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In situ monitoring of corrosion mechanisms and phosphate inhibitor surface deposition during corrosion of zinc–magnesium–aluminium (ZMA) alloys using novel time-lapse microscopy

James Sullivan Orcid Logo, Nathan Cooze Orcid Logo, Callum Gallagher, Tom Lewis, Tomas Prosek, Dominique Thierry

Faraday Discuss., Volume: 180, Pages: 361 - 379

Swansea University Authors: James Sullivan Orcid Logo, Nathan Cooze Orcid Logo

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DOI (Published version): 10.1039/C4FD00251B

Abstract

In-situ time-lapse optical microscopy was used to examine the microstructural corrosion mechanisms in three zinc-magnesium-aluminium (ZMA) alloy coated steels immersed in 1% NaCl pH 7. Preferential corrosion of MgZn2 lamellae within the eutectic phases was observed in all the ZMA alloys followed by...

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Published in: Faraday Discuss.
ISSN: 1359-6640 1364-5498
Published: 2015
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URI: https://cronfa.swan.ac.uk/Record/cronfa21370
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spelling 2020-10-29T16:33:23.5395713 v2 21370 2015-05-13 In situ monitoring of corrosion mechanisms and phosphate inhibitor surface deposition during corrosion of zinc–magnesium–aluminium (ZMA) alloys using novel time-lapse microscopy 40e32d66748ab74184a31207ab145708 0000-0003-1018-773X James Sullivan James Sullivan true false 0a64e9ea4739faddc8e873f0eee803bc 0000-0002-7870-9699 Nathan Cooze Nathan Cooze true false 2015-05-13 MTLS In-situ time-lapse optical microscopy was used to examine the microstructural corrosion mechanisms in three zinc-magnesium-aluminium (ZMA) alloy coated steels immersed in 1% NaCl pH 7. Preferential corrosion of MgZn2 lamellae within the eutectic phases was observed in all the ZMA alloys followed by subsequent dissolution of Zn rich phases. The total extent and rate of corrosion, measured using time-lapse image analysis and scanning vibrating electrode technique (SVET) estimated mass loss, decreased as Mg and Al alloying additions were increased up to a level of 3 wt% Mg and 3.7 wt% Al. This was probably due to the increased presence of MgO and Al2O3 at the alloy surface retarding the kinetics of cathodic oxygen reduction. The addition of 1 x 10-2 mol/dm3 Na3PO4 to 1% NaCl pH 7 had a dramatic influence on the corrosion mechanism for a ZMA with passivation of anodic sites through phosphate precipitation observed using time-lapse. Intriguing rapid precipitation of filamentous phosphate was also observed and it is postulated that these filaments nucleate and grow due to super saturation effects. Polarisation experiments showed that the addition of 1 x 10-2 mol/dm3 Na3PO4 to the 1% NaCl electrolyte promoted an anodic shift of 50mV in open circuit potential for the ZMA alloy with a reduction in anodic current of 2.5 orders of magnitude suggesting that it was acting primarily as an anodic inhibitor supporting the inferences from the time-lapse investigations. These phosphate additions resulted in a 98% reduction in estimated mass loss as measured by SVET demonstrating the effectiveness of phosphate inhibitors for this alloy system. Journal Article Faraday Discuss. 180 361 379 1359-6640 1364-5498 1 8 2015 2015-08-01 10.1039/C4FD00251B COLLEGE NANME Materials Science and Engineering COLLEGE CODE MTLS Swansea University 2020-10-29T16:33:23.5395713 2015-05-13T15:51:52.8810773 Faculty of Science and Engineering School of Engineering and Applied Sciences - Materials Science and Engineering James Sullivan 0000-0003-1018-773X 1 Nathan Cooze 0000-0002-7870-9699 2 Callum Gallagher 3 Tom Lewis 4 Tomas Prosek 5 Dominique Thierry 6 0021370-07072015142007.pdf Faraday__discussions__paper__revised.pdf 2015-07-07T14:20:07.8230000 Output 17550200 application/pdf Accepted Manuscript true 2015-07-07T00:00:00.0000000 true
title In situ monitoring of corrosion mechanisms and phosphate inhibitor surface deposition during corrosion of zinc–magnesium–aluminium (ZMA) alloys using novel time-lapse microscopy
spellingShingle In situ monitoring of corrosion mechanisms and phosphate inhibitor surface deposition during corrosion of zinc–magnesium–aluminium (ZMA) alloys using novel time-lapse microscopy
James Sullivan
Nathan Cooze
title_short In situ monitoring of corrosion mechanisms and phosphate inhibitor surface deposition during corrosion of zinc–magnesium–aluminium (ZMA) alloys using novel time-lapse microscopy
title_full In situ monitoring of corrosion mechanisms and phosphate inhibitor surface deposition during corrosion of zinc–magnesium–aluminium (ZMA) alloys using novel time-lapse microscopy
title_fullStr In situ monitoring of corrosion mechanisms and phosphate inhibitor surface deposition during corrosion of zinc–magnesium–aluminium (ZMA) alloys using novel time-lapse microscopy
title_full_unstemmed In situ monitoring of corrosion mechanisms and phosphate inhibitor surface deposition during corrosion of zinc–magnesium–aluminium (ZMA) alloys using novel time-lapse microscopy
title_sort In situ monitoring of corrosion mechanisms and phosphate inhibitor surface deposition during corrosion of zinc–magnesium–aluminium (ZMA) alloys using novel time-lapse microscopy
author_id_str_mv 40e32d66748ab74184a31207ab145708
0a64e9ea4739faddc8e873f0eee803bc
author_id_fullname_str_mv 40e32d66748ab74184a31207ab145708_***_James Sullivan
0a64e9ea4739faddc8e873f0eee803bc_***_Nathan Cooze
author James Sullivan
Nathan Cooze
author2 James Sullivan
Nathan Cooze
Callum Gallagher
Tom Lewis
Tomas Prosek
Dominique Thierry
format Journal article
container_title Faraday Discuss.
container_volume 180
container_start_page 361
publishDate 2015
institution Swansea University
issn 1359-6640
1364-5498
doi_str_mv 10.1039/C4FD00251B
college_str Faculty of Science and Engineering
hierarchytype
hierarchy_top_id facultyofscienceandengineering
hierarchy_top_title Faculty of Science and Engineering
hierarchy_parent_id facultyofscienceandengineering
hierarchy_parent_title Faculty of Science and Engineering
department_str School of Engineering and Applied Sciences - Materials Science and Engineering{{{_:::_}}}Faculty of Science and Engineering{{{_:::_}}}School of Engineering and Applied Sciences - Materials Science and Engineering
document_store_str 1
active_str 0
description In-situ time-lapse optical microscopy was used to examine the microstructural corrosion mechanisms in three zinc-magnesium-aluminium (ZMA) alloy coated steels immersed in 1% NaCl pH 7. Preferential corrosion of MgZn2 lamellae within the eutectic phases was observed in all the ZMA alloys followed by subsequent dissolution of Zn rich phases. The total extent and rate of corrosion, measured using time-lapse image analysis and scanning vibrating electrode technique (SVET) estimated mass loss, decreased as Mg and Al alloying additions were increased up to a level of 3 wt% Mg and 3.7 wt% Al. This was probably due to the increased presence of MgO and Al2O3 at the alloy surface retarding the kinetics of cathodic oxygen reduction. The addition of 1 x 10-2 mol/dm3 Na3PO4 to 1% NaCl pH 7 had a dramatic influence on the corrosion mechanism for a ZMA with passivation of anodic sites through phosphate precipitation observed using time-lapse. Intriguing rapid precipitation of filamentous phosphate was also observed and it is postulated that these filaments nucleate and grow due to super saturation effects. Polarisation experiments showed that the addition of 1 x 10-2 mol/dm3 Na3PO4 to the 1% NaCl electrolyte promoted an anodic shift of 50mV in open circuit potential for the ZMA alloy with a reduction in anodic current of 2.5 orders of magnitude suggesting that it was acting primarily as an anodic inhibitor supporting the inferences from the time-lapse investigations. These phosphate additions resulted in a 98% reduction in estimated mass loss as measured by SVET demonstrating the effectiveness of phosphate inhibitors for this alloy system.
published_date 2015-08-01T03:25:20Z
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