31Z |
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1821433356545425408 |
score |
11.047609 |